Ethylene/hexene living copolymerization and ethylene/methyl 10-undecenoate copolymerization by titanium complexes bearing phenoxy-phosphine or thiophenoxy-phosphine ligands
Publication type: Journal Article
Publication date: 2010-09-01
scimago Q1
wos Q2
SJR: 0.843
CiteScore: 7.7
Impact factor: 4.5
ISSN: 00323861, 18732291
Materials Chemistry
Organic Chemistry
Polymers and Plastics
Abstract
Several non-metallocene-type titanium(IV) complexes containing phenoxy-phosphine or thiophenoxy-phosphine ligands of type, (2-R-1-4-R-2-6-PPh2-C6H2X)(2)TiCl2 (2a: X O, R-1 = R-2 = t-Bu; 2b X = O, R-1 = R-2 = cumyl, 2c X = S, R-1 = SiMe3, R-2 - H) have been synthesized by treating TiCl4 with the corresponding ligands 2-R-1-4-R-2-6-PPh2-C6H2XH in the presence of n-BuLi The complexes 2a-c were investigated as the catalysts for ethylene with 1-hexene and/or polar alkenes copolymerizations The catalytic activity and the comonomer incorporation were highly dependent upon catalyst and reaction conditions employed Among these complexes, 2a can not only promote ethylene/1-hexene living copolymerization at room temperature, but also can utilize ethylene with methyl 10-undecenoate copolymerization (C) 2010 Elsevier Ltd All rights reserved
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GOST
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He L. et al. Ethylene/hexene living copolymerization and ethylene/methyl 10-undecenoate copolymerization by titanium complexes bearing phenoxy-phosphine or thiophenoxy-phosphine ligands // Polymer. 2010. Vol. 51. No. 19. pp. 4336-4339.
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He L., MIAO H., Li B., Liu J., Li Y. Ethylene/hexene living copolymerization and ethylene/methyl 10-undecenoate copolymerization by titanium complexes bearing phenoxy-phosphine or thiophenoxy-phosphine ligands // Polymer. 2010. Vol. 51. No. 19. pp. 4336-4339.
Cite this
RIS
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TY - JOUR
DO - 10.1016/j.polymer.2010.07.038
UR - https://doi.org/10.1016/j.polymer.2010.07.038
TI - Ethylene/hexene living copolymerization and ethylene/methyl 10-undecenoate copolymerization by titanium complexes bearing phenoxy-phosphine or thiophenoxy-phosphine ligands
T2 - Polymer
AU - He, Lipeng
AU - MIAO, HONG
AU - Li, Bai-Xiang
AU - Liu, Jing-Yu
AU - Li, Yue-Sheng
PY - 2010
DA - 2010/09/01
PB - Elsevier
SP - 4336-4339
IS - 19
VL - 51
SN - 0032-3861
SN - 1873-2291
ER -
Cite this
BibTex (up to 50 authors)
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@article{2010_He,
author = {Lipeng He and HONG MIAO and Bai-Xiang Li and Jing-Yu Liu and Yue-Sheng Li},
title = {Ethylene/hexene living copolymerization and ethylene/methyl 10-undecenoate copolymerization by titanium complexes bearing phenoxy-phosphine or thiophenoxy-phosphine ligands},
journal = {Polymer},
year = {2010},
volume = {51},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016/j.polymer.2010.07.038},
number = {19},
pages = {4336--4339},
doi = {10.1016/j.polymer.2010.07.038}
}
Cite this
MLA
Copy
He, Lipeng, et al. “Ethylene/hexene living copolymerization and ethylene/methyl 10-undecenoate copolymerization by titanium complexes bearing phenoxy-phosphine or thiophenoxy-phosphine ligands.” Polymer, vol. 51, no. 19, Sep. 2010, pp. 4336-4339. https://doi.org/10.1016/j.polymer.2010.07.038.