Synthesis and characterization of sodium polymeric complexes containing carbanionic 3,5-dicyano-6-dicyanomethyl-(ferrocenyl)pyridine and 2-ferroceny(tetracyano)propene ligands
1
Departamento de Química Orgánica, Facultad de Química, Univercidad Nacional Autónoma de México, Cd. Universitaria, Coyoacán, C.P. 04510 México D.F., Mexico
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Publication type: Journal Article
Publication date: 2014-01-01
scimago Q3
wos Q2
SJR: 0.396
CiteScore: 4.9
Impact factor: 2.6
ISSN: 02775387, 18733719
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract Novel Na+ polymeric complexes, {[Na+(2-ferrocenyl(tetracyano)propenyl)−L]∞ and [Na+(2-amino-3,5-dicyano-4-ferrocenyl-6-pyridyl-dicyanomethyl)−L]∞, where L = methanol, acetonitrile, dimethylformamide, acetone, ethyl acetate} were prepared by reactions of 2-cyano-3-ferrocenylacrylonitrile with malononitrile (∼1:3) in a MeOH/H2O medium in the presence of Na2CO3. The new complexes were characterized by elemental analysis, spectroscopy, and single-crystal X-ray diffraction analysis.
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Klimova E. I. et al. Synthesis and characterization of sodium polymeric complexes containing carbanionic 3,5-dicyano-6-dicyanomethyl-(ferrocenyl)pyridine and 2-ferroceny(tetracyano)propene ligands // Polyhedron. 2014. Vol. 68. pp. 272-278.
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Klimova E. I., Garcia M. F., Flores-Alamo M., Churakov A. V., Cortéz Maya S., Beletskaya I. P. Synthesis and characterization of sodium polymeric complexes containing carbanionic 3,5-dicyano-6-dicyanomethyl-(ferrocenyl)pyridine and 2-ferroceny(tetracyano)propene ligands // Polyhedron. 2014. Vol. 68. pp. 272-278.
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TY - JOUR
DO - 10.1016/j.poly.2013.11.003
UR - https://linkinghub.elsevier.com/retrieve/pii/S0277538713007481
TI - Synthesis and characterization of sodium polymeric complexes containing carbanionic 3,5-dicyano-6-dicyanomethyl-(ferrocenyl)pyridine and 2-ferroceny(tetracyano)propene ligands
T2 - Polyhedron
AU - Klimova, Elena I.
AU - Garcia, Marcos F.
AU - Flores-Alamo, Marcos
AU - Churakov, Andrei V.
AU - Cortéz Maya, Sandra
AU - Beletskaya, Irina P.
PY - 2014
DA - 2014/01/01
PB - Elsevier
SP - 272-278
VL - 68
SN - 0277-5387
SN - 1873-3719
ER -
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@article{2014_Klimova,
author = {Elena I. Klimova and Marcos F. Garcia and Marcos Flores-Alamo and Andrei V. Churakov and Sandra Cortéz Maya and Irina P. Beletskaya},
title = {Synthesis and characterization of sodium polymeric complexes containing carbanionic 3,5-dicyano-6-dicyanomethyl-(ferrocenyl)pyridine and 2-ferroceny(tetracyano)propene ligands},
journal = {Polyhedron},
year = {2014},
volume = {68},
publisher = {Elsevier},
month = {jan},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0277538713007481},
pages = {272--278},
doi = {10.1016/j.poly.2013.11.003}
}
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