Solvent-free synthesis of bisferrocenylimines and their rhodium(I) complexes
Publication type: Journal Article
Publication date: 2010-02-01
scimago Q3
wos Q2
SJR: 0.396
CiteScore: 4.9
Impact factor: 2.6
ISSN: 02775387, 18733719
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The solvent-free reaction of ferrocenecarboxaldehyde and diaminoalkanes under solvent-free conditions gave bisferrocenylimines ( L ) in excellent yields. Cationic rhodium(I) complexes with the formulation [Rh(COD)(L)]ClO 4 were prepared by the reaction of [Rh(COD)Cl] 2 with the bisferrocenylimines in the presence of silver perchlorate. The solvent-free reaction of ferrocenecarboxaldehyde and diaminoalkanes under solvent-free conditions gave bisferrocenylimines ( L ) in excellent yields. Cationic rhodium(I) complexes with the formulation [Rh(COD)(L)]ClO 4 were prepared by the reaction of [Rh(COD)Cl] 2 with the bisferrocenylimines in the presence of silver perchlorate. The compounds were characterised by NMR, IR, MS and elemental analysis. The X-ray crystal structures of two rhodium(I) complexes are also reported.
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Total citations:
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Citations from 2025:
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(16.67%)
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Kleyi P. E., Mccleland C. W., Gerber T. I. A. Solvent-free synthesis of bisferrocenylimines and their rhodium(I) complexes // Polyhedron. 2010. Vol. 29. No. 3. pp. 1095-1101.
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Kleyi P. E., Mccleland C. W., Gerber T. I. A. Solvent-free synthesis of bisferrocenylimines and their rhodium(I) complexes // Polyhedron. 2010. Vol. 29. No. 3. pp. 1095-1101.
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RIS
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TY - JOUR
DO - 10.1016/j.poly.2009.11.017
UR - https://doi.org/10.1016/j.poly.2009.11.017
TI - Solvent-free synthesis of bisferrocenylimines and their rhodium(I) complexes
T2 - Polyhedron
AU - Kleyi, P E
AU - Mccleland, C W
AU - Gerber, T. I. A.
PY - 2010
DA - 2010/02/01
PB - Elsevier
SP - 1095-1101
IS - 3
VL - 29
SN - 0277-5387
SN - 1873-3719
ER -
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BibTex (up to 50 authors)
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@article{2010_Kleyi,
author = {P E Kleyi and C W Mccleland and T. I. A. Gerber},
title = {Solvent-free synthesis of bisferrocenylimines and their rhodium(I) complexes},
journal = {Polyhedron},
year = {2010},
volume = {29},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/j.poly.2009.11.017},
number = {3},
pages = {1095--1101},
doi = {10.1016/j.poly.2009.11.017}
}
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MLA
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Kleyi, P. E., et al. “Solvent-free synthesis of bisferrocenylimines and their rhodium(I) complexes.” Polyhedron, vol. 29, no. 3, Feb. 2010, pp. 1095-1101. https://doi.org/10.1016/j.poly.2009.11.017.