Scripta Materialia, volume 162, pages 214-218

Mg-doping towards enhancing the composition-phase-structural stability of Li-La-zirconate based cubic garnet upon exposure to air

Amardeep ¹

Sushobhan Kobi ¹

Amartya Mukhopadhyay ¹

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High Temperature and Energy Materials Laboratory, Department of Metallurgical Engineering and Materials Science, Indian Institute of Technology (IIT) Bombay, Mumbai, India |

Publication type: Journal Article

Publication date: 2019-03-01

Elsevier

Journal: Scripta Materialia

Quartile SCImago

Quartile WOS

Impact factor: 6

ISSN: 13596462

DOI: 10.1016/j.scriptamat.2018.11.026

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Metals and Alloys

Condensed Matter Physics

General Materials Science

Mechanical Engineering

Mechanics of Materials

Abstract

Mg, as a new dopant, has been found to stabilize the desired cubic garnet structure (Ia 3 ¯ d) of Li-La-zirconate (LLZO) and lead to Li-ion conductivities similar to those obtained with the same level of Al-doping. More importantly, Mg-doping, as opposed to Al-doping, suppresses the deleterious reactions with the atmospheric moisture/CO2, leading to stability in the composition-phase-structure upon exposure to air. Accordingly, when exposed to air, even though Al-doped LLZO pellets get spontaneously fractured/disintegrated, accompanied by reduction in ionic conductivity by ~3 orders of magnitude, Mg-doped LLZO shows no sign of cracking and almost retains the ionic conductivity measured prior to exposure.

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Chemistry of Materials	Chemistry of Materials, 1, 3.85% Chemistry of Materials 1 publication, 3.85%
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Jurnal Kimia Sains dan Aplikasi	Jurnal Kimia Sains dan Aplikasi, 1, 3.85% Jurnal Kimia Sains dan Aplikasi 1 publication, 3.85%
AIP Conference Proceedings	AIP Conference Proceedings, 1, 3.85% AIP Conference Proceedings 1 publication, 3.85%
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Energy & Fuels	Energy & Fuels, 1, 3.85% Energy & Fuels 1 publication, 3.85%
Advanced Science	Advanced Science, 1, 3.85% Advanced Science 1 publication, 3.85%
Journal of Physical Chemistry C	Journal of Physical Chemistry C, 1, 3.85% Journal of Physical Chemistry C 1 publication, 3.85%
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Citations by publishers

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Elsevier	Elsevier, 7, 26.92% Elsevier 7 publications, 26.92%
American Chemical Society (ACS)	American Chemical Society (ACS), 6, 23.08% American Chemical Society (ACS) 6 publications, 23.08%
Wiley	Wiley, 5, 19.23% Wiley 5 publications, 19.23%
Springer Nature	Springer Nature, 2, 7.69% Springer Nature 2 publications, 7.69%
The Electrochemical Society	The Electrochemical Society, 1, 3.85% The Electrochemical Society 1 publication, 3.85%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 1, 3.85% Royal Society of Chemistry (RSC) 1 publication, 3.85%
Institute of Research and Community Services Diponegoro University (LPPM UNDIP)	Institute of Research and Community Services Diponegoro University (LPPM UNDIP), 1, 3.85% Institute of Research and Community Services Diponegoro University (LPPM UNDIP) 1 publication, 3.85%
American Institute of Physics (AIP)	American Institute of Physics (AIP), 1, 3.85% American Institute of Physics (AIP) 1 publication, 3.85%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 1, 3.85% Multidisciplinary Digital Publishing Institute (MDPI) 1 publication, 3.85%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 3.85% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 3.85%
	1 2 3 4 5 6 7

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Amardeep, Kobi S., Mukhopadhyay A. Mg-doping towards enhancing the composition-phase-structural stability of Li-La-zirconate based cubic garnet upon exposure to air // Scripta Materialia. 2019. Vol. 162. pp. 214-218.

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TY - JOUR

DO - 10.1016/j.scriptamat.2018.11.026

UR - https://doi.org/10.1016/j.scriptamat.2018.11.026

TI - Mg-doping towards enhancing the composition-phase-structural stability of Li-La-zirconate based cubic garnet upon exposure to air

T2 - Scripta Materialia

AU - Amardeep

AU - Kobi, Sushobhan

AU - Mukhopadhyay, Amartya

PY - 2019

DA - 2019/03/01 00:00:00

PB - Elsevier

SP - 214-218

VL - 162

SN - 1359-6462

ER -

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@article{2019_Amardeep,

author = {Amardeep and Sushobhan Kobi and Amartya Mukhopadhyay},

title = {Mg-doping towards enhancing the composition-phase-structural stability of Li-La-zirconate based cubic garnet upon exposure to air},

journal = {Scripta Materialia},

year = {2019},

volume = {162},

publisher = {Elsevier},

month = {mar},

url = {https://doi.org/10.1016/j.scriptamat.2018.11.026},

pages = {214--218},

doi = {10.1016/j.scriptamat.2018.11.026}

}

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Elsevier

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Scripta Materialia

Quartile SCImago

Quartile WOS

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13596462 (Print)