Water structure and hydration of polymer network in PMEO2MA hydrogels
Publication type: Journal Article
Publication date: 2020-12-01
scimago Q1
wos Q2
SJR: 0.843
CiteScore: 7.7
Impact factor: 4.5
ISSN: 00323861, 18732291
Materials Chemistry
Organic Chemistry
Polymers and Plastics
Abstract
The hydration of amphiphilic polymers with some different hydrophilic centers, such as poly(2-(2-methoxyethoxy)ethyl methacrylate) (PMEO2MA), is important to understand well their thermo-responsivity. The PMEO2MA hydrogels with varying swelling degree, synthetized by radiation-induced cross-linking polymerization, has been investigated by ATR-FTIR supported by DFT calculations. This study broadens the knowledge about mechanism of hydration of PMEO2MA and explores the relationships between the water content in hydrogels, polymer-water, and water-water interactions. A complete picture of hydration processes of all hydrophilic centers (carbonyl and ether groups) was shown and correlated with water structure for the first time. It was found that firstly, small water clusters, and water bridges between the polymer segments are formed. Next, the bridges break and polymer chains start to separate. Finally, water tend to structure characteristic for bulk water. The obtained results may be an excellent basis for the analysis of local changes in PMEO2MA hydration during volume phase transition.
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35
Total citations:
35
Citations from 2025:
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(22.86%)
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GOST
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Piechocki K., Kozanecki M., Saramak J. Water structure and hydration of polymer network in PMEO2MA hydrogels // Polymer. 2020. Vol. 210. p. 122974.
GOST all authors (up to 50)
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Piechocki K., Kozanecki M., Saramak J. Water structure and hydration of polymer network in PMEO2MA hydrogels // Polymer. 2020. Vol. 210. p. 122974.
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RIS
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TY - JOUR
DO - 10.1016/j.polymer.2020.122974
UR - https://doi.org/10.1016/j.polymer.2020.122974
TI - Water structure and hydration of polymer network in PMEO2MA hydrogels
T2 - Polymer
AU - Piechocki, Krzysztof
AU - Kozanecki, M
AU - Saramak, Jakub
PY - 2020
DA - 2020/12/01
PB - Elsevier
SP - 122974
VL - 210
SN - 0032-3861
SN - 1873-2291
ER -
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BibTex (up to 50 authors)
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@article{2020_Piechocki,
author = {Krzysztof Piechocki and M Kozanecki and Jakub Saramak},
title = {Water structure and hydration of polymer network in PMEO2MA hydrogels},
journal = {Polymer},
year = {2020},
volume = {210},
publisher = {Elsevier},
month = {dec},
url = {https://doi.org/10.1016/j.polymer.2020.122974},
pages = {122974},
doi = {10.1016/j.polymer.2020.122974}
}