volume 63 issue 3 pages 710-715

Highly efficient extraction of phenols and aromatic amines into novel ionic liquids incorporating quaternary ammonium cation

Publication typeJournal Article
Publication date2008-11-01
scimago Q1
wos Q1
SJR1.697
CiteScore15.1
Impact factor9.0
ISSN13835866, 18733794
Analytical Chemistry
Filtration and Separation
Abstract
Abstract Two novel hydrophobic room temperature ionic liquids (RTIL) incorporating quaternary ammonium cations: tetrahexylammonium dihexylsulfosuccinate (THADHSS) and trioctylmethylammonium salicylate (TOMAS) have been obtained. The mutual solubility of the both RTILs with water and their Reichardt's polarity index have been measured. The extraction of aromatic amines and phenols into novel RTILs and two 1-alkyl-3-methylimidazolium bis (trifluoromethanesulfonyl)amides has been studied. The dependences of RTIL–water distribution ratio for the studied liquids on the phase volume ratio, the time of phase contact, pH value of aqueous solutions and the solute concentration have been obtained. In some cases, the solute distribution ratios for ammonium-based RTILs are as high as n  × 10 4 that is much greater than for imidazolium ones. Notably, unlike the case of imidazolium-based RTILs, the quantitative extraction into ammonium RTILs is achieved even at the phase volume ratio V RTIL : V w  = 1:20.
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GOST |
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GOST Copy
Egorov V. V. et al. Highly efficient extraction of phenols and aromatic amines into novel ionic liquids incorporating quaternary ammonium cation // Separation and Purification Technology. 2008. Vol. 63. No. 3. pp. 710-715.
GOST all authors (up to 50) Copy
Egorov V. V., Smirnova S. V., Pletnev I. V. Highly efficient extraction of phenols and aromatic amines into novel ionic liquids incorporating quaternary ammonium cation // Separation and Purification Technology. 2008. Vol. 63. No. 3. pp. 710-715.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.seppur.2008.06.024
UR - https://linkinghub.elsevier.com/retrieve/pii/S1383586608002682
TI - Highly efficient extraction of phenols and aromatic amines into novel ionic liquids incorporating quaternary ammonium cation
T2 - Separation and Purification Technology
AU - Egorov, Vladimir V.
AU - Smirnova, Svetlana V
AU - Pletnev, Igor V
PY - 2008
DA - 2008/11/01
PB - Elsevier
SP - 710-715
IS - 3
VL - 63
SN - 1383-5866
SN - 1873-3794
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2008_Egorov,
author = {Vladimir V. Egorov and Svetlana V Smirnova and Igor V Pletnev},
title = {Highly efficient extraction of phenols and aromatic amines into novel ionic liquids incorporating quaternary ammonium cation},
journal = {Separation and Purification Technology},
year = {2008},
volume = {63},
publisher = {Elsevier},
month = {nov},
url = {https://linkinghub.elsevier.com/retrieve/pii/S1383586608002682},
number = {3},
pages = {710--715},
doi = {10.1016/j.seppur.2008.06.024}
}
MLA
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MLA Copy
Egorov, Vladimir V., et al. “Highly efficient extraction of phenols and aromatic amines into novel ionic liquids incorporating quaternary ammonium cation.” Separation and Purification Technology, vol. 63, no. 3, Nov. 2008, pp. 710-715. https://linkinghub.elsevier.com/retrieve/pii/S1383586608002682.