Open Access

Journal of Molecular Liquids, volume 337, pages 116416

Effect of polar protic solvents on the photophysical properties of bis(BODIPY) dyes

Antina Lubov A ¹

Antina Elena V ¹

Ksenofontov Alexander A

Berezin Mikhail B

Kalyagin Alexander A ¹

Lodochnikova Olga A

R. Islamov Daut ^{2, 3}

Pavelyev Roman S

Ksenofontov A.L. ¹

Pavelyev Roman S. ³

Lodochnikova Olga A. ^{2, 3}

Berezin Mikhail Y. ¹

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G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, 1 Akademicheskaya str., 153045 Ivanovo, Russian Federation |

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, 8 Arbuzov, 420088 Kazan, Russian Federation

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Kazan Scientific Center of the Russian Academy of Sciences

Kazan Federal University, 18 Kremlyovskaya s., 420008 Kazan, Russian Federation |

Publication type: Journal Article

Publication date: 2021-09-01

Elsevier

Journal: Journal of Molecular Liquids

Quartile SCImago

Quartile WOS

Impact factor: 6

ISSN: 01677322, 18733166

DOI: 10.1016/j.molliq.2021.116416

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Materials Chemistry

Electronic, Optical and Magnetic Materials

Physical and Theoretical Chemistry

Spectroscopy

Atomic and Molecular Physics, and Optics

Condensed Matter Physics

Abstract

• The bis(BODIPY)s fluorescence sensitivity to the medium polarity and acidity was analysed. • The bis(BODIPY)s fluorescence quenching was observed in alcohols. • Bis(BODIPY)s form supramolecular complexes with alcohol molecules. • Bichromophoric dyes have prospects of application as alcohols fluorescent sensors. In this paper, detailed comparative analysis of the spectral properties of bis(BODIPY) dyes in various organic solvents: saturated aromatic hydrocarbons, homologous series of alcohols (C n OH, n = 2–4, 8, 10) and mixture of ethanol-glycerol with different viscosity was carried out. In bis(BODIPY) dimeric molecules, the BODIPY chromophore domains are linked by a methylene spacer at the 2,2-, 2,3-, or 3,3-positions ( 1 , 2 , and 3 respectively). The absorption spectra of the bis(BODIPY)s exhibit exciton splitting of band maxima. We showed that bis(BODIPY)s are sensitive to the polarity and acidity of media due to its structural features. The mechanism of fluorescence quenching of 1 – 3 in the series of alcohols are explained in detail. It has been established that the fluorescence quenching efficiency of dimeric dyes in alcohols is determined by both universal and specific interactions. The fluorescence quantum yield of bis(BODIPY)s is minimal in ethanol and increases in the alcohols homologous series due to a reduction in medium polarity and the stability of the bis(BODIPY)(Solv) 2 supramolecular structures. In viscous ethanol-glycerol mixtures, fluorescence of 1 – 3 increases because of the limitation of the dye molecules conformational mobility. The results of the study allow us to predict the possibility of practical application of 1 – 3 as alcohols fluorescent sensors in various media.

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Citations by journals

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Journal of Photochemistry and Photobiology A: Chemistry	Journal of Photochemistry and Photobiology A: Chemistry, 3, 17.65% Journal of Photochemistry and Photobiology A: Chemistry 3 publications, 17.65%
Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy	Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 2, 11.76% Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy 2 publications, 11.76%
Physical Chemistry Chemical Physics	Physical Chemistry Chemical Physics, 2, 11.76% Physical Chemistry Chemical Physics 2 publications, 11.76%
Journal of Molecular Liquids	Journal of Molecular Liquids, 2, 11.76% Journal of Molecular Liquids 2 publications, 11.76%
Russian Journal of Inorganic Chemistry	Russian Journal of Inorganic Chemistry, 1, 5.88% Russian Journal of Inorganic Chemistry 1 publication, 5.88%
Coordination Chemistry Reviews	Coordination Chemistry Reviews, 1, 5.88% Coordination Chemistry Reviews 1 publication, 5.88%
Russian Physics Journal	Russian Physics Journal, 1, 5.88% Russian Physics Journal 1 publication, 5.88%
ACS Omega	ACS Omega, 1, 5.88% ACS Omega 1 publication, 5.88%
New Journal of Chemistry	New Journal of Chemistry, 1, 5.88% New Journal of Chemistry 1 publication, 5.88%
International Journal of Molecular Sciences	International Journal of Molecular Sciences, 1, 5.88% International Journal of Molecular Sciences 1 publication, 5.88%
Journal of Luminescence	Journal of Luminescence, 1, 5.88% Journal of Luminescence 1 publication, 5.88%
	1 2 3

