Nano Energy, volume 90, pages 106490

Local electric field effect of montmorillonite in solid polymer electrolytes for lithium metal batteries

Yong Wang ¹

李新阳 Li Xinyang ²

Yanyang Qin ²

Dongyang Zhang ²

Zhongxiao Song ³

Junlei Qi ⁴

Hide authors affiliations Show authors affiliations: 4 affiliations

State Key Laboratory for Mechanical Behaviour of Materials, Xi'an Jiaotong University, Xi'an 710049, China |

School of Chemistry, Xi'an Key Laboratory of Sustainable Energy Materials Chemistry,t, Xi'an Jiaotong University, Xi'an 710049, China |

State Key Laboratory for Mechanical Behaviour of Materials, Xi'an Jiaotong University, Xi'an 710049, China |

⁴

Shenzhen Research School of Xi'an Jiaotong University, Shenzhen 518057, China |

Publication type: Journal Article

Publication date: 2021-12-01

Elsevier

Journal: Nano Energy

Quartile SCImago

Quartile WOS

Impact factor: 17.6

ISSN: 22112855

DOI: 10.1016/j.nanoen.2021.106490

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General Materials Science

Electrical and Electronic Engineering

Renewable Energy, Sustainability and the Environment

Abstract

Solid polymer electrolytes (SPEs) with in-built inorganic fillers are very promising for building safe solid-state batteries, owing to their excellent flexibility, prominent interfacial wettability and low costs. However, the morphology and surface state of inorganic fillers greatly affect ionic conductivity of SPEs. Here, we report that ultraviolet (UV) initiates in situ cross-linking of poly(ethylene glycol) methyl ether acrylate (MPEGA), poly(ethylene glycol) diacrylate (PEGDA) and montmorillonite (MMT) between cathodes and anodes of cell, to produce a solid composite electrolyte (CMP/MMT) that is composed of a robust interpenetrating polymer network matrix and layered MMT nanosheets. Surprisingly, the CMP/MMT delivers a high room-temperature ionic conductivity (~1.06 mS cm −1 ), large lithium-ions transference number (t Li+ = 0.79). The large ionic conductivity enhancement is ascribed to the local electric field effect of montmorillonite (MMT), which accelerates the lithium-ions fast transport in the interlayer of the MMT nanosheets. In addition, the density functional theory (DFT) is conducted to demonstrate the mechanism of improving ionic conductivity. As a result, a solid-state battery with CMP/MMT demonstrates a high capacity of ~140 mAh g −1 and excellent capacity retention of >98% at 0.3 C after 400 cycling. • A solid composite electrolyte (CMP/MMT) is prepared by in situ cross-linking of liquid precursor between cathodes and anodes of cell. • The CMP/MMT delivers a high room-temperature ionic conductivity (~1.06 mS cm −1 ) and large lithium-ions transference number (t Li+ = 0.79). • The DFT demonstrated that the MMT assists in accelerating the dissociation of lithium salts and provides a “highway” for Li + fast transport by local electric field effect. • A solid-state battery with CMP/MMT demonstrates a high capacity of ~140 mAh g −1 and excellent capacity retention of >98% at 0.3 C after 400 cycling.

