Solid State Ionics, volume 263, pages 27-32

Water-stable lithium ion conducting solid electrolyte of iron and aluminum doped NASICON-type LiTi2(PO4)3

P. Zhang
M. Matsui
Y. Takeda
O. Yamamoto
N. Imanishi
Publication typeJournal Article
Publication date2014-10-01
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor3.2
ISSN01672738
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
High lithium ion conductivity solid electrolytes of Li 1.4 Fe x Al 0.4 - x Ti1.6(PO 4 ) 3 (x = 0−0.4) with the NASICON-type structure were synthesized by using a sol−gel precursor. The highest electrical conductivity was obtained for Li 1.4 Fe 0.25 Al 0.15 Ti 1.6 (PO 4 ) 3 sintered at 1040 °C for 7 h in air. The total, grain boundary, and bulk conductivities of the pellet were 1.01 × 10 -3 , 2.17 × 10 -3 and 1.81 × 10 -3  S cm -1 at 25 °C, respectively. The contribution of electron (or hole) conductivity to the total conductivity was negligibly small. Li 1.4 Fe 0.25 Al 0.15 Ti 1.6 (PO 4 ) 3 was unstable in water, but stable in saturated LiOH and LiCl aqueous solutions.

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Zhang P. et al. Water-stable lithium ion conducting solid electrolyte of iron and aluminum doped NASICON-type LiTi2(PO4)3 // Solid State Ionics. 2014. Vol. 263. pp. 27-32.
GOST all authors (up to 50) Copy
Zhang P., Matsui M., Takeda Y., Yamamoto O., Imanishi N. Water-stable lithium ion conducting solid electrolyte of iron and aluminum doped NASICON-type LiTi2(PO4)3 // Solid State Ionics. 2014. Vol. 263. pp. 27-32.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.ssi.2014.04.017
UR - https://doi.org/10.1016/j.ssi.2014.04.017
TI - Water-stable lithium ion conducting solid electrolyte of iron and aluminum doped NASICON-type LiTi2(PO4)3
T2 - Solid State Ionics
AU - Zhang, P.
AU - Matsui, M.
AU - Takeda, Y.
AU - Yamamoto, O.
AU - Imanishi, N.
PY - 2014
DA - 2014/10/01 00:00:00
PB - Elsevier
SP - 27-32
VL - 263
SN - 0167-2738
ER -
BibTex
Cite this
BibTex Copy
@article{2014_Zhang,
author = {P. Zhang and M. Matsui and Y. Takeda and O. Yamamoto and N. Imanishi},
title = {Water-stable lithium ion conducting solid electrolyte of iron and aluminum doped NASICON-type LiTi2(PO4)3},
journal = {Solid State Ionics},
year = {2014},
volume = {263},
publisher = {Elsevier},
month = {oct},
url = {https://doi.org/10.1016/j.ssi.2014.04.017},
pages = {27--32},
doi = {10.1016/j.ssi.2014.04.017}
}
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