Citations by publishers

	1 2 3 4 5 6 7 8 9
Elsevier	Elsevier, 9, 52.94% Elsevier 9 publications, 52.94%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 3, 17.65% Royal Society of Chemistry (RSC) 3 publications, 17.65%
Pleiades Publishing	Pleiades Publishing, 1, 5.88% Pleiades Publishing 1 publication, 5.88%
Springer Nature	Springer Nature, 1, 5.88% Springer Nature 1 publication, 5.88%
American Chemical Society (ACS)	American Chemical Society (ACS), 1, 5.88% American Chemical Society (ACS) 1 publication, 5.88%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 1, 5.88% Multidisciplinary Digital Publishing Institute (MDPI) 1 publication, 5.88%
	1 2 3 4 5 6 7 8 9

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Antina E. V. et al. Effect of polar protic solvents on the photophysical properties of bis(BODIPY) dyes // Journal of Molecular Liquids. 2021. Vol. 337. p. 116416.

GOST all authors (up to 50) Copy

Antina E. V., Kalyagin A. A., Ksenofontov A. A., Lodochnikova O. A., R. Islamov D., Berezin M. B., Antina L. A., Pavelyev R. S., Ksenofontov A., Pavelyev R. S., Lodochnikova O. A., Berezin M. Y. Effect of polar protic solvents on the photophysical properties of bis(BODIPY) dyes // Journal of Molecular Liquids. 2021. Vol. 337. p. 116416.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.molliq.2021.116416

UR - https://doi.org/10.1016%2Fj.molliq.2021.116416

TI - Effect of polar protic solvents on the photophysical properties of bis(BODIPY) dyes

T2 - Journal of Molecular Liquids

AU - Antina, Elena V

AU - Kalyagin, Alexander A

AU - Ksenofontov, Alexander A

AU - Lodochnikova, Olga A

AU - R. Islamov, Daut

AU - Berezin, Mikhail B

AU - Antina, Lubov A

AU - Pavelyev, Roman S

AU - Ksenofontov, A.L.

AU - Pavelyev, Roman S.

AU - Lodochnikova, Olga A.

AU - Berezin, Mikhail Y.

PY - 2021

DA - 2021/09/01 00:00:00

PB - Elsevier

SP - 116416

VL - 337

SN - 0167-7322

SN - 1873-3166

ER -

BibTex

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BibTex Copy

@article{2021_Antina,

author = {Elena V Antina and Alexander A Kalyagin and Alexander A Ksenofontov and Olga A Lodochnikova and Daut R. Islamov and Mikhail B Berezin and Lubov A Antina and Roman S Pavelyev and A.L. Ksenofontov and Roman S. Pavelyev and Olga A. Lodochnikova and Mikhail Y. Berezin},

title = {Effect of polar protic solvents on the photophysical properties of bis(BODIPY) dyes},

journal = {Journal of Molecular Liquids},

year = {2021},

volume = {337},

publisher = {Elsevier},

month = {sep},

url = {https://doi.org/10.1016%2Fj.molliq.2021.116416},

pages = {116416},

doi = {10.1016/j.molliq.2021.116416}

}

Found error?

Publisher

Elsevier

Journal

Journal of Molecular Liquids

Quartile SCImago

Quartile WOS

Impact factor

ISSN

01677322 (Print)
18733166 (Electronic)

Labs

Chemistry and molecular photonics of dipyrromethene dyes and phosphors

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