Bis-chelate N-heterocyclic tetracarbene Ru(II) complexes: Synthesis, structure, and catalytic activity toward transfer hydrogenation of ketones
Publication type: Journal Article
Publication date: 2013-04-01
scimago Q3
wos Q2
SJR: 0.396
CiteScore: 4.9
Impact factor: 2.6
ISSN: 02775387, 18733719
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Ru(II) complexes with two chelating di-N-heterocyclic carbenes (NHC) and two acetonitrile ligands (NHC = 1,1′-dialkyl-3,3′-methylene-diimidazol-2,2′-diylidene, and alkyl = methyl and n-butyl) were synthesized and structurally characterized. The crystal structures of the complexes determined by X-ray diffraction analyses show that the Ru(II) center is bound to two bidentate carbene ligands and two acetonitrile molecules, forming a distorted octahedron. The complexes prove to be an efficient catalyst having exceedingly high turnover frequencies and good reusability in transfer hydrogenation of ketones.
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Lai Y. B. et al. Bis-chelate N-heterocyclic tetracarbene Ru(II) complexes: Synthesis, structure, and catalytic activity toward transfer hydrogenation of ketones // Polyhedron. 2013. Vol. 53. pp. 243-248.
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Lai Y. B., Lee C., Lin W., Naziruddin A. R., Hwang W. Bis-chelate N-heterocyclic tetracarbene Ru(II) complexes: Synthesis, structure, and catalytic activity toward transfer hydrogenation of ketones // Polyhedron. 2013. Vol. 53. pp. 243-248.
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TY - JOUR
DO - 10.1016/j.poly.2013.01.042
UR - https://doi.org/10.1016/j.poly.2013.01.042
TI - Bis-chelate N-heterocyclic tetracarbene Ru(II) complexes: Synthesis, structure, and catalytic activity toward transfer hydrogenation of ketones
T2 - Polyhedron
AU - Lai, Yong Bin
AU - Lee, Chen-Shiang
AU - Lin, Wan‐Jung
AU - Naziruddin, Abbas Raja
AU - Hwang, Wen-Shu
PY - 2013
DA - 2013/04/01
PB - Elsevier
SP - 243-248
VL - 53
SN - 0277-5387
SN - 1873-3719
ER -
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@article{2013_Lai,
author = {Yong Bin Lai and Chen-Shiang Lee and Wan‐Jung Lin and Abbas Raja Naziruddin and Wen-Shu Hwang},
title = {Bis-chelate N-heterocyclic tetracarbene Ru(II) complexes: Synthesis, structure, and catalytic activity toward transfer hydrogenation of ketones},
journal = {Polyhedron},
year = {2013},
volume = {53},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016/j.poly.2013.01.042},
pages = {243--248},
doi = {10.1016/j.poly.2013.01.042}
}