Kinetics and mechanism of the radiation-chemical synthesis of krypton hydrides in solid krypton matrices
Publication type: Journal Article
Publication date: 2015-05-01
scimago Q2
wos Q1
SJR: 0.543
CiteScore: 5.6
Impact factor: 3.3
ISSN: 0969806X, 18790895
Radiation
Abstract
Abstract The processes occurring in the X-irradiated C2H2/Kr and HCl/Kr systems in the temperature range of 7–30 K were studied using a combination of FTIR and EPR spectroscopy. In both cases, irradiation results in effective decomposition of isolated molecules (C2H2 or HCl) and production of trapped H atoms. The thermal decay of trapped atoms in solid krypton was attributed to “local” reactions (below 21 K) and long-range mobility activated in the temperature range of 23–27 K. Two krypton hydrides, HKrCCH and HKrCl, were synthesized from the radiation-induced hydrogen atoms. In the case of C2H2/Kr system, competitive reaction channels of H atoms at various absorbed doses were investigated in details, and HKrCCH was found to be one of the main reaction products. The X-ray radiolysis in krypton matrices was concluded to be a promising method to obtain krypton hydrides.
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15
Total citations:
15
Citations from 2024:
1
(6%)
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Kameneva S. V. et al. Kinetics and mechanism of the radiation-chemical synthesis of krypton hydrides in solid krypton matrices // Radiation Physics and Chemistry. 2015. Vol. 110. pp. 17-23.
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Kameneva S. V., Kobzarenko A. V., Feldman V. I. Kinetics and mechanism of the radiation-chemical synthesis of krypton hydrides in solid krypton matrices // Radiation Physics and Chemistry. 2015. Vol. 110. pp. 17-23.
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TY - JOUR
DO - 10.1016/j.radphyschem.2015.01.007
UR - https://linkinghub.elsevier.com/retrieve/pii/S0969806X15000080
TI - Kinetics and mechanism of the radiation-chemical synthesis of krypton hydrides in solid krypton matrices
T2 - Radiation Physics and Chemistry
AU - Kameneva, Svetlana V
AU - Kobzarenko, Alexey V
AU - Feldman, Vladimir I.
PY - 2015
DA - 2015/05/01
PB - Elsevier
SP - 17-23
VL - 110
SN - 0969-806X
SN - 1879-0895
ER -
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@article{2015_Kameneva,
author = {Svetlana V Kameneva and Alexey V Kobzarenko and Vladimir I. Feldman},
title = {Kinetics and mechanism of the radiation-chemical synthesis of krypton hydrides in solid krypton matrices},
journal = {Radiation Physics and Chemistry},
year = {2015},
volume = {110},
publisher = {Elsevier},
month = {may},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0969806X15000080},
pages = {17--23},
doi = {10.1016/j.radphyschem.2015.01.007}
}
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