Microwave-assisted rapid one-step synthesis of poly(2-oxazoline)-based block copolymers using a dual initiator for CROP and RAFT polymerization
Publication type: Journal Article
Publication date: 2016-03-01
scimago Q1
wos Q2
SJR: 0.843
CiteScore: 7.7
Impact factor: 4.5
ISSN: 00323861, 18732291
Materials Chemistry
Organic Chemistry
Polymers and Plastics
Abstract
As the first example of the facile and rapid one-step synthesis of block copolymers, a range of poly (2-oxazoline) (POx)-based block copolymers were synthesized in a one-step procedure under microwave irradiation in a significantly shortened period of time using 4-cyano-4-(dodecylthiocarbonothioylthio)pentyl-4-methylbenzenesulfonate (CDPS) as a dual initiator for living cationic ring-opening polymerization (CROP) and reversible addition–fragmentation chain transfer (RAFT) polymerization. 2-Methyl- and 2-ethyl-2-oxazoline were polymerized for the POx block via CROP, and methyl acrylate, methyl methacrylate, N , N -dimethylacrylamide, N , N -diethylacrylamide, N -isopropylacrylamide, and 4-acryloylmorpholine were polymerized for the other block via RAFT polymerization. The CROP and RAFT polymerization proceeded independently in a controlled manner.
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13
Total citations:
13
Citations from 2025:
1
(7.69%)
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Kang M. et al. Microwave-assisted rapid one-step synthesis of poly(2-oxazoline)-based block copolymers using a dual initiator for CROP and RAFT polymerization // Polymer. 2016. Vol. 87. pp. 108-113.
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Kang M., LEE S., Shin H. H., Yu Y. C., Youk J. H. Microwave-assisted rapid one-step synthesis of poly(2-oxazoline)-based block copolymers using a dual initiator for CROP and RAFT polymerization // Polymer. 2016. Vol. 87. pp. 108-113.
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TY - JOUR
DO - 10.1016/j.polymer.2016.01.071
UR - https://doi.org/10.1016/j.polymer.2016.01.071
TI - Microwave-assisted rapid one-step synthesis of poly(2-oxazoline)-based block copolymers using a dual initiator for CROP and RAFT polymerization
T2 - Polymer
AU - Kang, Munhyung
AU - LEE, SOO-YOUNG
AU - Shin, Hwan Ho
AU - Yu, Young Chang
AU - Youk, Ji Ho
PY - 2016
DA - 2016/03/01
PB - Elsevier
SP - 108-113
VL - 87
SN - 0032-3861
SN - 1873-2291
ER -
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BibTex (up to 50 authors)
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@article{2016_Kang,
author = {Munhyung Kang and SOO-YOUNG LEE and Hwan Ho Shin and Young Chang Yu and Ji Ho Youk},
title = {Microwave-assisted rapid one-step synthesis of poly(2-oxazoline)-based block copolymers using a dual initiator for CROP and RAFT polymerization},
journal = {Polymer},
year = {2016},
volume = {87},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016/j.polymer.2016.01.071},
pages = {108--113},
doi = {10.1016/j.polymer.2016.01.071}
}