Solid State Ionics, volume 262, pages 617-621

Synthesis procedure and effect of Nd, Ca and Nb doping on structure and electrical conductivity of Li7La3Zr2O12 garnets

Emil Hanc ¹

Wojciech Zając ¹

Janina Molenda ¹

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AGH University of Science and Technology, Faculty of Energy and Fuels, Department of Hydrogen Energy, al. A. Mickiewicza 30, 30-059, Krakow, Poland |

Publication type: Journal Article

Publication date: 2014-09-01

Elsevier

Journal: Solid State Ionics

Quartile SCImago

Quartile WOS

Impact factor: 3.2

ISSN: 01672738

DOI: 10.1016/j.ssi.2013.11.033

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General Chemistry

Condensed Matter Physics

General Materials Science

Abstract

Procedure of solid state synthesis of Li 7 La 3 Zr 2 O 12 garnets was investigated. After calcination of reactants at 800 °C single-phased tetragonal-structure garnet material was produced. Subsequent sintering at 1200 °C gave cubic-structure garnet. The effect of Ca, Nd and Nb doping for structure parameters and Li-ion conductivity was studied. Ca and Nd dopants were located in La sublattice, whereas Nb was located in Zr sublattice, leading to changes in nominal lithium content. Similarly to nominally undoped Li 7 La 3 Zr 2 O 12 , all doped materials possessed cubic garnet structure, however, in all the cases the observed lattice parameters were lower than for the undoped material. For all synthesized materials, determined lithium content was lower than the nominal value, and slight amount of aluminum was detected. Electrical conductivity at room temperature for all tested materials was in the range 0.8–4.2 × 10 − 5 S cm − 1 . Nearly linear positive correlation between lattice constant and ionic conductivity was observed. The influence of lithium variation for the studied composition range was found to be insignificant.

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Hanc E., Zając W., Molenda J. Synthesis procedure and effect of Nd, Ca and Nb doping on structure and electrical conductivity of Li7La3Zr2O12 garnets // Solid State Ionics. 2014. Vol. 262. pp. 617-621.

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TY - JOUR

DO - 10.1016/j.ssi.2013.11.033

UR - https://doi.org/10.1016/j.ssi.2013.11.033

TI - Synthesis procedure and effect of Nd, Ca and Nb doping on structure and electrical conductivity of Li7La3Zr2O12 garnets

T2 - Solid State Ionics

AU - Hanc, Emil

AU - Zając, Wojciech

AU - Molenda, Janina

PY - 2014

DA - 2014/09/01 00:00:00

PB - Elsevier

SP - 617-621

VL - 262

SN - 0167-2738

ER -

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@article{2014_Hanc,

author = {Emil Hanc and Wojciech Zając and Janina Molenda},

title = {Synthesis procedure and effect of Nd, Ca and Nb doping on structure and electrical conductivity of Li7La3Zr2O12 garnets},

journal = {Solid State Ionics},

year = {2014},

volume = {262},

publisher = {Elsevier},

month = {sep},

url = {https://doi.org/10.1016/j.ssi.2013.11.033},

pages = {617--621},

doi = {10.1016/j.ssi.2013.11.033}

}

Found error?

Publisher

Elsevier

Journal

Solid State Ionics

Quartile SCImago

Quartile WOS

Impact factor

3.2

ISSN

01672738 (Print)