Exploring replacement of axially coordinated ligands in ruthenium(II) phthalocyaninates
Publication type: Journal Article
Publication date: 2022-07-01
scimago Q3
wos Q2
SJR: 0.396
CiteScore: 4.9
Impact factor: 2.6
ISSN: 02775387, 18733719
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
We report an extensive study of axial ligand replacement in ruthenium(II) complexes with tetra- tert- butyl-phthalocyanine (tBu 4 Pc). For this purpose oxidative decarbonylation of [tBu 4 PcRu](CO) in the presence of trimethylamine was performed providing [tBu 4 PcRu](NMe 3 ) 2 complex in 92% yield. Its heating with pyrazine in o -dichlorobenzene at 100 °C gave [tBu 4 PcRu](Pyz) 2 in quantitative yield. A simplified TD-DFT approximation has been used to explain the difference in the appearance of UV–Vis spectra of synthesized complexes with different N -donor ligands in terms of π-π* or charge transfer excitations, assignment was validated by the studies of solvatochromism of synthesized complexes. The reported finding can pave a convenient way to a relatively mild selective synthesis of ruthenium phthalocyaninates carrying N -donor aromatic ligands. Such complexes attract interest for various photo- and electroactive applications, catalysis and medicine.
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Dmitrienko A. A. et al. Exploring replacement of axially coordinated ligands in ruthenium(II) phthalocyaninates // Polyhedron. 2022. Vol. 220. p. 115821.
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Dmitrienko A. A., Kroitor A. P., Demina L. I., Gorbunova Y. G., Sorokin A. B., Martynov A. G. Exploring replacement of axially coordinated ligands in ruthenium(II) phthalocyaninates // Polyhedron. 2022. Vol. 220. p. 115821.
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TY - JOUR
DO - 10.1016/j.poly.2022.115821
UR - https://linkinghub.elsevier.com/retrieve/pii/S0277538722001735
TI - Exploring replacement of axially coordinated ligands in ruthenium(II) phthalocyaninates
T2 - Polyhedron
AU - Dmitrienko, Alexander A
AU - Kroitor, Andrey P
AU - Demina, Liudmila I
AU - Gorbunova, Yulia G.
AU - Sorokin, Alexander B
AU - Martynov, Alexander G.
PY - 2022
DA - 2022/07/01
PB - Elsevier
SP - 115821
VL - 220
SN - 0277-5387
SN - 1873-3719
ER -
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@article{2022_Dmitrienko,
author = {Alexander A Dmitrienko and Andrey P Kroitor and Liudmila I Demina and Yulia G. Gorbunova and Alexander B Sorokin and Alexander G. Martynov},
title = {Exploring replacement of axially coordinated ligands in ruthenium(II) phthalocyaninates},
journal = {Polyhedron},
year = {2022},
volume = {220},
publisher = {Elsevier},
month = {jul},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0277538722001735},
pages = {115821},
doi = {10.1016/j.poly.2022.115821}
}