Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, volume 218, pages 308-319

Luminescent properties of new 2,2-, 2,3- and 3,3-CH2-bis(BODIPY)s dyes: Structural and solvation effects

Publication typeJournal Article
Publication date2019-07-01
Quartile SCImago
Q2
Quartile WOS
Q1
Impact factor4.4
ISSN13861425
Spectroscopy
Analytical Chemistry
Atomic and Molecular Physics, and Optics
Instrumentation
Abstract
In this paper the synthesis and spectral properties of three new dimeric bis (BODIPY)s with two indacene domains connected by a methylene (–CH 2 –) spacer at 2,2-, 2,3- or 3,3- positions were reported. It was found bis (BODIPY)s exhibit a high sensitivity of fluorescence to the medium properties. To interpret solvatochromic effects of bis (BODIPY)s, a multilinear correlation analysis of bis (BODIPY)s fluorescence quantum yields with respect to solvent different parameters was carried out. To understand the features of the spectral properties of bis (BODIPY)s, we carried out a thorough quantum-chemical analysis of the structural, conformational, and spectral characteristics of bis (BODIPY)s. The obtained bis (BODIPY)s have a high potential for application as sensors of medium polarity. • New bis (BODIPY)s were synthesized. • The bis (BODIPY)s show a high fluorescence characteristics sensitivity to the media nature. • The bis (BODIPY)s have conformational invariance.

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Antina E. V. et al. Luminescent properties of new 2,2-, 2,3- and 3,3-CH2-bis(BODIPY)s dyes: Structural and solvation effects // Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy. 2019. Vol. 218. pp. 308-319.
GOST all authors (up to 50) Copy
Antina E. V., Ksenofontov A. A., Kalyagin A. A., Berezin M. B., Antina L. A., Khodov I. A., Ksenofontov A., Berezin M. Y., Khodov I. A. Luminescent properties of new 2,2-, 2,3- and 3,3-CH2-bis(BODIPY)s dyes: Structural and solvation effects // Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy. 2019. Vol. 218. pp. 308-319.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.saa.2019.03.117
UR - https://doi.org/10.1016%2Fj.saa.2019.03.117
TI - Luminescent properties of new 2,2-, 2,3- and 3,3-CH2-bis(BODIPY)s dyes: Structural and solvation effects
T2 - Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
AU - Antina, Elena V
AU - Ksenofontov, Alexander A
AU - Kalyagin, Alexander A
AU - Berezin, Mikhail B
AU - Antina, Lyubov A
AU - Khodov, Ilya A.
AU - Ksenofontov, A.L.
AU - Berezin, Mikhail Y.
AU - Khodov, Ilya A.
PY - 2019
DA - 2019/07/01 00:00:00
PB - Elsevier
SP - 308-319
VL - 218
SN - 1386-1425
ER -
BibTex
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BibTex Copy
@article{2019_Antina,
author = {Elena V Antina and Alexander A Ksenofontov and Alexander A Kalyagin and Mikhail B Berezin and Lyubov A Antina and Ilya A. Khodov and A.L. Ksenofontov and Mikhail Y. Berezin and Ilya A. Khodov},
title = {Luminescent properties of new 2,2-, 2,3- and 3,3-CH2-bis(BODIPY)s dyes: Structural and solvation effects},
journal = {Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy},
year = {2019},
volume = {218},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016%2Fj.saa.2019.03.117},
pages = {308--319},
doi = {10.1016/j.saa.2019.03.117}
}
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