Optical Materials, volume 35, issue 8, pages 1513-1519
On the luminescence enhancement of Mn2+ by co-doping of Eu2+ in ZnS:Mn,Eu
Marius Hossu
1
,
Roger O Schaeffer
1
,
Lun Ma
1
,
Wenhao Chen
1
,
Yongbin Zhu
2
,
Ramaswami Sammynaiken
2
,
Alan G. Joly
3
1
Department of Physics, The University of Texas at Arlington, Arlington, TX 76019-0059 (United States)
|
2
Saskatchewan Structural Sciences Centre, University of Saskatchewan, Saskatoon, SK, Canada S7N 5C9
|
Publication type: Journal Article
Publication date: 2013-06-01
Electronic, Optical and Magnetic Materials
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Spectroscopy
Atomic and Molecular Physics, and Optics
Electrical and Electronic Engineering
Abstract
The photoluminescence and X-ray luminescence of ZnS:Mn, ZnS:Mn,Eu and ZnS:Eu were investigated and it was found that the luminescence intensity of Mn2+ in ZnS:Mn,Eu co-doped phosphors is highly dependent on the doping concentration of Eu2+. At the optimized Eu2+ concentration (0.2%), the photoluminescence of Mn2+ shows about a 5.5 times enhancement and its X-ray luminescence is enhanced by a factor of 2.5. Both wurtzite and zinc blend phases are present in the samples with wurtzite phase dominant. Co-doping of Eu2+ into ZnS:Mn does not change appreciably the ratio of the two phases or the Mn2+ emission luminescence lifetime; however, the doping of Eu2+ into ZnS:Mn does change the phonon activity. Furthermore, it was found that the defect-related blue emission of ZnS:Eu overlaps with the excitation bands of Mn2+ in ZnS:Mn and there is likely energy transfer from these defect states to Mn2+ in ZnS:Mn,Eu. This energy transfer and the phonon modification are considered to be the two main reasons for the luminescence enhancement and the intensity dependence of Mn2+ emission on Eu2+ doping concentration in ZnS:Mn,Eu.
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Citations by publishers
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1 publication, 3.7%
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4
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12
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- We do not take into account publications without a DOI.
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Hossu M. et al. On the luminescence enhancement of Mn2+ by co-doping of Eu2+ in ZnS:Mn,Eu // Optical Materials. 2013. Vol. 35. No. 8. pp. 1513-1519.
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Hossu M., Schaeffer R. O., Ma L., Chen W., Zhu Y., Sammynaiken R., Joly A. G. On the luminescence enhancement of Mn2+ by co-doping of Eu2+ in ZnS:Mn,Eu // Optical Materials. 2013. Vol. 35. No. 8. pp. 1513-1519.
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TY - JOUR
DO - 10.1016/j.optmat.2013.03.014
UR - https://doi.org/10.1016/j.optmat.2013.03.014
TI - On the luminescence enhancement of Mn2+ by co-doping of Eu2+ in ZnS:Mn,Eu
T2 - Optical Materials
AU - Hossu, Marius
AU - Schaeffer, Roger O
AU - Ma, Lun
AU - Chen, Wenhao
AU - Zhu, Yongbin
AU - Sammynaiken, Ramaswami
AU - Joly, Alan G.
PY - 2013
DA - 2013/06/01 00:00:00
PB - Elsevier
SP - 1513-1519
IS - 8
VL - 35
SN - 0925-3467
ER -
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@article{2013_Hossu,
author = {Marius Hossu and Roger O Schaeffer and Lun Ma and Wenhao Chen and Yongbin Zhu and Ramaswami Sammynaiken and Alan G. Joly},
title = {On the luminescence enhancement of Mn2+ by co-doping of Eu2+ in ZnS:Mn,Eu},
journal = {Optical Materials},
year = {2013},
volume = {35},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016/j.optmat.2013.03.014},
number = {8},
pages = {1513--1519},
doi = {10.1016/j.optmat.2013.03.014}
}
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MLA
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Hossu, Marius, et al. “On the luminescence enhancement of Mn2+ by co-doping of Eu2+ in ZnS:Mn,Eu.” Optical Materials, vol. 35, no. 8, Jun. 2013, pp. 1513-1519. https://doi.org/10.1016/j.optmat.2013.03.014.