1D and 2D supramolecular structures of silver carborane dicyclohexylphosphine complexes constructed by C–H⋯H–B dihydrogen bonding interactions
Publication type: Journal Article
Publication date: 2011-05-01
scimago Q3
wos Q2
SJR: 0.396
CiteScore: 4.9
Impact factor: 2.6
ISSN: 02775387, 18733719
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Five new carborane dicyclohexylphosphine complexes, [Ag2(μ-I)2{1,2-(P Cy2)2-1,2-C2B10H10}2] (1), [Ag2(SCN)2{1,2-(PCy2)2-1,2-C2B10H10}2]n·CH2Cl2 (2), [Ag(ClO4){1,2-(PCy2)2-1,2-C2B10H10}]·CH2Cl2 (3), [Ag2(μ-NO3)2{1,2-(PCy2)2-1,2-C2B10H10}2]·CH2Cl2 (4) and [Ag(SC6H4COOH){1,2-(PCy2)2-1,2-C2B10H10}2]·CH2Cl2 (5), have been synthesized by the reactions of 1,2-bis(dicyclohexylphosphino)-1,2-dicarba-closo-dodecaborane with AgX (X = I, SCN, ClO4, NO3 and SC6H4COOH) in CH2Cl2. The structures of the five complexes were characterized by elemental analysis, FT-IR, 1H, 13C, 11B and 31P NMR spectroscopy. X-ray structure analysis revealed that the structures of the complexes can be classified into three types. Complexes 1 and 4 are di-μ-X-bridged structures and complexes 3 and 5 are mononuclear structures, while complex 2 is a chain-like polymer. Complexes 1 and 2 form 2D supramolecular networks and complexes 3, 4 and 5 form 1D chains via C–H⋯H–B dihydrogen bonding interactions.
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Yang L. et al. 1D and 2D supramolecular structures of silver carborane dicyclohexylphosphine complexes constructed by C–H⋯H–B dihydrogen bonding interactions // Polyhedron. 2011. Vol. 30. No. 9. pp. 1469-1477.
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Yang L., Zhu C. C., Zhang D., Li D., Wang D., Dou J. 1D and 2D supramolecular structures of silver carborane dicyclohexylphosphine complexes constructed by C–H⋯H–B dihydrogen bonding interactions // Polyhedron. 2011. Vol. 30. No. 9. pp. 1469-1477.
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TY - JOUR
DO - 10.1016/j.poly.2011.02.052
UR - https://doi.org/10.1016/j.poly.2011.02.052
TI - 1D and 2D supramolecular structures of silver carborane dicyclohexylphosphine complexes constructed by C–H⋯H–B dihydrogen bonding interactions
T2 - Polyhedron
AU - Yang, Liguo
AU - Zhu, Cheng Chen
AU - Zhang, Daopeng
AU - Li, Da-Cheng
AU - Wang, Da-Qi
AU - Dou, Jianmin
PY - 2011
DA - 2011/05/01
PB - Elsevier
SP - 1469-1477
IS - 9
VL - 30
SN - 0277-5387
SN - 1873-3719
ER -
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BibTex (up to 50 authors)
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@article{2011_Yang,
author = {Liguo Yang and Cheng Chen Zhu and Daopeng Zhang and Da-Cheng Li and Da-Qi Wang and Jianmin Dou},
title = {1D and 2D supramolecular structures of silver carborane dicyclohexylphosphine complexes constructed by C–H⋯H–B dihydrogen bonding interactions},
journal = {Polyhedron},
year = {2011},
volume = {30},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016/j.poly.2011.02.052},
number = {9},
pages = {1469--1477},
doi = {10.1016/j.poly.2011.02.052}
}
Cite this
MLA
Copy
Yang, Liguo, et al. “1D and 2D supramolecular structures of silver carborane dicyclohexylphosphine complexes constructed by C–H⋯H–B dihydrogen bonding interactions.” Polyhedron, vol. 30, no. 9, May. 2011, pp. 1469-1477. https://doi.org/10.1016/j.poly.2011.02.052.