Nano Energy, volume 79, pages 105475

Nanocomposite with fast Li+ conducting percolation network: Solid polymer electrolyte with Li+ non-conducting filler

Xin Ao

Xiaotao Wang

Jiewen Tan ¹

Shaolong Zhang

Chenliang Su

Lei Dong ²

Yan-Yan HU ³

Zhongchang Wang ⁴

Bingbing Tian

Haihui Wang ¹

Hide authors affiliations Show authors affiliations: 4 affiliations

School of Chemistry and Chemical Engineering, South China University of Technology , Guangzhou, 510640, China. |

School of Physical Science and Technology, ShanghaiTech University - Shanghai 201210, China |

Center for High Pressure Science and Technology Advanced Research, Beijing 100094, China |

⁴

Department of Quantum and Energy Materials, International Iberian Nanotechnology Laboratory (INL), Braga 4715-330, Portugal |

Publication type: Journal Article

Publication date: 2021-01-01

Elsevier

Journal: Nano Energy

Quartile SCImago

Quartile WOS

Impact factor: 17.6

ISSN: 22112855

DOI: 10.1016/j.nanoen.2020.105475

Copy DOI

General Materials Science

Electrical and Electronic Engineering

Renewable Energy, Sustainability and the Environment

Abstract

Solid polymer electrolytes (SPEs) have attracted considerable research interest because they are expected to solve the safety problems caused by the liquid electrolytes. However, the low ionic conductivity limits their practical applications. Constructing Li + fast conducting network in SPEs with Li + highly conducting ceramic fillers following the mixed matrix membrane concept have shown their limits in raising the Li + conductivity. Herein, a new strategy using Li + non-conducting fillers like CeO 2 nanowires, is proposed to construct a Li + fast conducting network through SPEs. CeO 2 nanowires can dissociate LiTFSI, which results in a high Li + conductivity through the SPEs near to the fiber surface. This experimental finding is confirmed by analytics (FT-IR, Raman and NMR) and theoretical calculations (DFT-MD and COHP). As a result, the network of interwoven CeO 2 nanowires helps form a continuous Li + fast conducting percolation network through the SPEs. The ionic conductivity of the composite SPEs with 10 wt% CeO 2 nanowires is greatly improved (1.1 × 10 −3 S cm −1 at 60 °C). The Li symmetric cells with this composite electrolyte exhibit good cyclic stability (without short circuiting after 2000 h), and the all-solid-state LiFePO 4 /Li cells present a superior cycling performance (remained 140 mA h g −1 after 100 cycles at 1 C). • Li + non-conducting nanofillers are used to construct Li + fast conducting network. • Dissociation process of LiTFSI on the CeO 2 surface is theoretically simulated. • Novel mechanism for the enhancement of Li + conductivity is proposed.

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Citations by journals

	1 2 3 4 5 6 7
Energy Storage Materials	Energy Storage Materials, 7, 9.09% Energy Storage Materials 7 publications, 9.09%
Chemical Engineering Journal	Chemical Engineering Journal, 5, 6.49% Chemical Engineering Journal 5 publications, 6.49%
Advanced Energy Materials	Advanced Energy Materials, 4, 5.19% Advanced Energy Materials 4 publications, 5.19%
Journal of Energy Chemistry	Journal of Energy Chemistry, 4, 5.19% Journal of Energy Chemistry 4 publications, 5.19%
Journal of Colloid and Interface Science	Journal of Colloid and Interface Science, 3, 3.9% Journal of Colloid and Interface Science 3 publications, 3.9%
Science China Materials	Science China Materials, 2, 2.6% Science China Materials 2 publications, 2.6%
Colloids and Surfaces A: Physicochemical and Engineering Aspects	Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2, 2.6% Colloids and Surfaces A: Physicochemical and Engineering Aspects 2 publications, 2.6%
Chemical Communications	Chemical Communications, 2, 2.6% Chemical Communications 2 publications, 2.6%
Journal of Materials Chemistry A	Journal of Materials Chemistry A, 2, 2.6% Journal of Materials Chemistry A 2 publications, 2.6%
Advanced Materials	Advanced Materials, 2, 2.6% Advanced Materials 2 publications, 2.6%
Materials Chemistry Frontiers	Materials Chemistry Frontiers, 2, 2.6% Materials Chemistry Frontiers 2 publications, 2.6%
Small	Small, 1, 1.3% Small 1 publication, 1.3%
Journal of the Electrochemical Society	Journal of the Electrochemical Society, 1, 1.3% Journal of the Electrochemical Society 1 publication, 1.3%
Ionics	Ionics, 1, 1.3% Ionics 1 publication, 1.3%
Nano-Micro Letters	Nano-Micro Letters, 1, 1.3% Nano-Micro Letters 1 publication, 1.3%
Chinese Journal of Chemical Engineering	Chinese Journal of Chemical Engineering, 1, 1.3% Chinese Journal of Chemical Engineering 1 publication, 1.3%
Materials Today	Materials Today, 1, 1.3% Materials Today 1 publication, 1.3%
Chinese Chemical Letters	Chinese Chemical Letters, 1, 1.3% Chinese Chemical Letters 1 publication, 1.3%
Electrochimica Acta	Electrochimica Acta, 1, 1.3% Electrochimica Acta 1 publication, 1.3%
Chemistry - An Asian Journal	Chemistry - An Asian Journal, 1, 1.3% Chemistry - An Asian Journal 1 publication, 1.3%
ChemNanoMat	ChemNanoMat, 1, 1.3% ChemNanoMat 1 publication, 1.3%
Advanced Functional Materials	Advanced Functional Materials, 1, 1.3% Advanced Functional Materials 1 publication, 1.3%
Energy & Environmental Materials	Energy & Environmental Materials, 1, 1.3% Energy & Environmental Materials 1 publication, 1.3%
Advanced Science	Advanced Science, 1, 1.3% Advanced Science 1 publication, 1.3%
Chinese Journal of Chemistry	Chinese Journal of Chemistry, 1, 1.3% Chinese Journal of Chemistry 1 publication, 1.3%
ACS applied materials & interfaces	ACS applied materials & interfaces, 1, 1.3% ACS applied materials & interfaces 1 publication, 1.3%
ACS Energy Letters	ACS Energy Letters, 1, 1.3% ACS Energy Letters 1 publication, 1.3%
Energy and Environmental Science	Energy and Environmental Science, 1, 1.3% Energy and Environmental Science 1 publication, 1.3%
Materials Advances	Materials Advances, 1, 1.3% Materials Advances 1 publication, 1.3%
Pure and Applied Chemistry	Pure and Applied Chemistry, 1, 1.3% Pure and Applied Chemistry 1 publication, 1.3%
	1 2 3 4 5 6 7

