Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms, volume 265, issue 1, pages 168-172

Preparation of composite polymer electrolytes by electron beam-induced grafting: Proton- and lithium ion-conducting membranes

Mohamed Mahmoud Nasef 1
H. Saidi 1
K Z M Dahlan 2
Publication typeJournal Article
Publication date2007-12-01
Quartile SCImago
Q2
Quartile WOS
Q3
Impact factor1.3
ISSN0168583X
Instrumentation
Nuclear and High Energy Physics
Abstract
Two classes of composite polymer electrolyte membranes, one conducting lithium ions (Li+) and the other conducting protons (H+) were prepared using simultaneous electron beam-induced grafting. Porous poly(vinylidene fluoride) (PVDF) films were impregnated with styrene and subjected to electron beam (EB) irradiation to obtain polystyrene (PS) filled PVDF precursor films that were subsequently treated with either chlorosulfonic acid/1,1,2,2-tetrachloroethane mixture to obtain H+-conducting composite membranes or LiPH6/EC/DEC liquid electrolyte to obtain Li+-conducting composite membranes. The properties of the obtained membranes were evaluated using Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and AC impedance measurements. The obtained membranes were found to achieve grafting content up to 46% with superior Li+-conductivity of 1.91 A— 10-3 S/cm and H+-conductivity of 5.95 A— 10-2 S/cm. The results of this work show that simultaneous radiation-induced grafting with EB is a promising method to prepare high quality ion-conducting membranes for possible use in fuel cells and lithium batteries.

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Nasef M. M., Saidi H., Dahlan K. Z. M. Preparation of composite polymer electrolytes by electron beam-induced grafting: Proton- and lithium ion-conducting membranes // Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms. 2007. Vol. 265. No. 1. pp. 168-172.
GOST all authors (up to 50) Copy
Nasef M. M., Saidi H., Dahlan K. Z. M. Preparation of composite polymer electrolytes by electron beam-induced grafting: Proton- and lithium ion-conducting membranes // Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms. 2007. Vol. 265. No. 1. pp. 168-172.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.nimb.2007.08.044
UR - https://doi.org/10.1016/j.nimb.2007.08.044
TI - Preparation of composite polymer electrolytes by electron beam-induced grafting: Proton- and lithium ion-conducting membranes
T2 - Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms
AU - Nasef, Mohamed Mahmoud
AU - Saidi, H.
AU - Dahlan, K Z M
PY - 2007
DA - 2007/12/01 00:00:00
PB - Elsevier
SP - 168-172
IS - 1
VL - 265
SN - 0168-583X
ER -
BibTex |
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BibTex Copy
@article{2007_Nasef,
author = {Mohamed Mahmoud Nasef and H. Saidi and K Z M Dahlan},
title = {Preparation of composite polymer electrolytes by electron beam-induced grafting: Proton- and lithium ion-conducting membranes},
journal = {Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms},
year = {2007},
volume = {265},
publisher = {Elsevier},
month = {dec},
url = {https://doi.org/10.1016/j.nimb.2007.08.044},
number = {1},
pages = {168--172},
doi = {10.1016/j.nimb.2007.08.044}
}
MLA
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Nasef, Mohamed Mahmoud, et al. “Preparation of composite polymer electrolytes by electron beam-induced grafting: Proton- and lithium ion-conducting membranes.” Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms, vol. 265, no. 1, Dec. 2007, pp. 168-172. https://doi.org/10.1016/j.nimb.2007.08.044.
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