Solid State Ionics, volume 177, issue 26-32, pages 2721-2725

High lithium ion conducting glass-ceramics in the system Li2S–P2S5

Fuminori Mizuno ¹

Akitoshi Hayashi ¹

Kiyoharu Tadanaga ¹

Masahiro Tatsumisago ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

Department of Applied Chemistry, Graduate School of Engineering Osaka Prefecture University 1-1, Gakuen-cho, Sakai, Osaka 599-8531, Japan |

Publication type: Journal Article

Publication date: 2006-10-01

Elsevier

Journal: Solid State Ionics

Quartile SCImago

Quartile WOS

Impact factor: 3.2

ISSN: 01672738

DOI: 10.1016/j.ssi.2006.04.017

Copy DOI

General Chemistry

Condensed Matter Physics

General Materials Science

Abstract

Highly ion-conductive Li2S–P2S5 glass-ceramic electrolytes were prepared by controlling the compositions and heat treatment temperatures of the glasses. The 70Li2S·30P2S5 (mol%) glass-ceramic heated at 360 °C showed the highest conductivity of 3.2 × 10− 3 S cm− 1 at room temperature and the lowest activation energy of 12 kJ mol− 1 for conduction in the binary system Li2S–P2S5. The outstanding property was attributed to both the precipitation of the new crystal as a metastable phase and the increase in crystallinity of the phase. With increasing heat treatment temperatures, the metastable phase changed into thermodynamically stable phases such as the Li4P2S6 crystal by heat treatment up to 550 °C, resulting in low conductivities of the glass-ceramics. It was, thus, found that the formation of superionic metastable phases by heating the Li2S–P2S5 glasses is responsible for the marked enhancement on the conducting properties of the glass-ceramics.

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Citations by journals

	5 10 15 20 25
Solid State Ionics	Solid State Ionics, 24, 8.19% Solid State Ionics 24 publications, 8.19%
Journal of Power Sources	Journal of Power Sources, 17, 5.8% Journal of Power Sources 17 publications, 5.8%
Journal of the Electrochemical Society	Journal of the Electrochemical Society, 13, 4.44% Journal of the Electrochemical Society 13 publications, 4.44%
ACS applied materials & interfaces	ACS applied materials & interfaces, 10, 3.41% ACS applied materials & interfaces 10 publications, 3.41%
Chemistry of Materials	Chemistry of Materials, 8, 2.73% Chemistry of Materials 8 publications, 2.73%
Electrochimica Acta	Electrochimica Acta, 8, 2.73% Electrochimica Acta 8 publications, 2.73%
Journal of Materials Chemistry A	Journal of Materials Chemistry A, 8, 2.73% Journal of Materials Chemistry A 8 publications, 2.73%
Advanced Energy Materials	Advanced Energy Materials, 7, 2.39% Advanced Energy Materials 7 publications, 2.39%
Energy Storage Materials	Energy Storage Materials, 6, 2.05% Energy Storage Materials 6 publications, 2.05%
Journal of Non-Crystalline Solids	Journal of Non-Crystalline Solids, 6, 2.05% Journal of Non-Crystalline Solids 6 publications, 2.05%
Electrochemistry	Electrochemistry, 5, 1.71% Electrochemistry 5 publications, 1.71%
Journal of Solid State Electrochemistry	Journal of Solid State Electrochemistry, 5, 1.71% Journal of Solid State Electrochemistry 5 publications, 1.71%
Journal of the American Ceramic Society	Journal of the American Ceramic Society, 5, 1.71% Journal of the American Ceramic Society 5 publications, 1.71%
Journal of Physical Chemistry C	Journal of Physical Chemistry C, 5, 1.71% Journal of Physical Chemistry C 5 publications, 1.71%
RSC Advances	RSC Advances, 5, 1.71% RSC Advances 5 publications, 1.71%
Energy & Fuels	Energy & Fuels, 4, 1.37% Energy & Fuels 4 publications, 1.37%
Chemical Engineering Journal	Chemical Engineering Journal, 4, 1.37% Chemical Engineering Journal 4 publications, 1.37%
ACS Energy Letters	ACS Energy Letters, 3, 1.02% ACS Energy Letters 3 publications, 1.02%
Journal of the Ceramic Society of Japan	Journal of the Ceramic Society of Japan, 3, 1.02% Journal of the Ceramic Society of Japan 3 publications, 1.02%
Frontiers in Energy Research	Frontiers in Energy Research, 3, 1.02% Frontiers in Energy Research 3 publications, 1.02%
Scientific Reports	Scientific Reports, 3, 1.02% Scientific Reports 3 publications, 1.02%
Advanced Materials	Advanced Materials, 3, 1.02% Advanced Materials 3 publications, 1.02%
ACS Applied Energy Materials	ACS Applied Energy Materials, 3, 1.02% ACS Applied Energy Materials 3 publications, 1.02%
Journal of Energy Storage	Journal of Energy Storage, 2, 0.68% Journal of Energy Storage 2 publications, 0.68%
Functional Materials Letters	Functional Materials Letters, 2, 0.68% Functional Materials Letters 2 publications, 0.68%
Nano Research	Nano Research, 2, 0.68% Nano Research 2 publications, 0.68%
Journal of Materials Science	Journal of Materials Science, 2, 0.68% Journal of Materials Science 2 publications, 0.68%
Nature Communications	Nature Communications, 2, 0.68% Nature Communications 2 publications, 0.68%
Materials Today Energy	Materials Today Energy, 2, 0.68% Materials Today Energy 2 publications, 0.68%
	5 10 15 20 25

