Polyhedron, volume 199, pages 115106
Catalytic and biological activities of homoleptic palladium(II) complexes bearing the 2-aminobenzothiazole moiety
Serkan Dayan
1
,
Melek Tercan
2
,
Fethi Ahmet Ozdemir
3
,
Gurkan Aykutoglu
3
,
Namık Özdemir
4
,
Zafer Şerbetçi
5
,
Muharrem Dinçer
6
,
Osman Dayan
2
Publication type: Journal Article
Publication date: 2021-05-01
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
In the presented study, bi-dentate N,O chelate Schiff base ligands containing an aminothiazole group were prepared, then their Pd(II) complexes were synthesized and characterized by NMR and FT-IR techniques. The catalytic activities of the synthesized Pd(II) complexes in the reduction of organic pollutants (4-nitrophenol (4-NP), Rhodamine B (Rh B), methylene blue (MB)) that cause water pollution were investigated. Also, the in vitro cytotoxic properties toward DU-145 and SH-SY5Y cells and the antibacterial/antifungal activities of L 1-3 and PdL 1-3 were investigated. • We have reported the design and synthesis of homoleptic palladium (II) complexes. • The fabricated palladium(II) complexes used as catalyst in the reduction reaction of some organic pollutants. • Also the cytotoxic effects of complexes were investigated on DU-145 cells and SH-SY5Y cells. • All synthesized compounds showed moderate catalytic, antimicrobial, and antifungal properties. The palladium(II) complexes PdL 1-3 , bearing bi-dentated Schiff base ligands ( L 1-3 ) were synthesized and characterized by FT-IR, NMR and single crystal-XRD techniques, and the structural, spectroscopic and electronic properties were obtained using the B3LYP density functional method (DFT). The fabricated complexes were used as catalysts in the reduction of some organic pollutants (4-nitrophenol (4-NP), Rhodamine B (Rh B) and methylene blue (MB)) in water at an ambient temperature. The PdL 3 complex was recorded as the best catalyst compared to the other complexes and the highest conversion rates were in the order of MB > RhB > 4-NP. Also, the antimicrobial and antifungal activities of all the compounds (ligands and complexes) and the cytotoxic effects on DU-145 and SH-SY5Y cells were investigated. The PdL 1-3 complexes show cytotoxic effects, especially against the SH-SY5Y cells. All the synthesized compounds showed moderate antimicrobial and antifungal properties.
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- We do not take into account publications without a DOI.
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Dayan S. et al. Catalytic and biological activities of homoleptic palladium(II) complexes bearing the 2-aminobenzothiazole moiety // Polyhedron. 2021. Vol. 199. p. 115106.
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Dayan S., Tercan M., Ozdemir F. A., Aykutoglu G., Özdemir N., Şerbetçi Z., Dinçer M., Dayan O. Catalytic and biological activities of homoleptic palladium(II) complexes bearing the 2-aminobenzothiazole moiety // Polyhedron. 2021. Vol. 199. p. 115106.
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TY - JOUR
DO - 10.1016/j.poly.2021.115106
UR - https://doi.org/10.1016/j.poly.2021.115106
TI - Catalytic and biological activities of homoleptic palladium(II) complexes bearing the 2-aminobenzothiazole moiety
T2 - Polyhedron
AU - Dayan, Serkan
AU - Tercan, Melek
AU - Ozdemir, Fethi Ahmet
AU - Aykutoglu, Gurkan
AU - Özdemir, Namık
AU - Şerbetçi, Zafer
AU - Dinçer, Muharrem
AU - Dayan, Osman
PY - 2021
DA - 2021/05/01 00:00:00
PB - Elsevier
SP - 115106
VL - 199
SN - 0277-5387
ER -
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@article{2021_Dayan,
author = {Serkan Dayan and Melek Tercan and Fethi Ahmet Ozdemir and Gurkan Aykutoglu and Namık Özdemir and Zafer Şerbetçi and Muharrem Dinçer and Osman Dayan},
title = {Catalytic and biological activities of homoleptic palladium(II) complexes bearing the 2-aminobenzothiazole moiety},
journal = {Polyhedron},
year = {2021},
volume = {199},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016/j.poly.2021.115106},
pages = {115106},
doi = {10.1016/j.poly.2021.115106}
}