Structural characterization, vibrational and optical properties of a novel one-dimensional organic–inorganic hybrid based-iodobismuthate(III) material, [C10H7NH3]BiI4
Тип публикации: Journal Article
Дата публикации: 2012-10-01
scimago Q3
wos Q2
БС2
SJR: 0.396
CiteScore: 4.9
Impact factor: 2.6
ISSN: 02775387, 18733719
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
The new organic–inorganic hybrid compound [C10H7NH3]BiI4 has been grown by the solvent evaporation method. The one-dimensional (1D) structure for [C10H7NH3]BiI4 has been determined by the single-crystal X-ray diffraction to be orthorhombic, Pbca with a = 15.515(3) A, b = 7.643(2) A, c = 29.067(5) A and Z = 8. The structure consists of corrugated layers of BiI4− chains, with Bi–I bond lengths ranging from 2.9260(2) to 3.2659(2) A, separated by the organic (C10H7NH3)+ cations. The crystal packing is governed by I⋯I electrostatic interactions forming a self-assembled multiple pseudo-two-dimensional structure. Raman and infrared spectra were used to gain more information of the title compound. An assignment of the observed vibration modes is reported. The optical absorption for thin films of the one-dimensional hybrid has also been investigated, revealing a semiconductive behavior with a characteristic energy of Eg = 2.32 eV.
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Hrizi C. et al. Structural characterization, vibrational and optical properties of a novel one-dimensional organic–inorganic hybrid based-iodobismuthate(III) material, [C10H7NH3]BiI4 // Polyhedron. 2012. Vol. 46. No. 1. pp. 41-46.
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Hrizi C., Chaari N., Abid Y., Chniba Boudjada N., Chaabouni S. Structural characterization, vibrational and optical properties of a novel one-dimensional organic–inorganic hybrid based-iodobismuthate(III) material, [C10H7NH3]BiI4 // Polyhedron. 2012. Vol. 46. No. 1. pp. 41-46.
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TY - JOUR
DO - 10.1016/j.poly.2012.07.062
UR - https://doi.org/10.1016/j.poly.2012.07.062
TI - Structural characterization, vibrational and optical properties of a novel one-dimensional organic–inorganic hybrid based-iodobismuthate(III) material, [C10H7NH3]BiI4
T2 - Polyhedron
AU - Hrizi, Chakib
AU - Chaari, Najla
AU - Abid, Y.
AU - Chniba Boudjada, Nassira
AU - Chaabouni, Slaheddine
PY - 2012
DA - 2012/10/01
PB - Elsevier
SP - 41-46
IS - 1
VL - 46
SN - 0277-5387
SN - 1873-3719
ER -
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@article{2012_Hrizi,
author = {Chakib Hrizi and Najla Chaari and Y. Abid and Nassira Chniba Boudjada and Slaheddine Chaabouni},
title = {Structural characterization, vibrational and optical properties of a novel one-dimensional organic–inorganic hybrid based-iodobismuthate(III) material, [C10H7NH3]BiI4},
journal = {Polyhedron},
year = {2012},
volume = {46},
publisher = {Elsevier},
month = {oct},
url = {https://doi.org/10.1016/j.poly.2012.07.062},
number = {1},
pages = {41--46},
doi = {10.1016/j.poly.2012.07.062}
}
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Hrizi, Chakib, et al. “Structural characterization, vibrational and optical properties of a novel one-dimensional organic–inorganic hybrid based-iodobismuthate(III) material, [C10H7NH3]BiI4.” Polyhedron, vol. 46, no. 1, Oct. 2012, pp. 41-46. https://doi.org/10.1016/j.poly.2012.07.062.