Nano Energy, volume 91, pages 106643
A fast and low-cost interface modification method to achieve high-performance garnet-based solid-state lithium metal batteries
Bing Zhao
1
,
Bing Zhao
,
Wencheng Ma
2
,
Bobo Li
,
Bo-Bo Li
2
,
Xiongtao Hu
2
,
Shangying Lu
2
,
Xiaoyu Liu
3
,
Yong Jiang
2
,
Jiujun Zhang
3
Publication type: Journal Article
Publication date: 2022-01-01
General Materials Science
Electrical and Electronic Engineering
Renewable Energy, Sustainability and the Environment
Abstract
Garnet-based solid-state lithium metal batteries (SSLMBs) are considered to be the candidate power sources for electric vehicles and large-scale energy storage systems due to their high energy density, wide operating temperature and high safety. However, poor wettability of garnet/Li metal anode interface, large interfacial impedance and penetrating lithium dendrite growth during cycling limit the practical application of SSLMBs. In this paper, SnS 2 ultra-thin film is fabricated on the surface of solid-state Li 6.75 La 3 Zr 1.75 Ta 0.25 O 12 (LLZTO) electrolyte by a rapid (ca. 5 min) liquid-phase deposition method. Then, a Li 2 S/Li x Sn mixed ionic/electronic conductive layer is in-situ constructed through the conversion reaction between molten Li and SnS 2 . This mixed conductive layer can significantly reduce interfacial impedance, ensure intimate contact at the Li/garnet interface and inhibit growth of lithium dendrites. Thus, the resulting Li symmetric cell with Li 2 S/Li x Sn modification layer exhibits a low interface resistance of 47 Ω cm 2 and a long lifespan over 1000 cycles. Moreover, using this Li/garnet interface, the full cell assembled with LiFePO 4 cathode shows both excellent cycling and rate performance. These results demonstrate the feasibility of the proposed modification strategy for solid-state garnet electrolyte, and pave the way for the development of high-performance solid-state batteries. A mixed ionic/electronic conductive Li 2 S/Li x Sn layer is in-situ constructed through the conversion reaction between molten Li and SnS 2 . Li 2 S has a wide band gap which can prevent electron attack on LLZTO electrolyte. The Li x Sn alloy not only guides a homogeneous electronic distribution but also serves as a lithiophilic material to make an intimate LLZTO/Li contact at the interface. • SnS 2 nanosheets are coated on LLZTO surface via a fast liquid deposition for interficial modification. • A mixed ionic/electronic conductive Li 2 S/Li x Sn layer is in-situ formed at LLZTO/Li interface. • The Li 2 S/Li x Sn layer improves wettability, decreases interfacial activation energy and prevents the electron attacking LLZTO. • Li 2 S/Li x Sn modified Li symmetric cell cycles stably over 1000 h at 0.2 mA cm −2 .
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Citations by publishers
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35
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Elsevier
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Springer Nature
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2 publications, 2.41%
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American Institute of Physics (AIP)
1 publication, 1.2%
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World Scientific
1 publication, 1.2%
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Nonferrous Metals Society of China
1 publication, 1.2%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 1.2%
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5
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35
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Zhao B. et al. A fast and low-cost interface modification method to achieve high-performance garnet-based solid-state lithium metal batteries // Nano Energy. 2022. Vol. 91. p. 106643.
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Zhao B., Zhao B., Ma W., Li B., Li B., Hu X., Lu S., Liu X., Jiang Y., Zhang J. A fast and low-cost interface modification method to achieve high-performance garnet-based solid-state lithium metal batteries // Nano Energy. 2022. Vol. 91. p. 106643.
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TY - JOUR
DO - 10.1016/j.nanoen.2021.106643
UR - https://doi.org/10.1016/j.nanoen.2021.106643
TI - A fast and low-cost interface modification method to achieve high-performance garnet-based solid-state lithium metal batteries
T2 - Nano Energy
AU - Zhao, Bing
AU - Ma, Wencheng
AU - Li, Bobo
AU - Hu, Xiongtao
AU - Lu, Shangying
AU - Zhao, Bing
AU - Li, Bo-Bo
AU - Liu, Xiaoyu
AU - Jiang, Yong
AU - Zhang, Jiujun
PY - 2022
DA - 2022/01/01 00:00:00
PB - Elsevier
SP - 106643
VL - 91
SN - 2211-2855
ER -
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@article{2022_Zhao,
author = {Bing Zhao and Wencheng Ma and Bobo Li and Xiongtao Hu and Shangying Lu and Bing Zhao and Bo-Bo Li and Xiaoyu Liu and Yong Jiang and Jiujun Zhang},
title = {A fast and low-cost interface modification method to achieve high-performance garnet-based solid-state lithium metal batteries},
journal = {Nano Energy},
year = {2022},
volume = {91},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/j.nanoen.2021.106643},
pages = {106643},
doi = {10.1016/j.nanoen.2021.106643}
}
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