Sensors and Actuators, B: Chemical, volume 230, pages 434-441
Phosphorescent oxygen sensors produced from polyolefin fibres by solvent-crazing method
1
School of Biochemistry and Cell Biology, University College Cork, Cavanagh Pharmacy Building, Cork, Ireland
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2
Faculty of Chemistry, Lomonosov Moscow State University, Leninskie Gory, Moscow 119991, Russian Federation
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Publication type: Journal Article
Publication date: 2016-07-01
Journal:
Sensors and Actuators, B: Chemical
Q1
Q1
SJR: 1.475
CiteScore: 14.6
Impact factor: 8
ISSN: 09254005
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Electrical and Electronic Engineering
Instrumentation
Abstract
Development of phosphorescent oxygen sensing materials based on commercially available semicrystalline polymer fibres (polyolefins, PP and PE) is described. The Pt-benzoporphyrin dye was incorporated into the nanoporous network of polyolefin fibres formed upon tensile drawing in the presence of physically active liquid environment via the mechanism of solvent crazing. Optimised fibre sensors showed optimal sensitivity to O2, stable calibration in the range of 0–21 kPa O2, reversible operation, linear temperature dependence and no significant cross-sensitivity towards humidity. The high surface area to volume ratio of the solvent-crazed polymer fibres enabled relatively bright phosphorescence intensity signals and fast response. Widefield and confocal microscopy combined with lifetime imaging were used to investigate the fine structure, dye distribution and heterogeneity of quenching by O2 in the solvent-crazed dye-containing polymer fibres.
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Banerjee S. et al. Phosphorescent oxygen sensors produced from polyolefin fibres by solvent-crazing method // Sensors and Actuators, B: Chemical. 2016. Vol. 230. pp. 434-441.
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Banerjee S., Arzhakova O. V., Dolgova A. A., Papkovsky D. Phosphorescent oxygen sensors produced from polyolefin fibres by solvent-crazing method // Sensors and Actuators, B: Chemical. 2016. Vol. 230. pp. 434-441.
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TY - JOUR
DO - 10.1016/j.snb.2016.02.062
UR - https://linkinghub.elsevier.com/retrieve/pii/S0925400516302118
TI - Phosphorescent oxygen sensors produced from polyolefin fibres by solvent-crazing method
T2 - Sensors and Actuators, B: Chemical
AU - Banerjee, Swagata
AU - Arzhakova, O V
AU - Dolgova, A A
AU - Papkovsky, Dmitri
PY - 2016
DA - 2016/07/01
PB - Elsevier
SP - 434-441
VL - 230
SN - 0925-4005
ER -
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@article{2016_Banerjee,
author = {Swagata Banerjee and O V Arzhakova and A A Dolgova and Dmitri Papkovsky},
title = {Phosphorescent oxygen sensors produced from polyolefin fibres by solvent-crazing method},
journal = {Sensors and Actuators, B: Chemical},
year = {2016},
volume = {230},
publisher = {Elsevier},
month = {jul},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0925400516302118},
pages = {434--441},
doi = {10.1016/j.snb.2016.02.062}
}
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