Polyhedron, volume 199, pages 115106
Catalytic and biological activities of homoleptic palladium(II) complexes bearing the 2-aminobenzothiazole moiety
Serkan Dayan
1
,
Melek Tercan
2
,
Fethi Ahmet Ozdemir
3
,
Gurkan Aykutoglu
3
,
Namık Özdemir
4
,
Zafer Şerbetçi
5
,
Muharrem Dinçer
6
,
Osman Dayan
2
Publication type: Journal Article
Publication date: 2021-05-01
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
In the presented study, bi-dentate N,O chelate Schiff base ligands containing an aminothiazole group were prepared, then their Pd(II) complexes were synthesized and characterized by NMR and FT-IR techniques. The catalytic activities of the synthesized Pd(II) complexes in the reduction of organic pollutants (4-nitrophenol (4-NP), Rhodamine B (Rh B), methylene blue (MB)) that cause water pollution were investigated. Also, the in vitro cytotoxic properties toward DU-145 and SH-SY5Y cells and the antibacterial/antifungal activities of L 1-3 and PdL 1-3 were investigated. • We have reported the design and synthesis of homoleptic palladium (II) complexes. • The fabricated palladium(II) complexes used as catalyst in the reduction reaction of some organic pollutants. • Also the cytotoxic effects of complexes were investigated on DU-145 cells and SH-SY5Y cells. • All synthesized compounds showed moderate catalytic, antimicrobial, and antifungal properties. The palladium(II) complexes PdL 1-3 , bearing bi-dentated Schiff base ligands ( L 1-3 ) were synthesized and characterized by FT-IR, NMR and single crystal-XRD techniques, and the structural, spectroscopic and electronic properties were obtained using the B3LYP density functional method (DFT). The fabricated complexes were used as catalysts in the reduction of some organic pollutants (4-nitrophenol (4-NP), Rhodamine B (Rh B) and methylene blue (MB)) in water at an ambient temperature. The PdL 3 complex was recorded as the best catalyst compared to the other complexes and the highest conversion rates were in the order of MB > RhB > 4-NP. Also, the antimicrobial and antifungal activities of all the compounds (ligands and complexes) and the cytotoxic effects on DU-145 and SH-SY5Y cells were investigated. The PdL 1-3 complexes show cytotoxic effects, especially against the SH-SY5Y cells. All the synthesized compounds showed moderate antimicrobial and antifungal properties.
Top-30
Citations by journals
|
1
2
3
|
|
|
Journal of Molecular Structure
3 publications, 23.08%
|
|
|
BioMetals
1 publication, 7.69%
|
|
|
Arabian Journal of Chemistry
1 publication, 7.69%
|
|
|
Journal of Inorganic Biochemistry
1 publication, 7.69%
|
|
|
ACS Omega
1 publication, 7.69%
|
|
|
Dalton Transactions
1 publication, 7.69%
|
|
|
New Journal of Chemistry
1 publication, 7.69%
|
|
|
Zeitschrift fur Kristallographie - New Crystal Structures
1 publication, 7.69%
|
|
|
Pharmacia
1 publication, 7.69%
|
|
|
Russian Chemical Reviews
1 publication, 7.69%
|
|
|
Applied Organometallic Chemistry
1 publication, 7.69%
|
|
|
1
2
3
|
Citations by publishers
|
1
2
3
4
|
|
|
Elsevier
4 publications, 30.77%
|
|
|
Royal Society of Chemistry (RSC)
2 publications, 15.38%
|
|
|
Springer Nature
1 publication, 7.69%
|
|
|
King Saud University
1 publication, 7.69%
|
|
|
American Chemical Society (ACS)
1 publication, 7.69%
|
|
|
Walter de Gruyter
1 publication, 7.69%
|
|
|
Pensoft Publishers
1 publication, 7.69%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 7.69%
|
|
|
Wiley
1 publication, 7.69%
|
|
|
1
2
3
4
|
- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2021,2022,2023],"ids":[0,0,0],"codes":[0,0,0],"imageUrls":["","",""],"datasets":[{"label":"Citations number","data":[1,6,6],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6"],"percentage":["7.69","46.15","46.15"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Journal of Molecular Structure","BioMetals","Arabian Journal of Chemistry","Journal of Inorganic Biochemistry","ACS Omega","Dalton Transactions","New Journal of Chemistry","Zeitschrift fur Kristallographie - New Crystal Structures","Pharmacia","Russian Chemical Reviews","Applied Organometallic