, volume 77 , issue 4 , pages 416-427

Structure and photochemistry of "bridged" bifunctional radical cations: Amidoesters vs. amides

Kirill B Nuzhdin ¹

Vladimir I. Feldman ^{2, 3}

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Department of Chemistry Moscow State University Moscow 119992 Russia |

Department of Chemistry, Moscow State University, Moscow 119992, Russia |

Institute of Synthetic Polymeric Materials, The Russian Academy of Sciences, 70 Profsoyuznaya Street, Moscow 117393, Russia |

Publication type: Journal Article

Publication date: 2008-04-01

Elsevier

Radiation Physics and Chemistry

scimago Q2

wos Q1

SJR: 0.543

CiteScore: 5.6

Impact factor: 3.3

ISSN: 0969806X, 18790895

DOI: 10.1016/j.radphyschem.2007.06.002

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Radiation

Abstract

Abstract Structure and properties of the radical cations of “bridged” amidoesters (functional groups separated by 0–4 methylene groups and the corresponding dimethyl-substituted amides) were investigated by EPR, optical absorption spectroscopy and DFT calculations. The EPR spectra and thermal reactions of these species are similar. Meanwhile, for amidoesters with 2–4 methylene groups, the methylene “bridge” is involved in photochemistry, which can be explained by specific conformation of amidoester radical cations determined by interaction between the functional groups.

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Tyurin Daniil

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PhD in Chemistry

69 publications, 680 citations

h-index: 15

Lomonosov Moscow State University

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Computational methods in chemistry

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Molecular spectroscopy

Non-covalent Interactions

Non-valent interactions

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Nuzhdin K. B. et al. Structure and photochemistry of "bridged" bifunctional radical cations: Amidoesters vs. amides // Radiation Physics and Chemistry. 2008. Vol. 77. No. 4. pp. 416-427.

GOST all authors (up to 50) Copy

Nuzhdin K. B., Feldman V. I. Structure and photochemistry of "bridged" bifunctional radical cations: Amidoesters vs. amides // Radiation Physics and Chemistry. 2008. Vol. 77. No. 4. pp. 416-427.

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TY - JOUR

DO - 10.1016/j.radphyschem.2007.06.002

UR - https://linkinghub.elsevier.com/retrieve/pii/S0969806X07002782

TI - Structure and photochemistry of "bridged" bifunctional radical cations: Amidoesters vs. amides

T2 - Radiation Physics and Chemistry

AU - Nuzhdin, Kirill B

AU - Feldman, Vladimir I.

PY - 2008

DA - 2008/04/01

PB - Elsevier

SP - 416-427

IS - 4

VL - 77

SN - 0969-806X

SN - 1879-0895

ER -

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@article{2008_Nuzhdin,

author = {Kirill B Nuzhdin and Vladimir I. Feldman},

title = {Structure and photochemistry of "bridged" bifunctional radical cations: Amidoesters vs. amides},

journal = {Radiation Physics and Chemistry},

year = {2008},

volume = {77},

publisher = {Elsevier},

month = {apr},

url = {https://linkinghub.elsevier.com/retrieve/pii/S0969806X07002782},

number = {4},

pages = {416--427},

doi = {10.1016/j.radphyschem.2007.06.002}

}

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Nuzhdin, Kirill B., et al. “Structure and photochemistry of "bridged" bifunctional radical cations: Amidoesters vs. amides.” Radiation Physics and Chemistry, vol. 77, no. 4, Apr. 2008, pp. 416-427. https://linkinghub.elsevier.com/retrieve/pii/S0969806X07002782.