Nano Energy, volume 31, pages 478-485
Natural halloysite nano-clay electrolyte for advanced all-solid-state lithium-sulfur batteries
Publication type: Journal Article
Publication date: 2017-01-01
General Materials Science
Electrical and Electronic Engineering
Renewable Energy, Sustainability and the Environment
Abstract
Solid polymer electrolytes (SPEs) show increasing potential for application in high energy lithium sulfur batteries due to good flexibility and high safety. However, low room temperature ionic conductivity of SPEs has become the main limitation. Herein, a novel SPE film using natural halloysite nano-clay has been fabricated, which exhibits exceptional ionic conductivity of 1.11×10−4 S cm−1 and lithium ion transference number of 0.40 at 25 °C. The mechanism of enhanced lithium ion transport is considered. The oppositely charged halloysite nanotube surfaces separate lithium salt into lithium ions that are absorbed on the negatively charged outer silica surface, and anions may be accommodated on the positively charged inner aluminol surface. So, an ordered 3D structure for free lithium ion transport is suggested. This potential application of the natural halloysite nano-clay has been demonstrated by an all-solid-state lithium-sulfur battery over a wide temperature range of 25–100 °C. These results reveal the possibility of realizing sustainable high energy storage at a reduced cost.
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- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
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Lin Y. et al. Natural halloysite nano-clay electrolyte for advanced all-solid-state lithium-sulfur batteries // Nano Energy. 2017. Vol. 31. pp. 478-485.
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Lin Y., Wang X., Liu J., Miller J. D. Natural halloysite nano-clay electrolyte for advanced all-solid-state lithium-sulfur batteries // Nano Energy. 2017. Vol. 31. pp. 478-485.
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TY - JOUR
DO - 10.1016/j.nanoen.2016.11.045
UR - https://doi.org/10.1016/j.nanoen.2016.11.045
TI - Natural halloysite nano-clay electrolyte for advanced all-solid-state lithium-sulfur batteries
T2 - Nano Energy
AU - Lin, Yue
AU - Wang, Xuming
AU - Liu, Jin
AU - Miller, Jan D
PY - 2017
DA - 2017/01/01 00:00:00
PB - Elsevier
SP - 478-485
VL - 31
SN - 2211-2855
ER -
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@article{2017_Lin,
author = {Yue Lin and Xuming Wang and Jin Liu and Jan D Miller},
title = {Natural halloysite nano-clay electrolyte for advanced all-solid-state lithium-sulfur batteries},
journal = {Nano Energy},
year = {2017},
volume = {31},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/j.nanoen.2016.11.045},
pages = {478--485},
doi = {10.1016/j.nanoen.2016.11.045}
}