Polymer

, volume 51 , issue 15 , pages 3416-3424

Preparation of multifunctional supported metallocene catalyst using organic multifunctional modifier for synthesizing polyethylene/clay nanocomposites via in situ intercalative polymerization

Changyi Ren ¹

Xiaohua Du ¹

Li Ma ²

Yanhui Wang ²

Jun Zheng ¹

Tao Tang ²

Hide authors affiliations Show authors affiliations: 2 affiliations

State Key laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China |

State Key Laboratory of Polymer, Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences , Changchun 130022, China. |

Publication type: Journal Article

Publication date: 2010-07-01

Elsevier

Polymer

scimago Q1

wos Q2

SJR: 0.843

CiteScore: 7.7

Impact factor: 4.5

ISSN: 00323861, 18732291

DOI: 10.1016/j.polymer.2010.05.041

Copy DOI

Materials Chemistry

Organic Chemistry

Polymers and Plastics

Abstract

A new type of multifunctional ammonium modifier with carbonyl group and vinyl group was synthesized to prepare multifunctional montmorillonites (F-MMTs), which were used as multifunctional catalyst supports for in situ ethylene polymerization. High loading of metallocene catalyst in the galleries of F-MMT had been achieved due to the presence of carbonyl group in the multifunctional modifier. XRD profiles and TEM images showed that polyethylene/montmorillonite (PE/F-MMT) nanocomposites with exfoliated structure could be synthesized using the intercalated catalyst described above, even when the content of MMT was very high (more than 15.1 wt%). The as-produced PE/F-MMTs nanocomposites were composed of flower-like particles with a diameter of about 5 pm. A thermal stable monoclinic phase was observed in PE/F-MMT nanocomposites. Comparatively, the resultant PE/F-MMT nanocomposites showed low gas permeability. Interfacial interaction between PE matrix and F-MMT was enhanced due to the chemical linking between the two components via copolymerization of ethylene with vinyl group of F-MMT. Thus the resultant PE/F-MMT nanocomposites showed good structural stability. (C) 2010 Elsevier Ltd. All rights reserved.

Found

Top-30

Journals

	1 2
Polymer Bulletin	Polymer Bulletin, 2, 10% Polymer Bulletin 2 publications, 10%
Polymers and Polymer Composites	Polymers and Polymer Composites, 1, 5% Polymers and Polymer Composites 1 publication, 5%
Journal of Polymer Research	Journal of Polymer Research, 1, 5% Journal of Polymer Research 1 publication, 5%
Materials Research Express	Materials Research Express, 1, 5% Materials Research Express 1 publication, 5%
Polymer	Polymer, 1, 5% Polymer 1 publication, 5%
Chinese Journal of Chemistry	Chinese Journal of Chemistry, 1, 5% Chinese Journal of Chemistry 1 publication, 5%
Macromolecular Rapid Communications	Macromolecular Rapid Communications, 1, 5% Macromolecular Rapid Communications 1 publication, 5%
ACS applied materials & interfaces	ACS applied materials & interfaces, 1, 5% ACS applied materials & interfaces 1 publication, 5%
Industrial & Engineering Chemistry Research	Industrial & Engineering Chemistry Research, 1, 5% Industrial & Engineering Chemistry Research 1 publication, 5%
Angewandte Chemie	Angewandte Chemie, 1, 5% Angewandte Chemie 1 publication, 5%
Angewandte Chemie - International Edition	Angewandte Chemie - International Edition, 1, 5% Angewandte Chemie - International Edition 1 publication, 5%
Polymer Science - Series A	Polymer Science - Series A, 1, 5% Polymer Science - Series A 1 publication, 5%
Journal of Macromolecular Science - Physics	Journal of Macromolecular Science - Physics, 1, 5% Journal of Macromolecular Science - Physics 1 publication, 5%
ACS Applied Polymer Materials	ACS Applied Polymer Materials, 1, 5% ACS Applied Polymer Materials 1 publication, 5%
Proceedings of SPIE - The International Society for Optical Engineering	Proceedings of SPIE - The International Society for Optical Engineering, 1, 5% Proceedings of SPIE - The International Society for Optical Engineering 1 publication, 5%
Polymer Reviews	Polymer Reviews, 1, 5% Polymer Reviews 1 publication, 5%
Russian Chemical Reviews	Russian Chemical Reviews, 1, 5% Russian Chemical Reviews 1 publication, 5%
	1 2

