Radiation Physics and Chemistry

, volume 158 , pages 115-121

Radiation-induced synthesis of copper nanostructures in the films of interpolymer complexes

Elena Zezina ¹

Artem M. Emel’yanov ²

Alexander S. Pozdnyakov ²

Galina F Prozorova ²

Sergei S Abramchuk ¹

Vladimir I. Feldman ¹

A. Zezin ^{3, 4}

Hide authors affiliations Show authors affiliations: 4 affiliations

Department of Chemistry, Lomonosov Moscow State University, Moscow 119991, Russia. |

Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Favorskogo st., 1, Irkutsk 664033, Russia |

Department of Chemistry, Lomonosov Moscow State University, Moscow 119991, Russia |

⁴

Enikolopov Institute of Synthetic Polymeric Materials, A foundation of Russian Academy of Sciences, Profsoyuznaya st., 70, Moscow 117393, Russia |

Publication type: Journal Article

Publication date: 2019-05-01

Elsevier

Radiation Physics and Chemistry

scimago Q2

wos Q1

SJR: 0.543

CiteScore: 5.6

Impact factor: 3.3

ISSN: 0969806X, 18790895

DOI: 10.1016/j.radphyschem.2019.01.019

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Radiation

Abstract

Abstract The composites with localization of copper nanoparticles on the surface of interpolymer films were prepared by X-ray irradiation of poly(1-vinyl-1,2,4-triazole) – poly(acrylic acid) – Cu2+ complexes. The kinetics of radiation-chemical reduction of ions Cu2+ in films of stoichiometric and nonstoichiometric complexes of poly(1-vinyl-1,2,4-triazole) – poly(acrylic acid) (PVT – PAA) was studied by EPR. The use of transmission electron microscopy with micro-diffraction mode showed that the preparation of metal nanoparticles occurs through the intermediate formation of copper protoxide. The efficiency of nanoparticle formation is determined by the ratio PVT/PAA in interpolymer films. The contrast of X-ray absorption by water-alcohol medium and interpolymer complexes with copper ions provides the favorable conditions for the formation of metal nanostructures in the near-surface layer of the films.

Found

10 citations

Pozdnyakov Alexander

🥼 🤝

PhD in Chemistry

91 publications, 825 citations, 32 reviews

h-index: 16

A.E. Favorsky Irkutsk Institute of Chemistry of the Siberian Branch of the Russian Academy of Sciences

Research interests

Nanocomposites

Nanoparticles

8 citations

Emelyanov Artem

PhD in Chemistry

68 publications, 612 citations

h-index: 14

A.E. Favorsky Irkutsk Institute of Chemistry of the Siberian Branch of the Russian Academy of Sciences

1 citation

Smyslov Ruslan

78 publications, 474 citations

h-index: 11

Institute of Macromolecular Compounds of NRC «Kurchatov Institute»

National Research Centre "Kurchatov Institute"

Petersburg Nuclear Physics Institute of NRC «Kurchatov Institute»

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GOST Copy

Zezina E. et al. Radiation-induced synthesis of copper nanostructures in the films of interpolymer complexes // Radiation Physics and Chemistry. 2019. Vol. 158. pp. 115-121.

GOST all authors (up to 50) Copy

Zezina E., Emel’yanov A. M., Pozdnyakov A. S., Prozorova G. F., Abramchuk S. S., Feldman V. I., Zezin A. Radiation-induced synthesis of copper nanostructures in the films of interpolymer complexes // Radiation Physics and Chemistry. 2019. Vol. 158. pp. 115-121.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1016/j.radphyschem.2019.01.019

UR - https://linkinghub.elsevier.com/retrieve/pii/S0969806X18311770

TI - Radiation-induced synthesis of copper nanostructures in the films of interpolymer complexes

T2 - Radiation Physics and Chemistry

AU - Zezina, Elena

AU - Emel’yanov, Artem M.

AU - Pozdnyakov, Alexander S.

AU - Prozorova, Galina F

AU - Abramchuk, Sergei S

AU - Feldman, Vladimir I.

AU - Zezin, A.

PY - 2019

DA - 2019/05/01

PB - Elsevier

SP - 115-121

VL - 158

SN - 0969-806X

SN - 1879-0895

ER -

BibTex

Cite this

BibTex (up to 50 authors) Copy

@article{2019_Zezina,

author = {Elena Zezina and Artem M. Emel’yanov and Alexander S. Pozdnyakov and Galina F Prozorova and Sergei S Abramchuk and Vladimir I. Feldman and A. Zezin},

title = {Radiation-induced synthesis of copper nanostructures in the films of interpolymer complexes},

journal = {Radiation Physics and Chemistry},

year = {2019},

volume = {158},

publisher = {Elsevier},

month = {may},

url = {https://linkinghub.elsevier.com/retrieve/pii/S0969806X18311770},

pages = {115--121},

doi = {10.1016/j.radphyschem.2019.01.019}

}

Publisher

Elsevier

Journal

Radiation Physics and Chemistry

scimago Q2

wos Q1

SJR

0.543

CiteScore

5.6

Impact factor

3.3

ISSN

0969806X (Print)

18790895

Labs

Laboratory of High Energy Chemistry

Profiles