том 144 страницы 219-224

Influence of synthetic conditions on the formation of thermally and hydrolytically stable Sc-based metal–organic frameworks

Тип публикацииJournal Article
Дата публикации2018-04-01
scimago Q3
wos Q2
БС2
SJR0.396
CiteScore4.9
Impact factor2.6
ISSN02775387, 18733719
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
Three new coordination polymers ((CH3)2NH2)[Sc(H2O)2(fdc)2]·1,5CH3CN (1), ((CH3)2NH2)2[Sc(fdc)2(HCOO)] (2), [Sc2(H2O)2(fdc)3] (3) based on scandium cations and 2,5-furandicarboxylate ligand (fdc2−) have been synthesized and characterized by single crystal and powder X-ray diffraction crystallography, TG, elemental analyses and IR-spectroscopy. Compound 1 is formed from layers bind by hydrogen bonds. Calculated accessible for solvent volume is 41%. Compound 2 is a structure of negatively charged layers connected with interlayer dimethylammonium cations. Layered compound 3 appeared to be thermally stable (up to 300 °C) and retain its structure in wide range of pH from 1 to 13. Additionally, the solid-state luminescence properties of compounds 2 and 3 we investigated.
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Barsukova M. O. et al. Influence of synthetic conditions on the formation of thermally and hydrolytically stable Sc-based metal–organic frameworks // Polyhedron. 2018. Vol. 144. pp. 219-224.
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Barsukova M. O., Samsonenko D. G., Sapianik A. A., Sapchenko S. A., Fedin V. P. Influence of synthetic conditions on the formation of thermally and hydrolytically stable Sc-based metal–organic frameworks // Polyhedron. 2018. Vol. 144. pp. 219-224.
RIS |
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TY - JOUR
DO - 10.1016/j.poly.2018.01.031
UR - https://doi.org/10.1016/j.poly.2018.01.031
TI - Influence of synthetic conditions on the formation of thermally and hydrolytically stable Sc-based metal–organic frameworks
T2 - Polyhedron
AU - Barsukova, Marina O
AU - Samsonenko, Denis G.
AU - Sapianik, Aleksandr A
AU - Sapchenko, Sergey A
AU - Fedin, Vladimir P.
PY - 2018
DA - 2018/04/01
PB - Elsevier
SP - 219-224
VL - 144
SN - 0277-5387
SN - 1873-3719
ER -
BibTex
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@article{2018_Barsukova,
author = {Marina O Barsukova and Denis G. Samsonenko and Aleksandr A Sapianik and Sergey A Sapchenko and Vladimir P. Fedin},
title = {Influence of synthetic conditions on the formation of thermally and hydrolytically stable Sc-based metal–organic frameworks},
journal = {Polyhedron},
year = {2018},
volume = {144},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016/j.poly.2018.01.031},
pages = {219--224},
doi = {10.1016/j.poly.2018.01.031}
}