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Citations by journals

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Chemical Engineering Journal	Chemical Engineering Journal, 7, 15.22% Chemical Engineering Journal 7 publications, 15.22%
Journal of Colloid and Interface Science	Journal of Colloid and Interface Science, 4, 8.7% Journal of Colloid and Interface Science 4 publications, 8.7%
Journal of Materials Chemistry A	Journal of Materials Chemistry A, 3, 6.52% Journal of Materials Chemistry A 3 publications, 6.52%
Small	Small, 2, 4.35% Small 2 publications, 4.35%
Nano-Micro Letters	Nano-Micro Letters, 2, 4.35% Nano-Micro Letters 2 publications, 4.35%
Journal of Power Sources	Journal of Power Sources, 2, 4.35% Journal of Power Sources 2 publications, 4.35%
ACS Applied Energy Materials	ACS Applied Energy Materials, 2, 4.35% ACS Applied Energy Materials 2 publications, 4.35%
Advanced Functional Materials	Advanced Functional Materials, 2, 4.35% Advanced Functional Materials 2 publications, 4.35%
Advanced Energy Materials	Advanced Energy Materials, 2, 4.35% Advanced Energy Materials 2 publications, 4.35%
Energy Storage Materials	Energy Storage Materials, 2, 4.35% Energy Storage Materials 2 publications, 4.35%
Journal of Energy Storage	Journal of Energy Storage, 2, 4.35% Journal of Energy Storage 2 publications, 4.35%
Matter	Matter, 1, 2.17% Matter 1 publication, 2.17%
Colloids and Surfaces A: Physicochemical and Engineering Aspects	Colloids and Surfaces A: Physicochemical and Engineering Aspects, 1, 2.17% Colloids and Surfaces A: Physicochemical and Engineering Aspects 1 publication, 2.17%
Chemical Record	Chemical Record, 1, 2.17% Chemical Record 1 publication, 2.17%
Energy & Fuels	Energy & Fuels, 1, 2.17% Energy & Fuels 1 publication, 2.17%
Carbon Energy	Carbon Energy, 1, 2.17% Carbon Energy 1 publication, 2.17%
ACS applied materials & interfaces	ACS applied materials & interfaces, 1, 2.17% ACS applied materials & interfaces 1 publication, 2.17%
ChemPlusChem	ChemPlusChem, 1, 2.17% ChemPlusChem 1 publication, 2.17%
Interdisciplinary Materials	Interdisciplinary Materials, 1, 2.17% Interdisciplinary Materials 1 publication, 2.17%
Sustainable Materials and Technologies	Sustainable Materials and Technologies, 1, 2.17% Sustainable Materials and Technologies 1 publication, 2.17%
Green Chemistry	Green Chemistry, 1, 2.17% Green Chemistry 1 publication, 2.17%
Journal of Physical Chemistry Letters	Journal of Physical Chemistry Letters, 1, 2.17% Journal of Physical Chemistry Letters 1 publication, 2.17%
Applied Clay Science	Applied Clay Science, 1, 2.17% Applied Clay Science 1 publication, 2.17%
ACS Nano	ACS Nano, 1, 2.17% ACS Nano 1 publication, 2.17%
eScience	eScience, 1, 2.17% eScience 1 publication, 2.17%
Rare Metals	Rare Metals, 1, 2.17% Rare Metals 1 publication, 2.17%
Russian Chemical Reviews	Russian Chemical Reviews, 1, 2.17% Russian Chemical Reviews 1 publication, 2.17%
	1 2 3 4 5 6 7

Citations by publishers

	5 10 15 20 25
Elsevier	Elsevier, 22, 47.83% Elsevier 22 publications, 47.83%
Wiley	Wiley, 10, 21.74% Wiley 10 publications, 21.74%
American Chemical Society (ACS)	American Chemical Society (ACS), 6, 13.04% American Chemical Society (ACS) 6 publications, 13.04%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 4, 8.7% Royal Society of Chemistry (RSC) 4 publications, 8.7%
Springer Nature	Springer Nature, 3, 6.52% Springer Nature 3 publications, 6.52%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 2.17% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 2.17%
	5 10 15 20 25

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Wang Y. et al. Local electric field effect of montmorillonite in solid polymer electrolytes for lithium metal batteries // Nano Energy. 2021. Vol. 90. p. 106490.

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Wang Y., Li Xinyang 李., Qin Y., Zhang D., Song Z., Qi J. Local electric field effect of montmorillonite in solid polymer electrolytes for lithium metal batteries // Nano Energy. 2021. Vol. 90. p. 106490.

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RIS Copy

TY - JOUR

DO - 10.1016/j.nanoen.2021.106490

UR - https://doi.org/10.1016/j.nanoen.2021.106490

TI - Local electric field effect of montmorillonite in solid polymer electrolytes for lithium metal batteries

T2 - Nano Energy

AU - Wang, Yong

AU - Li Xinyang, 李新阳

AU - Qin, Yanyang

AU - Zhang, Dongyang

AU - Song, Zhongxiao

AU - Qi, Junlei

PY - 2021

DA - 2021/12/01 00:00:00

PB - Elsevier

SP - 106490

VL - 90

SN - 2211-2855

ER -

BibTex

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BibTex Copy

@article{2021_Wang,

author = {Yong Wang and 李新阳 Li Xinyang and Yanyang Qin and Dongyang Zhang and Zhongxiao Song and Junlei Qi},

title = {Local electric field effect of montmorillonite in solid polymer electrolytes for lithium metal batteries},

journal = {Nano Energy},

year = {2021},

volume = {90},

publisher = {Elsevier},

month = {dec},

url = {https://doi.org/10.1016/j.nanoen.2021.106490},

pages = {106490},

doi = {10.1016/j.nanoen.2021.106490}

}

Found error?

Publisher

Elsevier

Journal

Nano Energy

Quartile SCImago

Quartile WOS

Impact factor

17.6

ISSN

22112855 (Print)