Open Access
Thermal stability of nitric acid solutions of reducing agents used in spent nuclear fuel reprocessing
Publication type: Journal Article
Publication date: 2022-09-01
scimago Q2
wos Q1
SJR: 0.692
CiteScore: 4.9
Impact factor: 2.6
ISSN: 17385733, 2234358X
Nuclear Energy and Engineering
Abstract
The thermal stability of carbohydrazide, hydrazine nitrate, acetohydroxamic acid in nitric acid solutions has been studied at atmospheric pressure and above atmospheric pressure. The volumes of gaseous products of thermolysis and the maximum rate of gas evolution have been determined at atmospheric pressure. It has been shown that, despite the high rate of gas evolution and large volumes of evolved gases, the conditions for the development of autocatalytic oxidation are not created. Exothermic processes are observed in a closed vessel in the temperature range of 50–250 °C. With an increase in the concentration of nitric acid, the temperatures of the onset of exothermic effects for all mixtures decrease, and the values of the total thermal effects of reactions increase, to the greatest extent for solutions with carbohydrazide.
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16
Total citations:
16
Citations from 2024:
10
(62%)
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GOST
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Obedkov A. S. et al. Thermal stability of nitric acid solutions of reducing agents used in spent nuclear fuel reprocessing // Nuclear Engineering and Technology. 2022. Vol. 54. No. 9. pp. 3580-3585.
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Obedkov A. S., Kalistratova V. V., Skvortsov I., Belova E. V. Thermal stability of nitric acid solutions of reducing agents used in spent nuclear fuel reprocessing // Nuclear Engineering and Technology. 2022. Vol. 54. No. 9. pp. 3580-3585.
Cite this
RIS
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TY - JOUR
DO - 10.1016/j.net.2022.03.034
UR - https://linkinghub.elsevier.com/retrieve/pii/S1738573322001759
TI - Thermal stability of nitric acid solutions of reducing agents used in spent nuclear fuel reprocessing
T2 - Nuclear Engineering and Technology
AU - Obedkov, A S
AU - Kalistratova, V V
AU - Skvortsov, Ilya
AU - Belova, Elena V
PY - 2022
DA - 2022/09/01
PB - Elsevier
SP - 3580-3585
IS - 9
VL - 54
SN - 1738-5733
SN - 2234-358X
ER -
Cite this
BibTex (up to 50 authors)
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@article{2022_Obedkov,
author = {A S Obedkov and V V Kalistratova and Ilya Skvortsov and Elena V Belova},
title = {Thermal stability of nitric acid solutions of reducing agents used in spent nuclear fuel reprocessing},
journal = {Nuclear Engineering and Technology},
year = {2022},
volume = {54},
publisher = {Elsevier},
month = {sep},
url = {https://linkinghub.elsevier.com/retrieve/pii/S1738573322001759},
number = {9},
pages = {3580--3585},
doi = {10.1016/j.net.2022.03.034}
}
Cite this
MLA
Copy
Obedkov, A. S., et al. “Thermal stability of nitric acid solutions of reducing agents used in spent nuclear fuel reprocessing.” Nuclear Engineering and Technology, vol. 54, no. 9, Sep. 2022, pp. 3580-3585. https://linkinghub.elsevier.com/retrieve/pii/S1738573322001759.