Nano-Structures and Nano-Objects, volume 35, pages 101020

Rational development of new phosphine telluride precursors for the synthesis of telluride quantum dots

Publication typeJournal Article
Publication date2023-07-01
Quartile SCImago
Q1
Quartile WOS
Impact factor
ISSN2352507X, 2352507X
Physical and Theoretical Chemistry
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
General Materials Science
Abstract
A series of phosphine tellurides with various electronic natures and steric hindrances were prepared. The solutions of these reagents were investigated by 31P/125Te NMR. Quantum chemical calculations were applied for the investigation of the stability of the monomers and complexes with a second phosphine using the DFT method. A good match between the reactivity in the nanocrystal synthesis and the NMR/DFT results was observed. Finally, we developed a tricyclohexylphosphine telluride reagent that is easier to handle and gives highly reproducible results in the synthesis of telluride nanocrystals than most currently applied tellurium solutions in trioctylphosphine (TOP-Te). The solvent effects, Hg:Te ratio and temperature dependences were studied for tricyclohexylphosphine telluride in the synthesis of HgTe quantum dots. The developed reagent was highly efficient in the synthesis of several telluride nanocrystals, namely CdTe, PbTe and ZnTe.

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Russian Chemical Reviews
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Nano-Structures and Nano-Objects
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
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Elsevier
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Shuklov I. A. et al. Rational development of new phosphine telluride precursors for the synthesis of telluride quantum dots // Nano-Structures and Nano-Objects. 2023. Vol. 35. p. 101020.
GOST all authors (up to 50) Copy
Shuklov I. A., Mardini A. A., Skabitsky I. V., Dubrovina N. V., Perepukhov A., Lizunova A. A., Razumov V. F. Rational development of new phosphine telluride precursors for the synthesis of telluride quantum dots // Nano-Structures and Nano-Objects. 2023. Vol. 35. p. 101020.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.nanoso.2023.101020
UR - https://doi.org/10.1016/j.nanoso.2023.101020
TI - Rational development of new phosphine telluride precursors for the synthesis of telluride quantum dots
T2 - Nano-Structures and Nano-Objects
AU - Shuklov, Ivan A
AU - Mardini, Alaa A
AU - Skabitsky, Ivan V
AU - Dubrovina, Natalia V.
AU - Perepukhov, Alexander
AU - Lizunova, Anna A.
AU - Razumov, Vladimir F.
PY - 2023
DA - 2023/07/01 00:00:00
PB - Elsevier
SP - 101020
VL - 35
SN - 2352-507X
SN - 2352-507X
ER -
BibTex
Cite this
BibTex Copy
@article{2023_Shuklov,
author = {Ivan A Shuklov and Alaa A Mardini and Ivan V Skabitsky and Natalia V. Dubrovina and Alexander Perepukhov and Anna A. Lizunova and Vladimir F. Razumov},
title = {Rational development of new phosphine telluride precursors for the synthesis of telluride quantum dots},
journal = {Nano-Structures and Nano-Objects},
year = {2023},
volume = {35},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/j.nanoso.2023.101020},
pages = {101020},
doi = {10.1016/j.nanoso.2023.101020}
}
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