Materials Today Energy, volume 30, pages 101178

Metal-organic aerogels based on titanium(IV) for visible-light conducted CO2 photoreduction to alcohols

Adrián Angulo-Ibáñez ¹

Maite Perfecto-Irigaray ²

I Merino Garcia ³

Naia Luengo ²

Amaia M Goitandia ¹

Jonathan Albo ³

Estibaliz Aranzabe ¹

Garikoitz Beobide ^{2, 4}

Óscar Castillo ^{2, 4}

Sonia Pérez-Yáñez ^{2, 4}

Hide authors affiliations Show authors affiliations: 4 affiliations

Surface Chemistry & Nanotechnologies Unit, Fdn Tekniker, Iñaki Goenaga 5, Eibar 20600, Spain |

Department of Organic and Inorganic Chemistry, University of the Basque Country, UPV/EHU, P.O. 644, E-48080 Bilbao, Spain |

Departamento de Ingenierías Química y Biomolecular, Universidad de Cantabria, Avda. Los Castros s/n, 39005 Santander, Spain |

⁴

BCMaterials, Basque Center for Materials, Applications and Nanostructures, UPV/EHU Science Park, 48940 Leioa, Spain |

Publication type: Journal Article

Publication date: 2022-12-01

Elsevier

Journal: Materials Today Energy

Quartile SCImago

Quartile WOS

Impact factor: 9.3

ISSN: 24686069, 24686069

DOI: 10.1016/j.mtener.2022.101178

Copy DOI

Materials Science (miscellaneous)

Energy Engineering and Power Technology

Fuel Technology

Nuclear Energy and Engineering

Renewable Energy, Sustainability and the Environment

Abstract

Metal-organic frameworks (MOFs) imply an appealing source of photocatalysts, as they combine porosity with tailorable electronic properties and surface chemistry. Herein we report a series of unprecedented metal-organic aerogels (MOAs) comprised by Ti(IV) oxo-clusters and aromatic dicarboxylic linkers as an alternative to microporous MIL-125 and MIL-125-NH 2 MOFs. Discrete titanium oxo-clusters polymerized upon the addition of the dicarboxylic linkers to give rise to a metal-organic gel. Their supercritical drying led to aerogels comprised by nanoscopic particles ( ca . 5–10 nm) cross-linked into a meso/macroporous microstructure with surface area ranging from 453 to 617 m 2 ·g –1 , which are comparatively lower than the surface area of the microporous counterparts (1336 and 1145 m 2 ·g –1 , respectively). However, the meso/macroporous microstructure of MOAs can provide a more fluent diffusion of reagents and products than the intrinsic porosity of MOFs, whose narrower channels are expected to imply a more sluggish mass transport. In fact, the assessment of the continuous visible-light driven photocatalytic CO 2 reduction into methanol shows that MOAs (221–786 μmol·g –1 ·h –1 ) far exceed the performance of their microporous counterparts (49–65 μmol·g –1 ·h –1 ), but also surpass the production rates provided by up-to-date reported photocatalysts. • Novel metal-organic aerogels based on titanium(IV) are presented. • These materials photocatalyse CO2 conversion under visible-light illumination. • The methanol production rates surpass up-to-date reported photocatalysts.

