Synthesis and properties of hydroxylated core-fluorinated diamines and polyurethanes based on them with azobenzene nonlinear optical chromophores in the backbone
Тип публикации: Journal Article
Дата публикации: 2013-11-01
scimago Q1
wos Q2
БС1
SJR: 0.843
CiteScore: 7.7
Impact factor: 4.5
ISSN: 00323861, 18732291
Materials Chemistry
Organic Chemistry
Polymers and Plastics
Краткое описание
We report on the synthesis of core-fluorinated phenylene- and biphenyldianilines, which was accomplished by diazotization reaction of diamines followed by coupling of the obtained diazonium salts with 2-[ethyl(phenyl)amino]-ethanol. Two types of core-fluorinated aromatic units were used in a molecular design of azo-chromophore monomers with enhanced second order nonlinear optical (NLO) properties: octafluorobiphenyl (OFB) and tetrafluorobenzene (TFB) ones. Polymerization of the monomers was performed to obtain polyurethanes with azo-chromophores in the main chain. Comparison of physical and optical properties of these polymers reveals that the main factor influencing the observed NLO activity of the latter is the inherent isomery of the macromolecular chains rather than a variation of the structure of electron-accepting groups.
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Shevchenko V. et al. Synthesis and properties of hydroxylated core-fluorinated diamines and polyurethanes based on them with azobenzene nonlinear optical chromophores in the backbone // Polymer. 2013. Vol. 54. No. 24. pp. 6516-6525.
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Shevchenko V., Sidorenko A., Bliznyuk V., Tkachenko I. M., Shekera O. V., Smirnov N. N., Maslyanitsyn I., Shigorin V. D., Yakimansky A. V., Tsukruk V. V. Synthesis and properties of hydroxylated core-fluorinated diamines and polyurethanes based on them with azobenzene nonlinear optical chromophores in the backbone // Polymer. 2013. Vol. 54. No. 24. pp. 6516-6525.
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TY - JOUR
DO - 10.1016/j.polymer.2013.09.053
UR - https://doi.org/10.1016/j.polymer.2013.09.053
TI - Synthesis and properties of hydroxylated core-fluorinated diamines and polyurethanes based on them with azobenzene nonlinear optical chromophores in the backbone
T2 - Polymer
AU - Shevchenko, V.V.
AU - Sidorenko, Anatolie
AU - Bliznyuk, Valery
AU - Tkachenko, Ihor M
AU - Shekera, O V
AU - Smirnov, N. N.
AU - Maslyanitsyn, I.A
AU - Shigorin, V. D.
AU - Yakimansky, Alexander V.
AU - Tsukruk, Vladimir V.
PY - 2013
DA - 2013/11/01
PB - Elsevier
SP - 6516-6525
IS - 24
VL - 54
SN - 0032-3861
SN - 1873-2291
ER -
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@article{2013_Shevchenko,
author = {V.V. Shevchenko and Anatolie Sidorenko and Valery Bliznyuk and Ihor M Tkachenko and O V Shekera and N. N. Smirnov and I.A Maslyanitsyn and V. D. Shigorin and Alexander V. Yakimansky and Vladimir V. Tsukruk},
title = {Synthesis and properties of hydroxylated core-fluorinated diamines and polyurethanes based on them with azobenzene nonlinear optical chromophores in the backbone},
journal = {Polymer},
year = {2013},
volume = {54},
publisher = {Elsevier},
month = {nov},
url = {https://doi.org/10.1016/j.polymer.2013.09.053},
number = {24},
pages = {6516--6525},
doi = {10.1016/j.polymer.2013.09.053}
}
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MLA
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Shevchenko, V.V., et al. “Synthesis and properties of hydroxylated core-fluorinated diamines and polyurethanes based on them with azobenzene nonlinear optical chromophores in the backbone.” Polymer, vol. 54, no. 24, Nov. 2013, pp. 6516-6525. https://doi.org/10.1016/j.polymer.2013.09.053.