Chemistry"],"ids":[9347,8167,18459,6830,18901,8473,1404,5448,5284,23802,11683],"codes":[0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/9z7b0TQJNgUxZHYXLrTmbnjJn9y5iq56Wxtqb1Lv_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/3SpVxcYL33bOvPq4sHxJLH2NeKNeDloahSUpNiO4_medium.webp","\/storage\/images\/resized\/b6G9vjk5CDda677dGbshycMePIiAXuDS2ebcYaBQ_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp"],"datasets":[{"label":"","data":[3,1,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[23.08,7.69,7.69,7.69,7.69,7.69,7.69,7.69,7.69,7.69,7.69],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Elsevier","Royal Society of Chemistry (RSC)","Springer Nature","King Saud University","American Chemical Society (ACS)","Walter de Gruyter","Pensoft Publishers","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii","Wiley"],"ids":[17,123,8,171,40,4,1086,9422,11],"codes":[0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/9z7b0TQJNgUxZHYXLrTmbnjJn9y5iq56Wxtqb1Lv_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/3SpVxcYL33bOvPq4sHxJLH2NeKNeDloahSUpNiO4_medium.webp","\/storage\/images\/resized\/b6G9vjk5CDda677dGbshycMePIiAXuDS2ebcYaBQ_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp"],"datasets":[{"label":"","data":[4,2,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[30.77,15.38,7.69,7.69,7.69,7.69,7.69,7.69,7.69],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartiles":{"type":"bar","data":{"show":true,"labels":[2021,2022,2023],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,1,0],"percentage":["0","7.69","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,0,0],"percentage":["0","0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[0,1,5],"percentage":["0","7.69","38.46"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[1,4,1],"percentage":["7.69","30.77","7.69"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,0,0],"percentage":["0","0","0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by SCImago per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartilesWs":{"type":"bar","data":{"show":true,"labels":[2021,2022,2023],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,1,0],"percentage":["0","7.69","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,1,0],"percentage":["0","7.69","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[1,2,3],"percentage":["7.69","15.38","23.08"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[0,2,2],"percentage":["0","15.38","15.38"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,0,1],"percentage":["0","0","7.69"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by WoS per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
Cite this
GOST |
RIS |
BibTex
Cite this
GOST
Copy
Dayan S. et al. Catalytic and biological activities of homoleptic palladium(II) complexes bearing the 2-aminobenzothiazole moiety // Polyhedron. 2021. Vol. 199. p. 115106.
GOST all authors (up to 50)
Copy
Dayan S., Tercan M., Ozdemir F. A., Aykutoglu G., Özdemir N., Şerbetçi Z., Dinçer M., Dayan O. Catalytic and biological activities of homoleptic palladium(II) complexes bearing the 2-aminobenzothiazole moiety // Polyhedron. 2021. Vol. 199. p. 115106.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.poly.2021.115106
UR - https://doi.org/10.1016/j.poly.2021.115106
TI - Catalytic and biological activities of homoleptic palladium(II) complexes bearing the 2-aminobenzothiazole moiety
T2 - Polyhedron
AU - Dayan, Serkan
AU - Tercan, Melek
AU - Ozdemir, Fethi Ahmet
AU - Aykutoglu, Gurkan
AU - Özdemir, Namık
AU - Şerbetçi, Zafer
AU - Dinçer, Muharrem
AU - Dayan, Osman
PY - 2021
DA - 2021/05/01 00:00:00
PB - Elsevier
SP - 115106
VL - 199
SN - 0277-5387
ER -
Cite this
BibTex
Copy
@article{2021_Dayan,
author = {Serkan Dayan and Melek Tercan and Fethi Ahmet Ozdemir and Gurkan Aykutoglu and Namık Özdemir and Zafer Şerbetçi and Muharrem Dinçer and Osman Dayan},
title = {Catalytic and biological activities of homoleptic palladium(II) complexes bearing the 2-aminobenzothiazole moiety},
journal = {Polyhedron},
year = {2021},
volume = {199},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016/j.poly.2021.115106},
pages = {115106},
doi = {10.1016/j.poly.2021.115106}
}