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Top-30

Citations by journals

	1 2
Energy & Fuels	Energy & Fuels, 2, 8.7% Energy & Fuels 2 publications, 8.7%
Journal of the American Chemical Society	Journal of the American Chemical Society, 2, 8.7% Journal of the American Chemical Society 2 publications, 8.7%
Dalton Transactions	Dalton Transactions, 2, 8.7% Dalton Transactions 2 publications, 8.7%
ChemSusChem	ChemSusChem, 2, 8.7% ChemSusChem 2 publications, 8.7%
RSC Sustainability	RSC Sustainability, 1, 4.35% RSC Sustainability 1 publication, 4.35%
ACS Applied Energy Materials	ACS Applied Energy Materials, 1, 4.35% ACS Applied Energy Materials 1 publication, 4.35%
Advanced Energy Materials	Advanced Energy Materials, 1, 4.35% Advanced Energy Materials 1 publication, 4.35%
Energy Sources, Part A: Recovery, Utilization and Environmental Effects	Energy Sources, Part A: Recovery, Utilization and Environmental Effects, 1, 4.35% Energy Sources, Part A: Recovery, Utilization and Environmental Effects 1 publication, 4.35%
Small	Small, 1, 4.35% Small 1 publication, 4.35%
ACS Sustainable Chemistry and Engineering	ACS Sustainable Chemistry and Engineering, 1, 4.35% ACS Sustainable Chemistry and Engineering 1 publication, 4.35%
Catalysis Science and Technology	Catalysis Science and Technology, 1, 4.35% Catalysis Science and Technology 1 publication, 4.35%
Journal of Cluster Science	Journal of Cluster Science, 1, 4.35% Journal of Cluster Science 1 publication, 4.35%
Russian Chemical Reviews	Russian Chemical Reviews, 1, 4.35% Russian Chemical Reviews 1 publication, 4.35%
Materials for Renewable and Sustainable Energy	Materials for Renewable and Sustainable Energy, 1, 4.35% Materials for Renewable and Sustainable Energy 1 publication, 4.35%
Materials Today Energy	Materials Today Energy, 1, 4.35% Materials Today Energy 1 publication, 4.35%
Fuel	Fuel, 1, 4.35% Fuel 1 publication, 4.35%
EnergyChem	EnergyChem, 1, 4.35% EnergyChem 1 publication, 4.35%
Applied Catalysis B: Environmental	Applied Catalysis B: Environmental, 1, 4.35% Applied Catalysis B: Environmental 1 publication, 4.35%
Chinese Journal of Chemistry	Chinese Journal of Chemistry, 1, 4.35% Chinese Journal of Chemistry 1 publication, 4.35%
	1 2

Citations by publishers

	1 2 3 4 5 6
American Chemical Society (ACS)	American Chemical Society (ACS), 6, 26.09% American Chemical Society (ACS) 6 publications, 26.09%
Wiley	Wiley, 5, 21.74% Wiley 5 publications, 21.74%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 4, 17.39% Royal Society of Chemistry (RSC) 4 publications, 17.39%
Elsevier	Elsevier, 4, 17.39% Elsevier 4 publications, 17.39%
Springer Nature	Springer Nature, 2, 8.7% Springer Nature 2 publications, 8.7%
Taylor & Francis	Taylor & Francis, 1, 4.35% Taylor & Francis 1 publication, 4.35%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 4.35% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 4.35%
	1 2 3 4 5 6

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Angulo-Ibáñez A. et al. Metal-organic aerogels based on titanium(IV) for visible-light conducted CO2 photoreduction to alcohols // Materials Today Energy. 2022. Vol. 30. p. 101178.

GOST all authors (up to 50) Copy

Angulo-Ibáñez A., Perfecto-Irigaray M., Merino Garcia I., Luengo N., Goitandia A. M., Albo J., Aranzabe E., Beobide G., Castillo Ó., Pérez-Yáñez S. Metal-organic aerogels based on titanium(IV) for visible-light conducted CO2 photoreduction to alcohols // Materials Today Energy. 2022. Vol. 30. p. 101178.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.mtener.2022.101178

UR - https://doi.org/10.1016/j.mtener.2022.101178

TI - Metal-organic aerogels based on titanium(IV) for visible-light conducted CO2 photoreduction to alcohols

T2 - Materials Today Energy

AU - Angulo-Ibáñez, Adrián

AU - Perfecto-Irigaray, Maite

AU - Merino Garcia, I

AU - Luengo, Naia

AU - Goitandia, Amaia M

AU - Albo, Jonathan

AU - Aranzabe, Estibaliz

AU - Beobide, Garikoitz

AU - Castillo, Óscar

AU - Pérez-Yáñez, Sonia

PY - 2022

DA - 2022/12/01 00:00:00

PB - Elsevier

SP - 101178

VL - 30

SN - 2468-6069

ER -

BibTex

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BibTex Copy

@article{2022_Angulo-Ibáñez,

author = {Adrián Angulo-Ibáñez and Maite Perfecto-Irigaray and I Merino Garcia and Naia Luengo and Amaia M Goitandia and Jonathan Albo and Estibaliz Aranzabe and Garikoitz Beobide and Óscar Castillo and Sonia Pérez-Yáñez},

title = {Metal-organic aerogels based on titanium(IV) for visible-light conducted CO2 photoreduction to alcohols},

journal = {Materials Today Energy},

year = {2022},

volume = {30},

publisher = {Elsevier},

month = {dec},

url = {https://doi.org/10.1016/j.mtener.2022.101178},

pages = {101178},

doi = {10.1016/j.mtener.2022.101178}

}

Found error?

Publisher

Elsevier

Journal

Materials Today Energy

Quartile SCImago

Quartile WOS

Impact factor

9.3

ISSN

24686069 (Electronic)
24686069 (Print)