volume 59 issue 1 pages 33-39

Asymmetric hydrogenation of furfuryl alcohol catalyzed by a biopolymer–metal complex, silica-supported alginic acid–amino acid–Pt complex

Publication typeJournal Article
Publication date2004-04-01
scimago Q1
wos Q1
SJR0.876
CiteScore8.6
Impact factor5.1
ISSN13815148, 1873166X
Materials Chemistry
General Chemistry
Biochemistry
General Chemical Engineering
Polymers and Plastics
Environmental Chemistry
Abstract
A biopolymer containing metal complex, silica-supported alginic acid–amino acid ( l -alanine, l -glutamic acid, l -serine or l -lysine)–Pt complex, SiO 2 –AA–aa–Pt (SiO 2 –AA–ala–Pt, SiO 2 –AA–glu–Pt, SiO 2 –AA–ser–Pt, SiO 2 –AA–lys–Pt) has been prepared and found to be able to catalyze the asymmetric hydrogenation of furfuryl alcohol to give ( S )-(+)-tetrahydrofurfuryl alcohol at 30 °C and under 1 atmH 2 . Among of them, SiO 2 –AA–glu–Pt complex catalyst is most effective for this asymmetric reaction and 84.4% product yield and 98.3% ee optical yield can be obtained, respectively. This catalyst can be reused several times without large change in the optical catalytic activity.
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GOST |
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GOST Copy
Wei W. et al. Asymmetric hydrogenation of furfuryl alcohol catalyzed by a biopolymer–metal complex, silica-supported alginic acid–amino acid–Pt complex // Reactive and Functional Polymers. 2004. Vol. 59. No. 1. pp. 33-39.
GOST all authors (up to 50) Copy
Wei W., Zhu H., Zhao C., Huang M., Jiang Y. Asymmetric hydrogenation of furfuryl alcohol catalyzed by a biopolymer–metal complex, silica-supported alginic acid–amino acid–Pt complex // Reactive and Functional Polymers. 2004. Vol. 59. No. 1. pp. 33-39.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.reactfunctpolym.2003.10.004
UR - https://doi.org/10.1016/j.reactfunctpolym.2003.10.004
TI - Asymmetric hydrogenation of furfuryl alcohol catalyzed by a biopolymer–metal complex, silica-supported alginic acid–amino acid–Pt complex
T2 - Reactive and Functional Polymers
AU - Wei, Wei-Lin
AU - Zhu, Huan-Yan
AU - Zhao, Cui-Li
AU - Huang, Mei-Yu
AU - Jiang, Ying‐Yan
PY - 2004
DA - 2004/04/01
PB - Elsevier
SP - 33-39
IS - 1
VL - 59
SN - 1381-5148
SN - 1873-166X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2004_Wei,
author = {Wei-Lin Wei and Huan-Yan Zhu and Cui-Li Zhao and Mei-Yu Huang and Ying‐Yan Jiang},
title = {Asymmetric hydrogenation of furfuryl alcohol catalyzed by a biopolymer–metal complex, silica-supported alginic acid–amino acid–Pt complex},
journal = {Reactive and Functional Polymers},
year = {2004},
volume = {59},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016/j.reactfunctpolym.2003.10.004},
number = {1},
pages = {33--39},
doi = {10.1016/j.reactfunctpolym.2003.10.004}
}
MLA
Cite this
MLA Copy
Wei, Wei-Lin, et al. “Asymmetric hydrogenation of furfuryl alcohol catalyzed by a biopolymer–metal complex, silica-supported alginic acid–amino acid–Pt complex.” Reactive and Functional Polymers, vol. 59, no. 1, Apr. 2004, pp. 33-39. https://doi.org/10.1016/j.reactfunctpolym.2003.10.004.