Environmental crazing and properties of mesoporous and nanocomposite materials based on poly(tetrafluoroethylene) films
Тип публикации: Journal Article
Дата публикации: 2019-01-01
scimago Q1
wos Q2
БС1
SJR: 0.843
CiteScore: 7.7
Impact factor: 4.5
ISSN: 00323861, 18732291
Materials Chemistry
Organic Chemistry
Polymers and Plastics
Краткое описание
Abstract The mechanism of environmental intercrystallite crazing (EIC) of semicrystalline poly(tetrafluoroethylene) (PTFE) films was studied. Stress-induced cavitation and fibrillation upon the EIC process provides the development of a marked porosity in PTFE (up to ∼40%) and pores with nanoscale dimensions (below 10 nm). Morphology and structural parameters of the mesoporous EIC PTFE samples were characterized, and the mechanism behind the EIC and low-temperature strain recovery of the EIC PTFE samples was proposed. The resultant mesoporous PTFE materials are shown to exhibit high chemical resistance, thermal stability, thermal conductivity, etc. The PTFE mesoporous materials can serve as matrices for diverse PTFE-based nanocomposite materials via the introduction and immobilization of various low-molecular-mass additives (alkali, metals, dyes). The bottom-up synthesis of silver nanoparticles within the mesoporous EIC PTFE as microreactors was described, and the structure of the silver-containing PTFE was characterized. Possible practical applications of the PTFE-based EIC nanomaterials were highlighted.
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Arzhakova O. V. et al. Environmental crazing and properties of mesoporous and nanocomposite materials based on poly(tetrafluoroethylene) films // Polymer. 2019. Vol. 161. pp. 151-161.
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Arzhakova O. V., Dolgova A. A., Volynskii A. L., Rukhlya E. G. Environmental crazing and properties of mesoporous and nanocomposite materials based on poly(tetrafluoroethylene) films // Polymer. 2019. Vol. 161. pp. 151-161.
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TY - JOUR
DO - 10.1016/j.polymer.2018.12.018
UR - https://doi.org/10.1016/j.polymer.2018.12.018
TI - Environmental crazing and properties of mesoporous and nanocomposite materials based on poly(tetrafluoroethylene) films
T2 - Polymer
AU - Arzhakova, O V
AU - Dolgova, A A
AU - Volynskii, Aleksandr L
AU - Rukhlya, Ekaterina G
PY - 2019
DA - 2019/01/01
PB - Elsevier
SP - 151-161
VL - 161
SN - 0032-3861
SN - 1873-2291
ER -
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@article{2019_Arzhakova,
author = {O V Arzhakova and A A Dolgova and Aleksandr L Volynskii and Ekaterina G Rukhlya},
title = {Environmental crazing and properties of mesoporous and nanocomposite materials based on poly(tetrafluoroethylene) films},
journal = {Polymer},
year = {2019},
volume = {161},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/j.polymer.2018.12.018},
pages = {151--161},
doi = {10.1016/j.polymer.2018.12.018}
}
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