Optical Materials, volume 34, issue 5, pages 807-811
An intrinsic luminescence in binary lead silicate glasses
Publication type: Journal Article
Publication date: 2012-03-01
Electronic, Optical and Magnetic Materials
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Spectroscopy
Atomic and Molecular Physics, and Optics
Electrical and Electronic Engineering
Abstract
The low-temperature photoluminescence (PL) of x PbO · (1 − x )SiO 2 glasses ( x = 0.20–0.75) was studied at Т = 10 K. The recorded PL-spectra are a superposition of three spectral components with maxima located at 1.8 eV (identified as Pb 6 p → metal-bridging O2 p radiative electron transition, the “ R ”-band), 2.0 eV (Pb 6 p → non-bridging O2 p , the “ O ”-band) and 2.55 eV (Pb 6 p → Pb 6 s , the “ B ”-band), respectively. It was found the essential link for “ R ”, “ O ” and “ B ” PL-bands with chemical composition x of the glasses under study. These concentration dependences are expressed as mutual PL-intensity variations for each recorded luminescence band that allowed to determine their origin. The shape of established dependences well coincides with numerical data on NBO- and MBO-density of chemical bonding, reported previously. The overall PL-manner within the temperature range of 10–295 K is described by an empirical Street’s law. It was shown that experimental photoluminescence quenching curves may be precisely approximated as a superposition of Mott relationships for nonequivalent luminescence centers. The obtained distribution of PL-centers on the activation energy for luminescence quenching reflects the essential donation of the low-energy states into the overall PL-process. The width of this energy distribution affects by the type of PL-emission band and the disordering degree in the arrangement of local PL-centers of a certain kind.
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Zatsepin А. F. et al. An intrinsic luminescence in binary lead silicate glasses // Optical Materials. 2012. Vol. 34. No. 5. pp. 807-811.
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Zatsepin А. F., ZHIDKOV I. S., KUKHARENKO A. I., Zatsepin D. A., Andronov М. P., CHOLAKH S. O. An intrinsic luminescence in binary lead silicate glasses // Optical Materials. 2012. Vol. 34. No. 5. pp. 807-811.
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TY - JOUR
DO - 10.1016/j.optmat.2011.11.012
UR - https://doi.org/10.1016/j.optmat.2011.11.012
TI - An intrinsic luminescence in binary lead silicate glasses
T2 - Optical Materials
AU - Zatsepin, А F
AU - ZHIDKOV, I. S.
AU - KUKHARENKO, A. I.
AU - Zatsepin, D. A.
AU - Andronov, М P
AU - CHOLAKH, S. O.
PY - 2012
DA - 2012/03/01 00:00:00
PB - Elsevier
SP - 807-811
IS - 5
VL - 34
SN - 0925-3467
ER -
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@article{2012_Zatsepin,
author = {А F Zatsepin and I. S. ZHIDKOV and A. I. KUKHARENKO and D. A. Zatsepin and М P Andronov and S. O. CHOLAKH},
title = {An intrinsic luminescence in binary lead silicate glasses},
journal = {Optical Materials},
year = {2012},
volume = {34},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016/j.optmat.2011.11.012},
number = {5},
pages = {807--811},
doi = {10.1016/j.optmat.2011.11.012}
}
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Zatsepin, А. F., et al. “An intrinsic luminescence in binary lead silicate glasses.” Optical Materials, vol. 34, no. 5, Mar. 2012, pp. 807-811. https://doi.org/10.1016/j.optmat.2011.11.012.
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