Solid State Ionics, volume 268, pages 300-304

The unusual role of Li6PS5Br in all-solid-state CuS/Li6PS5Br/In–Li batteries

Mao-Hua Chen ¹

Rayavarapu Prasada Rao ¹

Stefan Adams ¹

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Department of Materials Science and Engineering, National University of Singapore, 9 Engineering Drive 1, 117576 Singapore, Singapore |

Publication type: Journal Article

Publication date: 2014-12-01

Elsevier

Journal: Solid State Ionics

Quartile SCImago

Quartile WOS

Impact factor: 3.2

ISSN: 01672738

DOI: 10.1016/j.ssi.2014.05.004

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General Chemistry

Condensed Matter Physics

General Materials Science

Abstract

Fast ion conducting lithium argyrodites Li 6 PS 5 X (X = Cl, Br) are promising solid electrolytes for rechargeable all-solid-state lithium batteries. Here we realized all-solid-state lithium batteries combining Li 6 PS 5 Br with CuS as the cathode. An initial discharge capacity of 650 mAh/g was achieved, though the reversible capacity after 20 cycles was limited to be 90 mAh/g. Based on X-ray diffraction measurements at different discharge stages we identified a peculiar reaction mechanism of CuS in this all-solid-state battery design, as the Li 6 PS 5 Br electrolyte is found to reversibly participate in the cell reaction: at intermediate stages of the discharge Cu + is incorporated in the argyrodite leading to Cu y Li 6 − y PS 5 Br. The reduced ionic conductivity of Cu y Li 6 − y PS 5 Br and the volume change of the electrolyte during cycling affect the cyclic performance of the batteries in addition to the volume changes of the active materials. From the first cycle onwards both processes result – as evidenced by SEM – in progressive crack formation, dissociation of the active material from Li 6 PS 5 Br and carbon and consequential capacity fading.

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Chen M., Prasada Rao R., Adams S. The unusual role of Li6PS5Br in all-solid-state CuS/Li6PS5Br/In–Li batteries // Solid State Ionics. 2014. Vol. 268. pp. 300-304.

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Chen M., Prasada Rao R., Adams S. The unusual role of Li6PS5Br in all-solid-state CuS/Li6PS5Br/In–Li batteries // Solid State Ionics. 2014. Vol. 268. pp. 300-304.

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TY - JOUR

DO - 10.1016/j.ssi.2014.05.004

UR - https://doi.org/10.1016/j.ssi.2014.05.004

TI - The unusual role of Li6PS5Br in all-solid-state CuS/Li6PS5Br/In–Li batteries

T2 - Solid State Ionics

AU - Chen, Mao-Hua

AU - Prasada Rao, Rayavarapu

AU - Adams, Stefan

PY - 2014

DA - 2014/12/01 00:00:00

PB - Elsevier

SP - 300-304

VL - 268

SN - 0167-2738

ER -

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BibTex Copy

@article{2014_Chen,

author = {Mao-Hua Chen and Rayavarapu Prasada Rao and Stefan Adams},

title = {The unusual role of Li6PS5Br in all-solid-state CuS/Li6PS5Br/In–Li batteries},

journal = {Solid State Ionics},

year = {2014},

volume = {268},

publisher = {Elsevier},

month = {dec},

url = {https://doi.org/10.1016/j.ssi.2014.05.004},

pages = {300--304},

doi = {10.1016/j.ssi.2014.05.004}

}

Found error?

Publisher

Elsevier

Journal

Solid State Ionics

Quartile SCImago

Quartile WOS

Impact factor

3.2

ISSN

01672738 (Print)