The new decanuclear copper(II) cluster [Cu5(β-alaha)4Cl2]2·2HCl·15H2O, its structure, spectroscopy and magnetism
Publication type: Journal Article
Publication date: 2007-04-01
scimago Q3
wos Q2
SJR: 0.396
CiteScore: 4.9
Impact factor: 2.6
ISSN: 02775387, 18733719
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The new polynuclear copper(II) cluster with β-alaninehydroxamic acid of formula [Cu 5 (β-alaha) 4 Cl 2 ] 2 · 2HCl · 15H 2 O, where β-alaha stands for β-alaninehydroxamate ( C 3 H 6 N 2 O 2 2 - ), was obtained. Single crystals of the complex were growing up in water solution. The cluster is composed of two pentameric subunits joined together by chloride bridges. Magnetic studies showed rather strong spin correlation within pentanuclear clusters and weaker interaction between them. Spectroscopic behavior of the single crystals of the cluster were studied at 293 and 4 K. Strong interactions of copper ions with different symmetry sites and strong electron–phonon coupling lead to broad unsplit spectra even at 4 K.
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Legendziewicz J. et al. The new decanuclear copper(II) cluster [Cu5(β-alaha)4Cl2]2·2HCl·15H2O, its structure, spectroscopy and magnetism // Polyhedron. 2007. Vol. 26. No. 6. pp. 1331-1337.
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Legendziewicz J., Watras A., Ciunik Z., Wojciechowski W. The new decanuclear copper(II) cluster [Cu5(β-alaha)4Cl2]2·2HCl·15H2O, its structure, spectroscopy and magnetism // Polyhedron. 2007. Vol. 26. No. 6. pp. 1331-1337.
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TY - JOUR
DO - 10.1016/j.poly.2006.11.002
UR - https://doi.org/10.1016/j.poly.2006.11.002
TI - The new decanuclear copper(II) cluster [Cu5(β-alaha)4Cl2]2·2HCl·15H2O, its structure, spectroscopy and magnetism
T2 - Polyhedron
AU - Legendziewicz, J.
AU - Watras, Adam
AU - Ciunik, Z.
AU - Wojciechowski, W.
PY - 2007
DA - 2007/04/01
PB - Elsevier
SP - 1331-1337
IS - 6
VL - 26
SN - 0277-5387
SN - 1873-3719
ER -
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BibTex (up to 50 authors)
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@article{2007_Legendziewicz,
author = {J. Legendziewicz and Adam Watras and Z. Ciunik and W. Wojciechowski},
title = {The new decanuclear copper(II) cluster [Cu5(β-alaha)4Cl2]2·2HCl·15H2O, its structure, spectroscopy and magnetism},
journal = {Polyhedron},
year = {2007},
volume = {26},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016/j.poly.2006.11.002},
number = {6},
pages = {1331--1337},
doi = {10.1016/j.poly.2006.11.002}
}
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MLA
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Legendziewicz, J., et al. “The new decanuclear copper(II) cluster [Cu5(β-alaha)4Cl2]2·2HCl·15H2O, its structure, spectroscopy and magnetism.” Polyhedron, vol. 26, no. 6, Apr. 2007, pp. 1331-1337. https://doi.org/10.1016/j.poly.2006.11.002.