Optical Materials, volume 36, issue 2, pages 186-190

One-pot synthesis of CdS nanoparticles exhibiting quantum size effect prepared within a sol–gel derived ureasilicate matrix

Luis F F F Gonçalves ¹

Fehmida K Kanodarwala ²

John Stride ²

Carlos Silva ¹

M. J. M. Gomes ³

Hide authors affiliations Show authors affiliations: 3 affiliations

Centro de Química, Departamento de Química, Universidade do Minho, 4710-057 Braga, Portugal |

School of Chemistry, University of New South Wales, Sydney, 2052 Australia |

Centro de Física – Departamento de Física, Universidade do Minho, 4710-057 Braga, Portugal |

Publication type: Journal Article

Publication date: 2013-12-01

Elsevier

Journal: Optical Materials

Quartile SCImago

Quartile WOS

Impact factor: 3.9

ISSN: 09253467

DOI: 10.1016/j.optmat.2013.08.026

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Electronic, Optical and Magnetic Materials

Organic Chemistry

Inorganic Chemistry

Physical and Theoretical Chemistry

Spectroscopy

Atomic and Molecular Physics, and Optics

Electrical and Electronic Engineering

Abstract

This paper describes a novel single-pot synthesis process based on sol–gel for the production of a highly transparent hybrid matrix containing CdS nanoparticles (NPs). The reaction between cadmium and sulphide ions in the presence of 3-mercaptopropyltrimethoxysilane (MPTMS) that originates the formation of quantum confined CdS NPs occurs simultaneously with the condensation and polymerization of the gel precursors that evolves to a macromolecular hybrid organic–inorganic network. The obtained xerogel matrix is based on the reaction of organically modified alkoxysilane (3-isocyanatepropyltriethoxysilane) and a di-amine functionalized oligopolyoxyethylene (Jeffamine ED-600). The final material is characterized as highly transparent, homogeneous and flexible xerogel incorporating stabilized and high crystalline CdS NPs that exhibit size-dependent optical properties due to quantum confinement of photogenerated e-h pairs as observed from UV–visible and photoluminescence spectroscopy and HRTEM microscopy measurements. The developed approach has obvious advantages comparatively to the alternative and more complex routes of production of composite materials with embedded semiconductor NPs because of the simplified one-pot preparative procedure used. The developed sol–gel process allows the control of the optical characteristics of the obtained CdS NPs embedded within the network by adjusting the molar ratio between cadmium ion and MPTMS and between cadmium and sulphide ions.

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	2 4 6 8 10
Elsevier	Elsevier, 10, 47.62% Elsevier 10 publications, 47.62%
Springer Nature	Springer Nature, 4, 19.05% Springer Nature 4 publications, 19.05%
World Scientific	World Scientific, 1, 4.76% World Scientific 1 publication, 4.76%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 1, 4.76% Multidisciplinary Digital Publishing Institute (MDPI) 1 publication, 4.76%
Wiley	Wiley, 1, 4.76% Wiley 1 publication, 4.76%
Taylor & Francis	Taylor & Francis, 1, 4.76% Taylor & Francis 1 publication, 4.76%
Walter de Gruyter	Walter de Gruyter, 1, 4.76% Walter de Gruyter 1 publication, 4.76%
Sakarya University Journal of Science	Sakarya University Journal of Science, 1, 4.76% Sakarya University Journal of Science 1 publication, 4.76%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 4.76% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 4.76%
	2 4 6 8 10

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Gonçalves L. F. F. F. et al. One-pot synthesis of CdS nanoparticles exhibiting quantum size effect prepared within a sol–gel derived ureasilicate matrix // Optical Materials. 2013. Vol. 36. No. 2. pp. 186-190.

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Gonçalves L. F. F. F., Kanodarwala F. K., Stride J., Silva C., Gomes M. J. M. One-pot synthesis of CdS nanoparticles exhibiting quantum size effect prepared within a sol–gel derived ureasilicate matrix // Optical Materials. 2013. Vol. 36. No. 2. pp. 186-190.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.optmat.2013.08.026

UR - https://doi.org/10.1016/j.optmat.2013.08.026

TI - One-pot synthesis of CdS nanoparticles exhibiting quantum size effect prepared within a sol–gel derived ureasilicate matrix

T2 - Optical Materials

AU - Gonçalves, Luis F F F

AU - Kanodarwala, Fehmida K

AU - Stride, John

AU - Silva, Carlos

AU - Gomes, M. J. M.

PY - 2013

DA - 2013/12/01 00:00:00

PB - Elsevier

SP - 186-190

IS - 2

VL - 36

SN - 0925-3467

ER -

BibTex |

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@article{2013_Gonçalves,

author = {Luis F F F Gonçalves and Fehmida K Kanodarwala and John Stride and Carlos Silva and M. J. M. Gomes},

title = {One-pot synthesis of CdS nanoparticles exhibiting quantum size effect prepared within a sol–gel derived ureasilicate matrix},

journal = {Optical Materials},

year = {2013},

volume = {36},

publisher = {Elsevier},

month = {dec},

url = {https://doi.org/10.1016/j.optmat.2013.08.026},

number = {2},

pages = {186--190},

doi = {10.1016/j.optmat.2013.08.026}

}

MLA

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Gonçalves, Luis F. F. F., et al. “One-pot synthesis of CdS nanoparticles exhibiting quantum size effect prepared within a sol–gel derived ureasilicate matrix.” Optical Materials, vol. 36, no. 2, Dec. 2013, pp. 186-190. https://doi.org/10.1016/j.optmat.2013.08.026.

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Publisher

Elsevier

Journal

Optical Materials

Quartile SCImago

Quartile WOS

Impact factor

3.9

ISSN

09253467 (Print)

	1 2
Materials Chemistry and Physics	Materials Chemistry and Physics, 2, 9.52% Materials Chemistry and Physics 2 publications, 9.52%
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	1 2