Progress in Materials Science, volume 88, pages 325-411

Lithium garnets: Synthesis, structure, Li + conductivity, Li + dynamics and applications

Publication typeJournal Article
Publication date2017-07-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor37.4
ISSN00796425, 18732208
General Materials Science
Abstract
Inorganic solid fast Li + conductors based batteries are expected to overcome the limitations over safety concerns of flammable organic polymer electrolytes based Li + batteries. Hence, an all-solid-state Li + battery using non-flammable solid electrolyte have attracted much attention as next-generation battery. Therefore, in the development of all-solid-state lithium rechargeable batteries, it is important to search for a solid electrolyte material that has high Li + conductivity, low electronic conductivity, fast charge transfer at the electrode interface and wide electrochemical window stability against potential electrodes and lithium metal. Hence, significant research effort must be directed towards developing novel fast Li + conductors as electrolytes in all-solid-state lithium batteries. Among the reported inorganic solid Li + conductive oxides, garnet-like structural compounds received considerable attention in recent times for potential application as electrolytes in all-solid-state lithium batteries. The focus of this review is to provide comprehensive overview towards the importance of solid fast lithium ion conductors, advantages of lithium garnets over other ceramic lithium ion conductors and understanding different strategies on synthesis of lithium garnets. Attempts have also been made to understand relationship between the structure, Li + conduction and Li + dynamics of lithium garnets. The status of lithium garnets as solid electrolyte in electrochemical devices like all-solid state lithium battery, lithium-air battery and sensor are also discussed.

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GOST Copy
Ramakumar S. et al. Lithium garnets: Synthesis, structure, Li + conductivity, Li + dynamics and applications // Progress in Materials Science. 2017. Vol. 88. pp. 325-411.
GOST all authors (up to 50) Copy
Ramakumar S., Deviannapoorani C., Dhivya L., Shankar L. S., Murugan R. Lithium garnets: Synthesis, structure, Li + conductivity, Li + dynamics and applications // Progress in Materials Science. 2017. Vol. 88. pp. 325-411.
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RIS Copy
TY - JOUR
DO - 10.1016/j.pmatsci.2017.04.007
UR - https://linkinghub.elsevier.com/retrieve/pii/S0079642517300427
TI - Lithium garnets: Synthesis, structure, Li + conductivity, Li + dynamics and applications
T2 - Progress in Materials Science
AU - Ramakumar, S.
AU - Deviannapoorani, C
AU - Dhivya, L
AU - Shankar, Lakshmi S
AU - Murugan, Ramaswamy
PY - 2017
DA - 2017/07/01 00:00:00
PB - Elsevier
SP - 325-411
VL - 88
SN - 0079-6425
SN - 1873-2208
ER -
BibTex
Cite this
BibTex Copy
@article{2017_Ramakumar,
author = {S. Ramakumar and C Deviannapoorani and L Dhivya and Lakshmi S Shankar and Ramaswamy Murugan},
title = {Lithium garnets: Synthesis, structure, Li + conductivity, Li + dynamics and applications},
journal = {Progress in Materials Science},
year = {2017},
volume = {88},
publisher = {Elsevier},
month = {jul},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0079642517300427},
pages = {325--411},
doi = {10.1016/j.pmatsci.2017.04.007}
}
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