Physica B: Condensed Matter, volume 600, pages 412489
Effect of adding Li2O and MgO on Li-conductivity in NASICON material
Publication type: Journal Article
Publication date: 2021-01-01
Journal:
Physica B: Condensed Matter
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor: 2.8
ISSN: 09214526
Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Electrical and Electronic Engineering
Abstract
Li+ ion conducting properties in Li1·3Al0·15Y0·15Ti1·7(PO4)3 (LAYTP) compound added with 10 wt % Li2O and x wt% MgO (where x = 15, 25, 35, 45) binder salts are investigated in the present study. LiTi2(PO4)3 (LTP) is found to be the primary Li+ ion conducting phase. This phase belongs to NASICON group with R 3 ‾ c space group. A maximum Li+ ion conductivity of ~10−4 S/cm for bulk and ~10−7 S/cm for grain boundary regions in the sample with maximum MgO concentration is observed at ~145 °C. Role of secondary phase and glassy phase on Li+ conductivity is discussed. Samples, prepared by solid state reaction method are characterised by XRD, SEM and DSC techniques. The electrical properties have been studied using electrochemical impedance spectroscopy (EIS) in the frequency range 10 Hz–20 MHz and temperature range 25 °C–145 °C.
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Kothari D. H., Kanchan D. K. Effect of adding Li2O and MgO on Li-conductivity in NASICON material // Physica B: Condensed Matter. 2021. Vol. 600. p. 412489.
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Kothari D. H., Kanchan D. K. Effect of adding Li2O and MgO on Li-conductivity in NASICON material // Physica B: Condensed Matter. 2021. Vol. 600. p. 412489.
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TY - JOUR
DO - 10.1016/j.physb.2020.412489
UR - https://doi.org/10.1016/j.physb.2020.412489
TI - Effect of adding Li2O and MgO on Li-conductivity in NASICON material
T2 - Physica B: Condensed Matter
AU - Kothari, Dharmesh H
AU - Kanchan, D. K.
PY - 2021
DA - 2021/01/01 00:00:00
PB - Elsevier
SP - 412489
VL - 600
SN - 0921-4526
ER -
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@article{2021_Kothari,
author = {Dharmesh H Kothari and D. K. Kanchan},
title = {Effect of adding Li2O and MgO on Li-conductivity in NASICON material},
journal = {Physica B: Condensed Matter},
year = {2021},
volume = {600},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/j.physb.2020.412489},
pages = {412489},
doi = {10.1016/j.physb.2020.412489}
}