Nano Energy, volume 122, pages 109261
Single-ion conducting Polymer Electrolyte: A promising electrolyte formulation to extend the lifespans of LMBs
1
Department of Chemistry, Ravenshaw University, Cuttack, Odisha, India-753003
|
2
School for Advanced Research in Polymers (SARP), Laboratory for Advanced Research in Polymeric Materials (LARPM), Central Institute of Petrochemicals Engineering & Technology (CIPET), Bhubaneswar, Odisha-751024
|
Publication type: Journal Article
Publication date: 2024-04-01
General Materials Science
Electrical and Electronic Engineering
Renewable Energy, Sustainability and the Environment
Abstract
Lithium metal batteries (LMBs) are considered as "Holy Grail" energy storage and conversion devices in order to meet the continuous energy consumption demands, owing to their high energy density and specific energy. However, the persistent loss of cell capacity and power density caused by the non-uniform deposition of Li-ions on the anode surface, raises questions regarding the lifespan of these devices. Thus, upholding long-term cycling life of LMBs is the foremost attention of researchers in current time. By keeping this in mind, here, we first rewind one of the key factors that affect the lifespan of LMBs, i.e. the effect of formation and growth of Li-dendrites at anode with other undesirable side reactions. Moreover, an insight into the fresh research avenues for extending lifespans of LMBs such as designing of single-ion conducting polymer electrolytes (SIPEs) in various forms and methods are briefly reviewed. Additionally, the structure-property relationship of SIPEs made from conventional as well as emerging materials such as poly ionic liquids (PILs) and covalent organic frameworks (COFs) are also deliberated. The effect of various factors such as architecture, length, concentration, molecular weight, backbone polarity of SIPEs on Li-transference number (LTN) and ionic conductivity are extensively analysed. Finally, different future perspectives to modify the SIPEs has been proposed to realise increasing lifespan of LMBs. This article offers a cutting-edge knowledge to re-evaluate the major degradation issues in LMBs and introduces research on SIPEs as a robust avenue for advancements in battery sector.
Top-30
Citations by journals
|
1
|
|
|
ACS applied materials & interfaces
1 publication, 33.33%
|
|
|
Macromolecular Rapid Communications
1 publication, 33.33%
|
|
|
Russian Chemical Reviews
1 publication, 33.33%
|
|
|
1
|
Citations by publishers
|
1
|
|
|
American Chemical Society (ACS)
1 publication, 33.33%
|
|
|
Wiley
1 publication, 33.33%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 33.33%
|
|
|
1
|
- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2024],"ids":[0],"codes":[0],"imageUrls":[""],"datasets":[{"label":"Citations number","data":[3],"backgroundColor":["#3B82F6"],"percentage":["100"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["ACS applied materials & interfaces","Macromolecular Rapid Communications","Russian Chemical Reviews"],"ids":[1458,13443,23802],"codes":[0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6"],"percentage":[33.33,33.33,33.33],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["American Chemical Society (ACS)","Wiley","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii"],"ids":[40,11,9422],"codes":[0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6"],"percentage":[33.33,33.33,33.33],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartiles":{"type":"bar","data":{"show":true,"labels":[2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0],"percentage":["0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0],"percentage":["0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[0],"percentage":["0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[3],"percentage":["100"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0],"percentage":["0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by SCImago per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartilesWs":{"type":"bar","data":{"show":true,"labels":[2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0],"percentage":["0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0],"percentage":["0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[0],"percentage":["0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[3],"percentage":["100"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0],"percentage":["0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by WoS per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
Cite this
GOST |
RIS |
BibTex
Cite this
GOST
Copy
Sahu A. K. et al. Single-ion conducting Polymer Electrolyte: A promising electrolyte formulation to extend the lifespans of LMBs // Nano Energy. 2024. Vol. 122. p. 109261.
GOST all authors (up to 50)
Copy
Sahu A. K., Varadwaj K. S. K., Nayak S., NAYAK S. K., Mohanty S. Single-ion conducting Polymer Electrolyte: A promising electrolyte formulation to extend the lifespans of LMBs // Nano Energy. 2024. Vol. 122. p. 109261.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.nanoen.2024.109261
UR - https://linkinghub.elsevier.com/retrieve/pii/S2211285524000090
TI - Single-ion conducting Polymer Electrolyte: A promising electrolyte formulation to extend the lifespans of LMBs
T2 - Nano Energy
AU - Sahu, Asish K
AU - Varadwaj, K. S. K.
AU - Nayak, Sanjay
AU - Mohanty, Smita
AU - NAYAK, SANJAY K.
PY - 2024
DA - 2024/04/01 00:00:00
PB - Elsevier
SP - 109261
VL - 122
SN - 2211-2855
ER -
Cite this
BibTex
Copy
@article{2024_Sahu,
author = {Asish K Sahu and K. S. K. Varadwaj and Sanjay Nayak and Smita Mohanty and SANJAY K. NAYAK},
title = {Single-ion conducting Polymer Electrolyte: A promising electrolyte formulation to extend the lifespans of LMBs},
journal = {Nano Energy},
year = {2024},
volume = {122},
publisher = {Elsevier},
month = {apr},
url = {https://linkinghub.elsevier.com/retrieve/pii/S2211285524000090},
pages = {109261},
doi = {10.1016/j.nanoen.2024.109261}
}