Nano Energy, volume 60, pages 205-212
Rechargeable solid-state lithium metal batteries with vertically aligned ceramic nanoparticle/polymer composite electrolyte
Xue Wang
,
Haowei Zhai
,
Boyu Qie
,
Cheng Qian
,
Aijun Li
,
James Borovilas
,
Bingqing Xu
,
Changmin Shi
,
Tianwei Jin
,
Xiangbiao Liao
,
Li Yibin
,
Xiaodong He
,
Shanyi Du
,
Yanke Fu
,
Martin Dontigny
,
Karim Zaghib
,
Yang Yuan
Publication type: Journal Article
Publication date: 2019-06-01
General Materials Science
Electrical and Electronic Engineering
Renewable Energy, Sustainability and the Environment
Abstract
Composite solid electrolytes are attractive as they combine the high ionic conductivity of ceramic nanoparticles and the excellent mechanical properties of polymer electrolytes. Vertically aligned ceramic nanoparticles in the polymer matrix represent an ideal structure for maximizing ionic conductivity of composite electrolytes. The ice-templating method was used to build rechargeable solid-state lithium metal batteries with a vertically aligned ceramic/polymer composite electrolyte composed of high ionic conductivity Li1.5Al0.5Ge1.5(PO4)3 (LAGP) and polyethylene oxide (PEO) polymer. The vertical LAGP walls provide continuous channels for fast ionic transport, while the PEO matrix renders the composite electrolyte flexible. This solid-state composite electrolyte has a conductivity of 1.67 × 10−4 S cm−1 at room temperature and 1.11 × 10−3 S cm−1 at 60 °C. LiFePO4 (LFP)/vertically aligned LAGP- PEO/Li full cells were also developed with a high capacity retention of 93.3% after 300 cycles. This study demonstrates the successful application of vertically aligned ceramic/polymer composite electrolytes for solid-state batteries with high performance.
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Citations by publishers
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
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Wang X. et al. Rechargeable solid-state lithium metal batteries with vertically aligned ceramic nanoparticle/polymer composite electrolyte // Nano Energy. 2019. Vol. 60. pp. 205-212.
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Wang X., Zhai H., Qie B., Qian C., Li A., Borovilas J., Xu B., Shi C., Jin T., Liao X., Yibin L., He X., Du S., Fu Y., Dontigny M., Zaghib K., Yuan Y. Rechargeable solid-state lithium metal batteries with vertically aligned ceramic nanoparticle/polymer composite electrolyte // Nano Energy. 2019. Vol. 60. pp. 205-212.
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TY - JOUR
DO - 10.1016/j.nanoen.2019.03.051
UR - https://doi.org/10.1016/j.nanoen.2019.03.051
TI - Rechargeable solid-state lithium metal batteries with vertically aligned ceramic nanoparticle/polymer composite electrolyte
T2 - Nano Energy
AU - Wang, Xue
AU - Zhai, Haowei
AU - Qie, Boyu
AU - Qian, Cheng
AU - Li, Aijun
AU - Borovilas, James
AU - Xu, Bingqing
AU - Shi, Changmin
AU - Jin, Tianwei
AU - Liao, Xiangbiao
AU - Yibin, Li
AU - He, Xiaodong
AU - Du, Shanyi
AU - Fu, Yanke
AU - Dontigny, Martin
AU - Zaghib, Karim
AU - Yuan, Yang
PY - 2019
DA - 2019/06/01 00:00:00
PB - Elsevier
SP - 205-212
VL - 60
SN - 2211-2855
ER -
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@article{2019_Wang,
author = {Xue Wang and Haowei Zhai and Boyu Qie and Cheng Qian and Aijun Li and James Borovilas and Bingqing Xu and Changmin Shi and Tianwei Jin and Xiangbiao Liao and Li Yibin and Xiaodong He and Shanyi Du and Yanke Fu and Martin Dontigny and Karim Zaghib and Yang Yuan},
title = {Rechargeable solid-state lithium metal batteries with vertically aligned ceramic nanoparticle/polymer composite electrolyte},
journal = {Nano Energy},
year = {2019},
volume = {60},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016/j.nanoen.2019.03.051},
pages = {205--212},
doi = {10.1016/j.nanoen.2019.03.051}
}