Citations by publishers

	20 40 60 80 100 120
Elsevier	Elsevier, 103, 35.15% Elsevier 103 publications, 35.15%
Wiley	Wiley, 40, 13.65% Wiley 40 publications, 13.65%
American Chemical Society (ACS)	American Chemical Society (ACS), 39, 13.31% American Chemical Society (ACS) 39 publications, 13.31%
Springer Nature	Springer Nature, 23, 7.85% Springer Nature 23 publications, 7.85%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 23, 7.85% Royal Society of Chemistry (RSC) 23 publications, 7.85%
The Electrochemical Society	The Electrochemical Society, 13, 4.44% The Electrochemical Society 13 publications, 4.44%
The Electrochemical Society of Japan	The Electrochemical Society of Japan, 5, 1.71% The Electrochemical Society of Japan 5 publications, 1.71%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 4, 1.37% Multidisciplinary Digital Publishing Institute (MDPI) 4 publications, 1.37%
American Physical Society (APS)	American Physical Society (APS), 3, 1.02% American Physical Society (APS) 3 publications, 1.02%
Ceramic Society of Japan	Ceramic Society of Japan, 3, 1.02% Ceramic Society of Japan 3 publications, 1.02%
Frontiers Media S.A.	Frontiers Media S.A., 3, 1.02% Frontiers Media S.A. 3 publications, 1.02%
American Institute of Physics (AIP)	American Institute of Physics (AIP), 2, 0.68% American Institute of Physics (AIP) 2 publications, 0.68%
World Scientific	World Scientific, 2, 0.68% World Scientific 2 publications, 0.68%
Materials Research Society	Materials Research Society, 2, 0.68% Materials Research Society 2 publications, 0.68%
IOP Publishing	IOP Publishing, 2, 0.68% IOP Publishing 2 publications, 0.68%
Taylor & Francis	Taylor & Francis, 2, 0.68% Taylor & Francis 2 publications, 0.68%
Oxford University Press	Oxford University Press, 2, 0.68% Oxford University Press 2 publications, 0.68%
American Vacuum Society	American Vacuum Society, 1, 0.34% American Vacuum Society 1 publication, 0.34%
The Chemical Society of Japan	The Chemical Society of Japan, 1, 0.34% The Chemical Society of Japan 1 publication, 0.34%
The Royal Society	The Royal Society, 1, 0.34% The Royal Society 1 publication, 0.34%
Japan Institute of Metals and Materials	Japan Institute of Metals and Materials, 1, 0.34% Japan Institute of Metals and Materials 1 publication, 0.34%
Cambridge University Press	Cambridge University Press, 1, 0.34% Cambridge University Press 1 publication, 0.34%
Korean Institute of Metals and Materials	Korean Institute of Metals and Materials, 1, 0.34% Korean Institute of Metals and Materials 1 publication, 0.34%
Higher Education Press	Higher Education Press, 1, 0.34% Higher Education Press 1 publication, 0.34%
Korean Society of Industrial Engineering Chemistry	Korean Society of Industrial Engineering Chemistry, 1, 0.34% Korean Society of Industrial Engineering Chemistry 1 publication, 0.34%
SPIE	SPIE, 1, 0.34% SPIE 1 publication, 0.34%
Funtai Funmatsu Yakin Kyokai	Funtai Funmatsu Yakin Kyokai, 1, 0.34% Funtai Funmatsu Yakin Kyokai 1 publication, 0.34%
Walter de Gruyter	Walter de Gruyter, 1, 0.34% Walter de Gruyter 1 publication, 0.34%
American Association for the Advancement of Science (AAAS)	American Association for the Advancement of Science (AAAS), 1, 0.34% American Association for the Advancement of Science (AAAS) 1 publication, 0.34%
	20 40 60 80 100 120

We do not take into account publications without a DOI.
Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
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Mizuno F. et al. High lithium ion conducting glass-ceramics in the system Li2S–P2S5 // Solid State Ionics. 2006. Vol. 177. No. 26-32. pp. 2721-2725.

GOST all authors (up to 50) Copy

Mizuno F., Hayashi A., Tadanaga K., Tatsumisago M. High lithium ion conducting glass-ceramics in the system Li2S–P2S5 // Solid State Ionics. 2006. Vol. 177. No. 26-32. pp. 2721-2725.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.ssi.2006.04.017

UR - https://doi.org/10.1016/j.ssi.2006.04.017

TI - High lithium ion conducting glass-ceramics in the system Li2S–P2S5

T2 - Solid State Ionics

AU - Mizuno, Fuminori

AU - Hayashi, Akitoshi

AU - Tadanaga, Kiyoharu

AU - Tatsumisago, Masahiro

PY - 2006

DA - 2006/10/01 00:00:00

PB - Elsevier

SP - 2721-2725

IS - 26-32

VL - 177

SN - 0167-2738

ER -

BibTex |

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BibTex Copy

@article{2006_Mizuno,

author = {Fuminori Mizuno and Akitoshi Hayashi and Kiyoharu Tadanaga and Masahiro Tatsumisago},

title = {High lithium ion conducting glass-ceramics in the system Li2S–P2S5},

journal = {Solid State Ionics},

year = {2006},

volume = {177},

publisher = {Elsevier},

month = {oct},

url = {https://doi.org/10.1016/j.ssi.2006.04.017},

number = {26-32},

pages = {2721--2725},

doi = {10.1016/j.ssi.2006.04.017}

}

MLA

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MLA Copy

Mizuno, Fuminori, et al. “High lithium ion conducting glass-ceramics in the system Li2S–P2S5.” Solid State Ionics, vol. 177, no. 26-32, Oct. 2006, pp. 2721-2725. https://doi.org/10.1016/j.ssi.2006.04.017.

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Publisher

Elsevier

Journal

Solid State Ionics

Quartile SCImago

Quartile WOS

Impact factor

3.2

ISSN

01672738 (Print)