volume 160 pages 116747

Structural rearrangements induced by low-temperature Na+-Ag+ ion exchange in silicate matrix of photo-thermo-refractive glass

Publication typeJournal Article
Publication date2025-03-01
scimago Q1
wos Q1
SJR0.699
CiteScore6.8
Impact factor4.2
ISSN09253467, 18731252
Abstract
The work is devoted to structural study of Na+-Ag+ ion-exchanged photo-thermo-refractive (PTR) glass matrix by FTIR and Raman spectroscopies. FTIR reflectance spectra showed minor shift of the bands related to change in Si–O force constant in structural units associated with Na+ and Ag+ ions. On the other hand, Raman spectra showed progressive changes from glass surface deeper into bulk in bands related to 3-membered rings, mixed stretching-bending vibrations of Si–O–Si, and Si–O stretching vibrations in SiO4 tetrahedra with different amount of bridging/non-bridging oxygen atoms. Location and relative intensity of the indicated bands is shown to well correlate with the refractive index profile. The latter allows one to reconstruct concentration profile of silver ions in Na+-Ag+ ion-exchanged PTR glass matrix with high accuracy by Raman spectroscopy as a non-contact and non-destructive method.
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Sgibnev Y. et al. Structural rearrangements induced by low-temperature Na+-Ag+ ion exchange in silicate matrix of photo-thermo-refractive glass // Optical Materials. 2025. Vol. 160. p. 116747.
GOST all authors (up to 50) Copy
Sgibnev Y., Shelaev A. V., Bykov I., Marasanov D. V., Ignatiev A. I., Nikonorov N., Baryshev A. V. Structural rearrangements induced by low-temperature Na+-Ag+ ion exchange in silicate matrix of photo-thermo-refractive glass // Optical Materials. 2025. Vol. 160. p. 116747.
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RIS Copy
TY - JOUR
DO - 10.1016/j.optmat.2025.116747
UR - https://linkinghub.elsevier.com/retrieve/pii/S0925346725001065
TI - Structural rearrangements induced by low-temperature Na+-Ag+ ion exchange in silicate matrix of photo-thermo-refractive glass
T2 - Optical Materials
AU - Sgibnev, Yevgeniy
AU - Shelaev, A V
AU - Bykov, I.V
AU - Marasanov, Dmitriy V
AU - Ignatiev, A I
AU - Nikonorov, N.V
AU - Baryshev, A V
PY - 2025
DA - 2025/03/01
PB - Elsevier
SP - 116747
VL - 160
SN - 0925-3467
SN - 1873-1252
ER -
BibTex
Cite this
BibTex (up to 50 authors) Copy
@article{2025_Sgibnev,
author = {Yevgeniy Sgibnev and A V Shelaev and I.V Bykov and Dmitriy V Marasanov and A I Ignatiev and N.V Nikonorov and A V Baryshev},
title = {Structural rearrangements induced by low-temperature Na+-Ag+ ion exchange in silicate matrix of photo-thermo-refractive glass},
journal = {Optical Materials},
year = {2025},
volume = {160},
publisher = {Elsevier},
month = {mar},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0925346725001065},
pages = {116747},
doi = {10.1016/j.optmat.2025.116747}
}