Nano Energy, volume 48, pages 35-43
Boosting the performance of lithium batteries with solid-liquid hybrid electrolytes: Interfacial properties and effects of liquid electrolytes
Changhong Wang
1
,
Qian Sun
1
,
Yulong Liu
1
,
Yang Zhao
1
,
Xiaona Li
1
,
Xiaoting Lin
1
,
Mohammad Norouzi Banis
1
,
Minsi Li
1
,
Weihan Li
1
,
Keegan Adair
1
,
Dawei Wang
1
,
Jianneng Liang
1
,
Ruying Li
1
,
Li Zhang
2
,
Rong Yang
2
,
Shigang Lu
2
,
Xuhui Sun
1
1
Department of Mechanical and Materials Engineering, University of Western Ontario, 1151 Richmond St., London, Ontario, Canada N6A 3K7
|
2
China Automotive Battery Research Institute Co., Ltd., 5th Floor, No. 43, Mining Building, North Sanhuan Middle Road, Haidian District, Beijing 100088, China
|
Publication type: Journal Article
Publication date: 2018-06-01
General Materials Science
Electrical and Electronic Engineering
Renewable Energy, Sustainability and the Environment
Abstract
Solid-state lithium batteries have attracted significant attention recently due to their superior safety and energy density. Nevertheless, the large interfacial resistance has limited the development of SSLBs. To tackle this problem, a general strategy is to add liquid electrolytes (LE) at the interface to form a solid-liquid hybrid electrolyte. However, the effects and interfacial properties of LE in the solid-liquid hybrid electrolyte have not been well-understood. In this work, we quantitatively add LE at the interface to eliminate the large interfacial resistance and study its interfacial properties. As little as 2 µL of LE at the interface enables a hybrid LiFePO4/LATP/Li battery to deliver a specific capacity of 125 mA h g−1 at 1 C and 98 mA h g−1 at 4 C. Excess LE has no further contribution to the electrochemical performance. Furthermore, the rigid SSE could suppress the formation of lithium dendrites, especially in the case with a high cathode loading (9.1 mg/cm2), suggesting the feasibility of high energy density SSLBs using Li metal anodes. The interfacial analysis reveals that an interfacial solid-liquid electrolyte interphase (SLEI) was formed at the interface, preventing the reduction of LATP by Li metal, thus ensuring the long-term durability of LATP in LE.
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Wang C. et al. Boosting the performance of lithium batteries with solid-liquid hybrid electrolytes: Interfacial properties and effects of liquid electrolytes // Nano Energy. 2018. Vol. 48. pp. 35-43.
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Wang C., Sun Q., Liu Y., Zhao Y., Li X., Lin X., Norouzi Banis M., Li M., Li W., Adair K., Wang D., Liang J., Li R., Zhang L., Yang R., Lu S., Sun X. Boosting the performance of lithium batteries with solid-liquid hybrid electrolytes: Interfacial properties and effects of liquid electrolytes // Nano Energy. 2018. Vol. 48. pp. 35-43.
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TY - JOUR
DO - 10.1016/j.nanoen.2018.03.020
UR - https://doi.org/10.1016/j.nanoen.2018.03.020
TI - Boosting the performance of lithium batteries with solid-liquid hybrid electrolytes: Interfacial properties and effects of liquid electrolytes
T2 - Nano Energy
AU - Wang, Changhong
AU - Sun, Qian
AU - Liu, Yulong
AU - Zhao, Yang
AU - Li, Xiaona
AU - Lin, Xiaoting
AU - Norouzi Banis, Mohammad
AU - Li, Minsi
AU - Li, Weihan
AU - Adair, Keegan
AU - Wang, Dawei
AU - Liang, Jianneng
AU - Li, Ruying
AU - Zhang, Li
AU - Yang, Rong
AU - Lu, Shigang
AU - Sun, Xuhui
PY - 2018
DA - 2018/06/01 00:00:00
PB - Elsevier
SP - 35-43
VL - 48
SN - 2211-2855
ER -
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@article{2018_Wang,
author = {Changhong Wang and Qian Sun and Yulong Liu and Yang Zhao and Xiaona Li and Xiaoting Lin and Mohammad Norouzi Banis and Minsi Li and Weihan Li and Keegan Adair and Dawei Wang and Jianneng Liang and Ruying Li and Li Zhang and Rong Yang and Shigang Lu and Xuhui Sun},
title = {Boosting the performance of lithium batteries with solid-liquid hybrid electrolytes: Interfacial properties and effects of liquid electrolytes},
journal = {Nano Energy},
year = {2018},
volume = {48},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016/j.nanoen.2018.03.020},
pages = {35--43},
doi = {10.1016/j.nanoen.2018.03.020}
}