Bifunctional terpyridine/ o -hydroxyimine chemosensors
Evgenii N Shepelenko
1
,
Vitaly A Podshibyakin
2
,
Yurii V Revinskii
1
,
Karina S Tikhomirova
2
,
Leonid D. Popov
3
,
A D Dubonosov
1
,
V A Bren
2
,
V. I. Minkin
1, 4
1
Publication type: Journal Article
Publication date: 2018-02-01
scimago Q2
wos Q2
SJR: 0.628
CiteScore: 8.0
Impact factor: 4.7
ISSN: 00222860, 18728014
Organic Chemistry
Inorganic Chemistry
Spectroscopy
Analytical Chemistry
Abstract
Terpyridines containing substituted o-iminophenolic groups were synthesized. The obtained compounds possess two emission bands: with normal (at 480–495 nm) and anomalous Stokes shifts (at 509–569 nm) generated by the fast intramolecular O→N proton transfer in the singlet excited state (ESIPT effect). They represent bifunctional chromogenic “naked-eye” chemosensors for Cu2+ and Ni2+ due to their complexation with o-hydroxyimine fragment (change of the solution color from colorless to bright yellow) and for Fe2+ - due to complexation with the terpyridine moiety (colorless to violet).
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Citations from 2025:
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GOST
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Shepelenko E. N. et al. Bifunctional terpyridine/ o -hydroxyimine chemosensors // Journal of Molecular Structure. 2018. Vol. 1154. pp. 219-224.
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Shepelenko E. N., Podshibyakin V. A., Revinskii Y. V., Tikhomirova K. S., Popov L. D., Dubonosov A. D., Shcherbakov I. N., Bren V. A., Minkin V. I. Bifunctional terpyridine/ o -hydroxyimine chemosensors // Journal of Molecular Structure. 2018. Vol. 1154. pp. 219-224.
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RIS
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TY - JOUR
DO - 10.1016/j.molstruc.2017.09.069
UR - https://doi.org/10.1016/j.molstruc.2017.09.069
TI - Bifunctional terpyridine/ o -hydroxyimine chemosensors
T2 - Journal of Molecular Structure
AU - Shepelenko, Evgenii N
AU - Podshibyakin, Vitaly A
AU - Revinskii, Yurii V
AU - Tikhomirova, Karina S
AU - Popov, Leonid D.
AU - Dubonosov, A D
AU - Shcherbakov, Igor N.
AU - Bren, V A
AU - Minkin, V. I.
PY - 2018
DA - 2018/02/01
PB - Elsevier
SP - 219-224
VL - 1154
SN - 0022-2860
SN - 1872-8014
ER -
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BibTex (up to 50 authors)
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@article{2018_Shepelenko,
author = {Evgenii N Shepelenko and Vitaly A Podshibyakin and Yurii V Revinskii and Karina S Tikhomirova and Leonid D. Popov and A D Dubonosov and Igor N. Shcherbakov and V A Bren and V. I. Minkin},
title = {Bifunctional terpyridine/ o -hydroxyimine chemosensors},
journal = {Journal of Molecular Structure},
year = {2018},
volume = {1154},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/j.molstruc.2017.09.069},
pages = {219--224},
doi = {10.1016/j.molstruc.2017.09.069}
}