Citations by publishers

	5 10 15 20 25 30 35 40
Elsevier	Elsevier, 36, 46.75% Elsevier 36 publications, 46.75%
Wiley	Wiley, 16, 20.78% Wiley 16 publications, 20.78%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 9, 11.69% Royal Society of Chemistry (RSC) 9 publications, 11.69%
Springer Nature	Springer Nature, 6, 7.79% Springer Nature 6 publications, 7.79%
American Chemical Society (ACS)	American Chemical Society (ACS), 5, 6.49% American Chemical Society (ACS) 5 publications, 6.49%
The Electrochemical Society	The Electrochemical Society, 1, 1.3% The Electrochemical Society 1 publication, 1.3%
Chemical Industry Press	Chemical Industry Press, 1, 1.3% Chemical Industry Press 1 publication, 1.3%
Walter de Gruyter	Walter de Gruyter, 1, 1.3% Walter de Gruyter 1 publication, 1.3%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 1.3% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 1.3%
Taylor & Francis	Taylor & Francis, 1, 1.3% Taylor & Francis 1 publication, 1.3%
	5 10 15 20 25 30 35 40

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Ao X. et al. Nanocomposite with fast Li+ conducting percolation network: Solid polymer electrolyte with Li+ non-conducting filler // Nano Energy. 2021. Vol. 79. p. 105475.

GOST all authors (up to 50) Copy

Ao X., Wang X., Tan J., Zhang S., Su C., Dong L., HU Y., Wang Z., Tian B., Wang H. Nanocomposite with fast Li+ conducting percolation network: Solid polymer electrolyte with Li+ non-conducting filler // Nano Energy. 2021. Vol. 79. p. 105475.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.nanoen.2020.105475

UR - https://doi.org/10.1016/j.nanoen.2020.105475

TI - Nanocomposite with fast Li+ conducting percolation network: Solid polymer electrolyte with Li+ non-conducting filler

T2 - Nano Energy

AU - Ao, Xin

AU - Wang, Xiaotao

AU - Tan, Jiewen

AU - Zhang, Shaolong

AU - Su, Chenliang

AU - Dong, Lei

AU - HU, Yan-Yan

AU - Wang, Zhongchang

AU - Tian, Bingbing

AU - Wang, Haihui

PY - 2021

DA - 2021/01/01 00:00:00

PB - Elsevier

SP - 105475

VL - 79

SN - 2211-2855

ER -

BibTex

Cite this

BibTex Copy

@article{2021_Ao,

author = {Xin Ao and Xiaotao Wang and Jiewen Tan and Shaolong Zhang and Chenliang Su and Lei Dong and Yan-Yan HU and Zhongchang Wang and Bingbing Tian and Haihui Wang},

title = {Nanocomposite with fast Li+ conducting percolation network: Solid polymer electrolyte with Li+ non-conducting filler},

journal = {Nano Energy},

year = {2021},

volume = {79},

publisher = {Elsevier},

month = {jan},

url = {https://doi.org/10.1016/j.nanoen.2020.105475},

pages = {105475},

doi = {10.1016/j.nanoen.2020.105475}

}

Found error?

Publisher

Elsevier

Journal

Nano Energy

Quartile SCImago

Quartile WOS

Impact factor

17.6

ISSN

22112855 (Print)