Synthesis, crystal structure and thermal behaviour of [La(hfa) 3 (Phen)2 ] (hfa = hexafluoroacetylacetonate, Phen = o-phenanthroline)
A. Yu. Rogachev
1
,
L Kh Minacheva
2
,
V S Sergienko
2
,
I. P. MALKEROVA
2
,
A. S. ALIKHANYAN
2
,
V V Stryapan
1
,
Publication type: Journal Article
Publication date: 2005-04-01
scimago Q3
wos Q2
SJR: 0.396
CiteScore: 4.9
Impact factor: 2.6
ISSN: 02775387, 18733719
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract The mixed ligand complex [La(hfa)3(Phen)2] (I) was obtained by the interaction of La(hfa)3 and Phen; its composition does not depend on the stoichiometry of the reagents. According to the X-ray single crystal analysis data, complex I crystallizes in the monoclinic space group P21/n, with a = 13.583(3) A, b = 16.959(3) A, c = 18.860(4) A, β = 94.71(3)° and Z = 4. The structure of I consists of isolated mononuclear molecules, the coordination number of La being 10. Thermal behaviour and composition of the vapor phase have been studied for I by thermal analysis and mass-spectrometry using a Knudsen cell. The mixed ligand complex I was found to sublime congruently in the temperature range 370–460 K: [La(hfa)3(Phen)2](s) = [La(hfa)3(Phen)](g) + Phen(g), ΔrH0(T) = 316.2 ± 1.8 kJ/mol.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
3
4
|
|
|
Inorganica Chimica Acta
4 publications, 14.81%
|
|
|
Journal of Molecular Structure
3 publications, 11.11%
|
|
|
Russian Journal of Inorganic Chemistry
3 publications, 11.11%
|
|
|
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
2 publications, 7.41%
|
|
|
Polyhedron
2 publications, 7.41%
|
|
|
Inorganic Chemistry
2 publications, 7.41%
|
|
|
Acta Crystallographica Section E: Crystallographic Communications
1 publication, 3.7%
|
|
|
Journal of Structural Chemistry
1 publication, 3.7%
|
|
|
Journal of Chemical Thermodynamics
1 publication, 3.7%
|
|
|
Arabian Journal of Chemistry
1 publication, 3.7%
|
|
|
Chemistry - A European Journal
1 publication, 3.7%
|
|
|
Zeitschrift fur Anorganische und Allgemeine Chemie
1 publication, 3.7%
|
|
|
Annual Reports Section A (Inorganic Chemistry)
1 publication, 3.7%
|
|
|
New Journal of Chemistry
1 publication, 3.7%
|
|
|
Advanced Materials Research
1 publication, 3.7%
|
|
|
1
2
3
4
|
Publishers
|
2
4
6
8
10
12
|
|
|
Elsevier
11 publications, 40.74%
|
|
|
Pleiades Publishing
6 publications, 22.22%
|
|
|
Wiley
3 publications, 11.11%
|
|
|
American Chemical Society (ACS)
2 publications, 7.41%
|
|
|
Royal Society of Chemistry (RSC)
2 publications, 7.41%
|
|
|
International Union of Crystallography (IUCr)
1 publication, 3.7%
|
|
|
King Saud University
1 publication, 3.7%
|
|
|
Trans Tech Publications
1 publication, 3.7%
|
|
|
2
4
6
8
10
12
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
27
Total citations:
27
Citations from 2024:
0
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Rogachev A. Y. et al. Synthesis, crystal structure and thermal behaviour of [La(hfa) 3(Phen)2] (hfa = hexafluoroacetylacetonate, Phen = o-phenanthroline) // Polyhedron. 2005. Vol. 24. No. 6. pp. 723-729.
GOST all authors (up to 50)
Copy
Rogachev A. Y., Minacheva L. Kh., Sergienko V. S., MALKEROVA I. P., ALIKHANYAN A. S., Stryapan V. V., Kuzmina N. P. Synthesis, crystal structure and thermal behaviour of [La(hfa) 3(Phen)2] (hfa = hexafluoroacetylacetonate, Phen = o-phenanthroline) // Polyhedron. 2005. Vol. 24. No. 6. pp. 723-729.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.poly.2004.06.006
UR - https://doi.org/10.1016/j.poly.2004.06.006
TI - Synthesis, crystal structure and thermal behaviour of [La(hfa) 3(Phen)2] (hfa = hexafluoroacetylacetonate, Phen = o-phenanthroline)
T2 - Polyhedron
AU - Rogachev, A. Yu.
AU - Minacheva, L Kh
AU - Sergienko, V S
AU - MALKEROVA, I. P.
AU - ALIKHANYAN, A. S.
AU - Stryapan, V V
AU - Kuzmina, Natalia P.
PY - 2005
DA - 2005/04/01
PB - Elsevier
SP - 723-729
IS - 6
VL - 24
SN - 0277-5387
SN - 1873-3719
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2005_Rogachev,
author = {A. Yu. Rogachev and L Kh Minacheva and V S Sergienko and I. P. MALKEROVA and A. S. ALIKHANYAN and V V Stryapan and Natalia P. Kuzmina},
title = {Synthesis, crystal structure and thermal behaviour of [La(hfa) 3(Phen)2] (hfa = hexafluoroacetylacetonate, Phen = o-phenanthroline)},
journal = {Polyhedron},
year = {2005},
volume = {24},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016/j.poly.2004.06.006},
number = {6},
pages = {723--729},
doi = {10.1016/j.poly.2004.06.006}
}
Cite this
MLA
Copy
Rogachev, A. Yu., et al. “Synthesis, crystal structure and thermal behaviour of [La(hfa) 3(Phen)2] (hfa = hexafluoroacetylacetonate, Phen = o-phenanthroline).” Polyhedron, vol. 24, no. 6, Apr. 2005, pp. 723-729. https://doi.org/10.1016/j.poly.2004.06.006.
Profiles