One-step plasma electrochemical synthesis and oxygen electrocatalysis of nanocomposite of few-layer graphene structures with cobalt oxides
Тип публикации: Journal Article
Дата публикации: 2020-09-01
scimago Q1
wos Q1
БС1
SJR: 2.116
CiteScore: 16.7
Impact factor: 8.6
ISSN: 24686069
Materials Science (miscellaneous)
Energy Engineering and Power Technology
Fuel Technology
Nuclear Energy and Engineering
Renewable Energy, Sustainability and the Environment
Краткое описание
One-step synthesis of the nanocomposite of few-layer graphene structures with cobalt oxides was realized using the method of electrochemical exfoliation of graphite. The exfoliation process was carried out in alternating anodic-cathodic plasma mode in 1 M Na2SO4 + 0.01 M CoSO4 solution. Obtained nanocomposite was characterized by scanning and transmission electron microscopy, X-ray photoelectron and Raman spectroscopy. Besides, a catalytic activity of the nanocomposite of few-layer graphene structures with cobalt oxides towards the oxygen reduction reaction was assessed, and a considerable decrease in the oxygen reduction overpotential and an electron transfer number of ca. 3.6 were demonstrated. The observed effect was found to be caused by 40 wt% of cobalt (II) and (III) oxides in the nanocomposite.
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Kotkin A. S. et al. One-step plasma electrochemical synthesis and oxygen electrocatalysis of nanocomposite of few-layer graphene structures with cobalt oxides // Materials Today Energy. 2020. Vol. 17. p. 100459.
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Kotkin A. S., Kochergin V. K., Kabachkov E. N., Shulga Y. M., Lobach A. S., Manzhos R. A., Krivenko A. G. One-step plasma electrochemical synthesis and oxygen electrocatalysis of nanocomposite of few-layer graphene structures with cobalt oxides // Materials Today Energy. 2020. Vol. 17. p. 100459.
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TY - JOUR
DO - 10.1016/j.mtener.2020.100459
UR - https://doi.org/10.1016/j.mtener.2020.100459
TI - One-step plasma electrochemical synthesis and oxygen electrocatalysis of nanocomposite of few-layer graphene structures with cobalt oxides
T2 - Materials Today Energy
AU - Kotkin, Alexander S
AU - Kochergin, V K
AU - Kabachkov, E N
AU - Shulga, Yury M.
AU - Lobach, Anatoly S.
AU - Manzhos, Roman A
AU - Krivenko, A G
PY - 2020
DA - 2020/09/01
PB - Elsevier
SP - 100459
VL - 17
SN - 2468-6069
ER -
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@article{2020_Kotkin,
author = {Alexander S Kotkin and V K Kochergin and E N Kabachkov and Yury M. Shulga and Anatoly S. Lobach and Roman A Manzhos and A G Krivenko},
title = {One-step plasma electrochemical synthesis and oxygen electrocatalysis of nanocomposite of few-layer graphene structures with cobalt oxides},
journal = {Materials Today Energy},
year = {2020},
volume = {17},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016/j.mtener.2020.100459},
pages = {100459},
doi = {10.1016/j.mtener.2020.100459}
}