volume 89 issue 1 pages 38-42

Analysis of chlorine distribution in the pyrolysis products of poly(vinylidene chloride) mixed with polyethylene, polypropylene or polystyrene

Publication typeJournal Article
Publication date2005-07-01
scimago Q1
wos Q1
SJR1.237
CiteScore11.3
Impact factor7.4
ISSN01413910, 18732321
Materials Chemistry
Condensed Matter Physics
Polymers and Plastics
Mechanics of Materials
Abstract
The analysis of chlorine distribution in the pyrolysis products of poly(vinylidene chloride) PVDC mixed with polyethylene (PE), polypropylene (PP) or polystyrene (PS) were investigated [PE/PVDC, PP/PVDC, PS/PVDC and 3P/PVDC, where 3P is equal mixture of PE, PP and PS] and reported for the first time. The interaction of degradation products from individual (PE, PP and PS) and mixed (3P) plastics with the PVDC degradation products was investigated and compared with poly(vinyl chloride), PVC. The formation of chlorinated hydrocarbons in the liquid products were in the order of PS/PVDC > 3P/PVDC > PP/PVDC > PE/PVDC. Surprisingly, the quantities of chlorinated hydrocarbons were less compared with the pyrolysis liquid products of PVC mixed plastics even though the chlorine content in PVDC is higher than in PVC. The structurally similar chlorinated hydrocarbons were observed from PVDC or PVC with PE, PP, and PS liquid products. Thermogravimetric analysis results suggest that the decomposition temperature of PVDC is lower than PVC and major portion of chlorine (from PVDC) left the degradation reactor before the degradation of PP, PE, and PS.
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BHASKAR T. et al. Analysis of chlorine distribution in the pyrolysis products of poly(vinylidene chloride) mixed with polyethylene, polypropylene or polystyrene // Polymer Degradation and Stability. 2005. Vol. 89. No. 1. pp. 38-42.
GOST all authors (up to 50) Copy
BHASKAR T., MAKI T., Muto A., Sakata Y., Liu C., Chen M., Chao C. Analysis of chlorine distribution in the pyrolysis products of poly(vinylidene chloride) mixed with polyethylene, polypropylene or polystyrene // Polymer Degradation and Stability. 2005. Vol. 89. No. 1. pp. 38-42.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.polymdegradstab.2004.12.022
UR - https://doi.org/10.1016/j.polymdegradstab.2004.12.022
TI - Analysis of chlorine distribution in the pyrolysis products of poly(vinylidene chloride) mixed with polyethylene, polypropylene or polystyrene
T2 - Polymer Degradation and Stability
AU - BHASKAR, Thallada
AU - MAKI, TANABE
AU - Muto, Akinori
AU - Sakata, Yusaku
AU - Liu, Chiung-Fang
AU - Chen, Ming-Der
AU - Chao, Chih-Yeh
PY - 2005
DA - 2005/07/01
PB - Elsevier
SP - 38-42
IS - 1
VL - 89
SN - 0141-3910
SN - 1873-2321
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2005_BHASKAR,
author = {Thallada BHASKAR and TANABE MAKI and Akinori Muto and Yusaku Sakata and Chiung-Fang Liu and Ming-Der Chen and Chih-Yeh Chao},
title = {Analysis of chlorine distribution in the pyrolysis products of poly(vinylidene chloride) mixed with polyethylene, polypropylene or polystyrene},
journal = {Polymer Degradation and Stability},
year = {2005},
volume = {89},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/j.polymdegradstab.2004.12.022},
number = {1},
pages = {38--42},
doi = {10.1016/j.polymdegradstab.2004.12.022}
}
MLA
Cite this
MLA Copy
BHASKAR, Thallada, et al. “Analysis of chlorine distribution in the pyrolysis products of poly(vinylidene chloride) mixed with polyethylene, polypropylene or polystyrene.” Polymer Degradation and Stability, vol. 89, no. 1, Jul. 2005, pp. 38-42. https://doi.org/10.1016/j.polymdegradstab.2004.12.022.