Publishers

	1 2 3 4 5
Wiley	Wiley, 5, 25% Wiley 5 publications, 25%
Springer Nature	Springer Nature, 3, 15% Springer Nature 3 publications, 15%
American Chemical Society (ACS)	American Chemical Society (ACS), 3, 15% American Chemical Society (ACS) 3 publications, 15%
Taylor & Francis	Taylor & Francis, 2, 10% Taylor & Francis 2 publications, 10%
SAGE	SAGE, 1, 5% SAGE 1 publication, 5%
IOP Publishing	IOP Publishing, 1, 5% IOP Publishing 1 publication, 5%
Elsevier	Elsevier, 1, 5% Elsevier 1 publication, 5%
Pleiades Publishing	Pleiades Publishing, 1, 5% Pleiades Publishing 1 publication, 5%
SPIE-Intl Soc Optical Eng	SPIE-Intl Soc Optical Eng, 1, 5% SPIE-Intl Soc Optical Eng 1 publication, 5%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 5% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 5%
	1 2 3 4 5

We do not take into account publications without a DOI.
Statistics recalculated weekly.

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.

Metrics

Cite this

GOST |

Cite this

GOST Copy

Ren C. et al. Preparation of multifunctional supported metallocene catalyst using organic multifunctional modifier for synthesizing polyethylene/clay nanocomposites via in situ intercalative polymerization // Polymer. 2010. Vol. 51. No. 15. pp. 3416-3424.

GOST all authors (up to 50) Copy

Ren C., Du X., Ma L., Wang Y., Zheng J., Tang T. Preparation of multifunctional supported metallocene catalyst using organic multifunctional modifier for synthesizing polyethylene/clay nanocomposites via in situ intercalative polymerization // Polymer. 2010. Vol. 51. No. 15. pp. 3416-3424.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1016/j.polymer.2010.05.041

UR - https://doi.org/10.1016/j.polymer.2010.05.041

TI - Preparation of multifunctional supported metallocene catalyst using organic multifunctional modifier for synthesizing polyethylene/clay nanocomposites via in situ intercalative polymerization

T2 - Polymer

AU - Ren, Changyi

AU - Du, Xiaohua

AU - Ma, Li

AU - Wang, Yanhui

AU - Zheng, Jun

AU - Tang, Tao

PY - 2010

DA - 2010/07/01

PB - Elsevier

SP - 3416-3424

IS - 15

VL - 51

SN - 0032-3861

SN - 1873-2291

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2010_Ren,

author = {Changyi Ren and Xiaohua Du and Li Ma and Yanhui Wang and Jun Zheng and Tao Tang},

title = {Preparation of multifunctional supported metallocene catalyst using organic multifunctional modifier for synthesizing polyethylene/clay nanocomposites via in situ intercalative polymerization},

journal = {Polymer},

year = {2010},

volume = {51},

publisher = {Elsevier},

month = {jul},

url = {https://doi.org/10.1016/j.polymer.2010.05.041},

number = {15},

pages = {3416--3424},

doi = {10.1016/j.polymer.2010.05.041}

}

MLA

Cite this

MLA Copy

Ren, Changyi, et al. “Preparation of multifunctional supported metallocene catalyst using organic multifunctional modifier for synthesizing polyethylene/clay nanocomposites via in situ intercalative polymerization.” Polymer, vol. 51, no. 15, Jul. 2010, pp. 3416-3424. https://doi.org/10.1016/j.polymer.2010.05.041.

Publisher

Elsevier

Journal

Polymer

scimago Q1

wos Q2

SJR

0.843

CiteScore

7.7

Impact factor

4.5

ISSN

00323861 (Print)

18732291